Tangled lines in New Zealand's quota management system: The process of including recreational fisheries

This article uses New Zealand as a case study of processes relating to the inclusion of recreational fisheries in modern fisheries management systems based on Individual Transferable Quotas (ITQs). The New Zealand case highlights challenges governments often meet when attempting to integrate the recreational sector into fisheries management, including: (a) resistance to restrictions on what has historically been free-of-charge public access to fish for recreational purposes and (b) the fragmented character of the recreational sector, which makes it difficult to have recreational interests attend to their management role and responsibilities.     

Holocene cool‐water carbonate and terrigenous sediments from southern Spencer Gulf,South Australia

Holocene sediments from southern Spencer Gulf are cool‐water carbonate‐rich gravels and sands, dominated by molluscs and Bryozoa. Five sedimentary fades are recognized: (i) molluscan gravel; (ii) branching coralline‐algal gravel, associated with shallow partially protected environments; (iii) molluscan‐biyozoan sand; (iv) mixed bioclastic sand, representative of the deeper central region of the lower gulf; and (v) bryozoan gravel, an isolated fades developed in a semi‐protected micro‐environment. The southern gulf is characterized by complex oceanographic conditions together with variations in water depth and substrate. The sediments share the characteristics of both the southern shelf and upper Spencer Gulf. Grain‐size distribution and sedimentary facies are controlled by a combination of all the above processes. Past sea level fluctuations are recognized from sea floor strand‐line deposits. The relic component of the palimpsest sediments has eroded from the Pleistocene aeolianite dunes. The sediments, therefore, reflect both the modern marine and past environments.     

Sabkha and playa environments in late Proterozoic grabens,Willouran Ranges,South Australia

We have reconstructed the depositional environment of sulphate‐dolomite‐sand‐mud sequences of the Callanna Beds of the late Proterozoic Adelaidean System in three areas of the Willouran Ranges, South Australia. We interpret the Callanna Beds which represent the earliest Adelaidean sediments as having been deposited in a series of discrete shallow cratonic basins. The sequences in all three areas consist of cyclic hypersaline sand‐shale‐carbonate sheets and wedges. Hypersalinity has been inferred from a study of evaporites and their pseudomorphs, which imply basin evolution in sabkha and playa palaeoenvironments. We interpret the Callanna Beds in the Willouran Ranges to have been formed in playa lake or prograding sabkha complexes, that formed in a series of yoked half‐grabens within the tectonic setting of the Adelaide palaeorift.     

A model for the internal structures of asteroids

Interpretation of reflectance spectra indicates that most belt asteroids are composed of materials similar to carbonaceous chondrites. Also, there is considerable evidence to support the origin of many, if not most, lunar and meteoritic chondrules by impact processes. The accretional histories of the carbonaceous asteroids must have influenced greatly their internal structures and textures. A model for this accretional history can be divided conveniently into three temporal stages that produce distinctly different lithologies: (1) low-velocity accretion of fine silicate and carbonaceous grains producing chondrule-free petrologic type 1 lithology; (2) continued accretion of low-velocity fine silicate and carbonaceous grains, but with a few larger, higher-velocity bodies also impacting the surface thereby producing both fluid drop and lithic chondrules (the resultant lithology would be that of petrologic type 2 and 3 carbonaceous chondrites); and (3) dominance of high-velocity low-mass meteoroid impacts, producing a sparse, thin, erosive lunar-like regolith. The lithologic product of stage 3 is not ideally represented among the presently described carbonaceous chondrites, but texturally analogous samples are known from the achondrites. The greater proportion of chondrules in the CV group meteorites, in contrast to the CM2 and CO3 groups, may be due to the origin of the CV chondrites on larger asteroid parent bodies that could withstand more numerous and higher-energy chondrule-producing impacts prior to fragmentation.     

