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1.
Experimental study on prevention of acid mine drainage by silica coating of pyrite waste rocks with amorphous silica solution 总被引:1,自引:1,他引:0
Masahiko Bessho Takaaki Wajima Takuro Ida Takashi Nishiyama 《Environmental Earth Sciences》2011,64(2):311-318
Acid mine drainage (AMD) is a widespread environmental problem associated with working and abandoned mining operations. It
results from the microbial oxidation of pyrite in the presence of water and air, affording an acidic solution that contains
toxic metal ions. Pyrite microencapsulation, utilizing silica coating, is a novel approach for controlling AMD that has been
shown to be very effective in controlling pyrite oxidation. The roles of the solution pH and silica concentration in the formation
mechanism for the AMD-preventing coating were investigated. A silica coating can be formed from silica solution at pH 7, at
which the amount of Fe eluted from pyrite into the solution is small. No coating was formed at other pH values, and the amounts
of eluted Fe were larger than at pH 7, especially at pH 11. The silica coating forms from 2,500 to 5,000 mg/L silica solutions,
but not from 0 or 1,000 mg/L silica solutions. The coating formation rate was slower in the 2,500 mg/L silica solution than
in the 5,000 mg/L silica solution. The formation of silica coating on pyrite surfaces depends on three main steps: formation
of Fe(OH)3 on the surface of pyrite, reaction between Fe(OH)3 and silicate in the solution on the pyrite surface, and growth of the silica layer on the first layer of silica. The best
pH condition to enable these steps was around 7, and the silica coating formation rate can be controlled by the concentration
of silica. 相似文献
2.
Argon and nitrogen isotopes of air in polar ice cores provide constraints on past temperature and firn thickness, with relevance to past climate. We developed a method to simultaneously measure nitrogen and argon isotopes in trapped air from the same sample of polar ice. This method reduces the time required for analysis, allowing large numbers of measurements. We applied this method to the entire Holocene sequence of the GISP2 ice core (82.37-1692.22 m) with a 10-20 year sampling interval (670 depths). δ40Ar and δ15N show elevated values in the oldest part of the dataset, consistent with a thicker firn layer and increased temperature gradient in the firn due to the legacy of the abrupt warming at the end of the Younger Dryas interval and the gradual warming during the Preboreal interval (11.5-10.0 ka). The Preboreal Oscillation and the 8.2k event are clearly recorded. The data show remarkable stability after the 8.2k event.Available data suggests that post-coring gas loss involves two distinct types of fractionation. First, smaller molecules with less than a certain threshold size leak through the ice lattice with little isotopic fractionation. Second, gas composition changes via gas loss through microcracks, which induces isotopic fractionation. These two gas loss processes can explain most trends in our data and in other ice core records. 相似文献
3.
GIS-based weights-of-evidence modelling of rainfall-induced landslides in small catchments for landslide susceptibility mapping 总被引:10,自引:0,他引:10
Ranjan Kumar Dahal Shuichi Hasegawa Atsuko Nonomura Minoru Yamanaka Takuro Masuda Katsuhiro Nishino 《Environmental Geology》2008,54(2):311-324
Landslide susceptibility mapping is a vital tool for disaster management and planning development activities in mountainous terrains of tropical and subtropical environments. In this paper, the weights-of-evidence modelling was applied, within a geographical information system (GIS), to derive landslide susceptibility map of two small catchments of Shikoku, Japan. The objective of this paper is to evaluate the importance of weights-of-evidence modelling in the generation of landslide susceptibility maps in relatively small catchments having an area less than 4 sq km. For the study area in Moriyuki and Monnyu catchments, northeast Shikoku Island in west Japan, a data set was generated at scale 1:5,000. Relevant thematic maps representing various factors (e.g. slope, aspect, relief, flow accumulation, soil depth, soil type, land use and distance to road) that are related to landslide activity were generated using field data and GIS techniques. Both catchments have homogeneous geology and only consist of Cretaceous granitic rock. Thus, bedrock geology was not considered in data layering during GIS analysis. Success rates were also estimated to evaluate the accuracy of landslide susceptibility maps and the weights-of-evidence modelling was found useful in landslide susceptibility mapping of small catchments. 相似文献
4.