Dissolved organic matter (DOM) export to a temperate estuary: seasonal variations and implications of land use

Inputs of dissolved carbon, nitrogen, and phosphorus were assessed for an estuary and its catchment (Horsens, Denmark). Seasonal patterns in the concentrations of DOM in the freshwater supply to the estuary differed depending on the soil and drainage characteristics of the area. In streams draining more natural areas the, patterns observed were largely driven by seasonal temperature fluctuations. The material exported from agricultural areas was more variable and largely controlled by precipitation events. Positive exponential relationships were found between the nitrogen and phosphorus loading, and the percentage of catchment area used for agriculture. Colored DOM (CDOM) loading measurements were found to be a good predictor of dissolved organic carbon (DOC) loading across the different subcatchments, offering a rapid and inexpensive alternative of operationally monitoring DOC export. For all the dissolved nutrient inputs to the estuary, dissolved inorganic nitrogen (DIN) and dissolved organic phosphorus dominated the loadings. Although 81% of the nitrogen annually supplied to the estuary was DIN, 83% of the nitrogen exported from the estuary was dissolved organic nitrogen (DON). Results show that increasing the area of the catchment covered by forest and natural pastures would have a positive effect on the trophic status of the estuary, leading to a considerable decrease in the phosphorus loading and a shift in the nitrogen loading from DIN to DON. Such a change in land use would also increase the export of DOC and CDOM to the estuary having the potential to increase oxygen consumption and reduce the photic depth.     

GRAIN SIZE AND PETROGRAPHY OF C2 AND C3 CARBONACEOUS CHONDRITES

Grain size frequency distributions of the ≥ 0.1 mm size fractions have been measured for 19 C2 and C3 carbonaceous chondrites (7 CM2, 5 CO3, 6 CV3 and 1 CV2). The grain size frequency distribution curves and summary statistics are remarkably similar for the CM2 and CO3 meteorites, with ranges of median grain size from 2.36φ to 2.67φ and graphic mean grain size from 2.20φ to 2.59φ. The CV3 specimens are distinctly coarser than the CM2 and CO3 meteorites and have a wider range of grain size summary statistics. The grain size frequency data for fluid drop chondrules and for lithic chondrules show approximately the same size frequency characteristics as the more abundant particles in each of the petrologic subgroups. If the chondrules and other particles were produced by different mechanisms or in different environments, an extremely effective size sorting process is required to produce the observed grain size frequency distributions. Alternatively, most of the particles and the observed grain size frequency distributions might have been produced by small impacts into an immature, accretionary regolith. The strong similarity between the grain sizes of the CM2 and CO3 meteorites, together with previously recognized chemical similarities, suggest a genetic relationship between the two petrologic subgroups. The grain size frequency distributions of chondrules and other particles in CM2 and CO3 meteorites are different from those found previously in ordinary chondrites     

SIZE FREQUENCY DISTRIBUTIONS OF FLUID DROP CHONDRULES IN ORDINARY CHONDRITES

The size frequency distributions of fluid drop chondrules in 11 ordinary chondrites (five H3, one H4, four L3, one LL3) have been determined by optical measurements in petrographic thin sections. The extreme range of median size of the fluid drop chondrules in individual meteorites is only slightly greater than lφ unit, and the grain size frequency distributions are approximately log normal. Chondrule size frequency distributions generally are fine skewed, platykurtic, and indicate moderate sorting. The size frequency distributions of fluid drop chondrules in ordinary chondrites are distinctly coarser than similar chondrules measured previously in CM2 and C03 carbonaceous chondrites.     

Towards a new galaxy template library for multi-colour classification

The COMBO-17 survey cite(Wolf et al., 2002) contains ≈ 40000 galaxies down to R=24 mag on an area of one square degree, obtained with the wide field imager at the 2.2 m telescope at La Silla. A multi-colour classification on the basis of 5 broadband and 12 medium band filters (=17 bands) yields accurate redshifts (σ _z ≤ 0.01 at the bright end up to σ _z ≈ 0.1 at the faint end) and spectral energy distribution types (SEDs) when using observed galaxy templates from (Kinney et al.,1996). However, there is an obvious weakness in this classification scheme: The relation between star formation history and SED remains unclear. It is therefore impossible to draw firm conclusions about the age of the underlying stellar population and the expected aging between z ≈ 1 and z ≈ 0 can not be quantified. We will present first results of our attempt to replace the observed templates with model spectra from the PEGASE code (Fioc and Rocca-Volmerange, 1997), in order to get a better handle on the star formation history. This revised version was published online in August 2006 with corrections to the Cover Date.     