A fluidized landslide on a natural slope by artificial rainfall 总被引:9,自引:5,他引:4
Hirotaka?Ochiai Yasuhiko?OkadaEmail author Gen?Furuya Yoichi?Okura Takuro?Matsui Toshiaki?Sammori Tomomi?Terajima Kyoji?Sassa 《Landslides》2004,1(3):211-219
An experiment to induce a fluidized landslide by artificial rainfall was conducted on a natural slope at Mt. Kaba-san in the village of Yamato, Ibaraki Prefecture, Japan. The experimental slope was 30 m long, 5 m wide, and the average slope gradient was 33°. A landslide initiated 24,627.5 s (410 m/27.5 s) after the start of sprinkling at a rainfall intensity of 78 mm/h. The landslide mass was 14 m long and 1.2 m deep (at maximum). It first slid, then fluidized, and changed into a debris flow. The travel distance was up to 50 m in 17s. The apparent friction angle of the fluidized landslide was 16.7°. Formation of the sliding surface was detected by soil-strain probes. Motion of the surface of the failed landslide mass was determined by stereo photogrammetry. 相似文献
5.
Rapid development of arctic cyclone in June 2008 simulated by the cloud resolving global model NICAM
In this study, we conducted a numerical simulation of a rapid development of an arctic cyclone (AC) that appeared in June 2008 using a cloud resolving global model, Nonhydrostatic ICosahedral Atmospheric Model (NICAM). We investigated the three dimensional structure and intensification mechanism of the simulated AC that developed to the minimum sea level pressure of 971 hPa in the model. According to the result, the AC indicates a barotropic structure with a warm core in the lower stratosphere and a cold core in the troposphere. The development of the AC is accompanied by an intense mesoscale cyclone (MC) showing baroclinic structure with a marked local arctic front. The upper level warm core of the AC is formed by an adiabatic heating associated with the downdraft in the lower stratosphere. The rapid development of the AC is caused by the combination of the intensification of the upper level warm core and the merging with the baroclinically growing MC in the lower level. The merging of the AC and MC and the vertical vortex coupling with the upper air polar vortex are the most important mechanisms for the rapid development of the arctic cyclone. 相似文献
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Culture-dependent and independent analyses of subsurface microbial communities in oil-bearing strata of the Sagara oil reservoir 总被引:3,自引:0,他引:3
Takuro Nunoura Hanako Oida Noriaki Masui Fumio Inagaki Ken Takai Satoshi Hirano Kenneth H. Nealson Koki Horikoshi 《Island Arc》2006,15(3):328-337
Abstract Culture-dependent and independent methods were used to evaluate the microbial communities in cores collected at depths up to 200 m in oil-bearing and oil-free strata near the Sagara oil reservoir near Shizuoka, Japan. Direct microbial counts revealed much higher numbers (2.2 × 104 −7.9 × 106 /g) of microbes in the oil-bearing strata than in the oil-free zones, where counts were uniform at approximately 1.0 × 104 /g. Molecular taxonomic analyses via 16S rRNA gene sequence comparisons showed that the oil-free strata were dominated by members of the γ-Proteobacteria including Pseudomonas , Stenotrophomonas and Sphingomonas , whereas the oil-bearing strata were dominated by a single species closely related to Pseudomonas stutzeri . All archaeal clones were phylogenetically affiliated with the uncultured soil group in Crenarchaeota with the exception of a single phylotype that belonged to the genus Thermococcus . Culture-dependent analysis was carried out by most-probable-number culturing as well as direct plating to determine viable cell counts, using both complex organic substrates or native oil and autotrophic media. Both culture-dependent and independent methods revealed the abundant cultivable member was the aerobic oil-degrading bacterium Pseudomonas stutzeri and neither autotrophs nor anaerobic heterotrophs could be detected in the oil-bearing strata. 相似文献
9.
Etsuo Uchida Takuro Haitani Takayuki Suetsugu Takahiro Kashima Ken Tsutsui 《Resource Geology》2003,53(2):155-161
Abstract. The distribution of Na, K, Ca, Mg, Mn and Fe between the granodiorite JG-la, one of the geochemical standard rocks, and 2M NaCl aqueous solution was experimentally determined at temperatures of 300 to 800C and a pressure of 1 kb using standard cold seal-type pressure vessels. The solid run products melted partially at 800C. Only K shows a significantly different behavior from the experiments using the basalt JB-la (Uchida and Tsutsui, 2000) due to the presence of ortho-clase in the JG-la. The transition elements tend to be preferably partitioned into the aqueous chloride solutions with increasing temperature. At 800C and 1 kb, the Fe concentration of the aqueous chloride solutions reached up to 5,000 ppm, and the Mn concentration up to 350 ppm. The distribution coefficient, KD, i = Ci, sol /Ci , rock, is in the order of Na>K>Mn>Ca> Fe>Mg at 300C, but changed in the order of Mn>N>K>Fe>Ca>Mg at 800C. The distribution coefficients of the divalent cations for the JG-la are higher than those for the JB-1a. The distribution coefficient of the transition elements, Fe and Mn, increases significantly with increasing temperature. The thermodynamic analysis for aqueous speciation revealed that this is attributable to the formation of the tri-chloro complexes of the transition elements at higher temperatures. 相似文献