Phosphatic concretions and nodules from the upper continental slope,northern New South Wales

Phosphatic concretions and nodules, some of which are coated with goethite, have been dredged at depths between 210 and 385 m from the upper continental slope off northern New South Wales. Some of these appear to have been concentrated on a low sea level terrace at a depth of about 210 m by wave action, while deeper‐water non‐abraded examples may have been winnowed from host sediments by relatively gentle current activity. Similarities in structure, mineralogy and age of contained fauna are noted between nodules described in this paper and phosphatic nodules from the California Continental Borderland, the Chatham Rise off New Zealand and Cainozoic sediments outcropping in Victoria. It is proposed that the Eastern Australian material formed as phosphatic concretions within phosphorus‐enriched slope sediments during diagenesis and that they have since been winnowed, exposed and in some cases re‐cemented into agglomerations on the sea floor in areas of low sedimentation rate.     

Arsenic redox transformation by humic substances and Fe minerals

The toxicity and mobility of the redox-active metalloid As strongly depends on its oxidation state, with As(III) (arsenite) being more toxic and mobile than As(V) (arsenate). It is, therefore, necessary to know the biogeochemical processes potentially influencing As redox state to understand and predict its environmental behavior. The first part of this presentation will discuss the quantification of As redox changes by pH-neutral mineral suspensions of goethite [α-Fe^IIIOOH] amended with Fe(II) using wet-chemical and synchrotron X-ray absorption (XANES) analysis (Amstaetter et al., 2010). First, it was found that goethite itself did not oxidize As(III). Second, in contrast to thermodynamic predictions, Fe(II)–goethite systems did not reduce As(V). However, surprisingly, rapid oxidation of As(III) to As(V) was observed in Fe(II)–goethite systems. Iron speciation and mineral analysis by Mössbauer spectroscopy showed rapid formation of ⁵⁷Fe–goethite after ⁵⁷Fe(II) addition and the formation of a so far unidentified additional Fe(II) phase. No other Fe(III) phase could be detected by Mössbauer spectroscopy, EXAFS, scanning electron microscopy, X-ray diffraction or high-resolution transmission electron microscopy. This suggests that reactive Fe(III) species form as an intermediate Fe(III) phase upon Fe(II) addition and electron transfer into bulk goethite but before crystallization of the newly formed Fe(III) as goethite.The second part of the presentation will show that semiquinone radicals produced during microbial or chemical reduction of a humic substance model quinone (AQDS, 9,10-anthraquinone-2,6-disulfonic acid) can react with As and change its redox state (Jiang et al., 2009). The results of these experiments showed that these semiquinone radicals are strong oxidants and oxidize arsenite to arsenate, thus decreasing As toxicity and mobility. The oxidation of As(III) depended strongly on pH. More arsenite (up to 67.3%) was oxidized at pH 11 compared to pH 7 (12.6% oxidation) and pH 3 (0.5% oxidation). In addition to As(III) oxidation by semiquinone radicals, hydroquinones that were also produced during quinone reduction, reduced As(V) to As(III) at neutral and acidic pH values (less than 12%) but not at alkaline pH. In an attempt to understand the observed redox reactions between As and reduced/oxidized quinones present in humic substances, the radical content in reduced AQDS solutions was quantified and Eh-pH diagrams were constructed. Both the radical quantification and the Eh-pH diagram allowed explaining the observed redox reactions between the reduced AQDS solutions and the As.In summary these studies indicate that in the simultaneous presence of Fe(III) oxyhydroxides, Fe(II), and humic substances as commonly observed in environments inhabited by Fe-reducing microorganisms, As(III) oxidation can occur. This potentially explains the presence of As(V) in reduced groundwater aquifers.