Geothermal palaeogradients and metamorphic zonation from the conodont colour alteration index (CAI)

The conodont colour alteration index (CAI) is potentially valuable in thermal history investigations, but there are problems in its use. An approach is proposed herein to overcome the problem of establishing reliable geothermal palaeogradients in areas with burial metamorphism, based on knowledge of the stratigraphic succession thickness, the boundaries of chronostratigraphic units, and the age and duration of deformation episodes. Although also problematical that a correlation between CAI and Kübler index (KI) values does not exist, there are areas where CAI and KI values are notably consistent for the anchizone boundaries; however, anomalous correlations between CAI and KI values have also been found in some areas. A CAI anchizone (or ancaizone) is defined in order to enable CAI values to be used independently to establish a metamorphic zonation.     

Late Carboniferous porphyry copper mineralization at La Voluntad,Neuquén,Argentina: Constraints from Re–Os molybdenite dating

The La Voluntad porphyry Cu–Mo deposit in Neuquén, Argentina, is one of several poorly known porphyry-type deposits of Paleozoic to Early Jurassic age in the central and southern Andes. Mineralization at La Voluntad is related to a tonalite porphyry from the Chachil Plutonic Complex that intruded metasedimentary units of the Piedra Santa Complex. Five new Re–Os molybdenite ages from four samples representing three different vein types (i.e., quartz–molybdenite, quartz–sericite–molybdenite and quartz–sericite–molybdenite ± chalcopyrite–pyrite) are identical within error and were formed between ~312 to ~316 Ma. Rhenium and Os concentrations range between 34 to 183 ppm and 112 to 599 ppb, respectively. The new Re–Os ages indicate that the main mineralization event at La Voluntad, associated to sericitic alteration, was emplaced during a time span of 1.7 ± 3.2 Ma and that the deposit is Carboniferous in age, not Permian as previously thought. La Voluntad is the oldest porphyry copper deposit so far recognized in the Andes and indicates the presence of an active magmatic arc, with associated porphyry style mineralization, at the proto-Pacific margin of Gondwana during the Early Pennsylvanian.     

Three-Dimensional Velocity Field and Cross-Frontal Water Exchange in the Kuroshio Extension

A spread of warm water from the first crest of the Kuroshio Extension is periodically enhanced by northward warm water intrusions from the main current. The water type in the spread area was previously found to be the same as that in the Kuroshio front at depth. In looking for the possible mechanism responsible for the northward warm water intrusions, a dynamic analysis in the Kuroshio front was carried out by using CTD, ADCP, AVHRR and ARGOS buoy data, obtained in 1996 by the R.V. Hakuho Maru. Downstream, cross-stream and vertical velocities in the Kuroshio Extension were found by using a "stream coordinate system". The velocity field in the Kuroshio front at the first crest showed a double structure with two surface velocity maxima. In the inner part of the front, relatively high cross-stream (northward) and vertical (upward) velocities were found. Thus, this study suggests that while water particles flow downstream along the first stationary meander of the Kuroshio Extension, they also experience lateral and vertical movements which allow the deeper water from an upstream location to rise to the surface layer, and in certain locations to deflect northward. By assuming isopycnal movement and conservation of potential vorticity, it was found that in those locations where anticyclonic curvature of the meander increases, warm water is more likely to deflect northward. High ageostrophic components observed in the first 300 m of the water column are probably related to the relatively high cross-stream and vertical velocities in the inner part of the front.     

The Alcamayo and Cedrobamba catastrophic debris flow (January, March and April 2004) in Machupicchu area—Peru

A debris flow originating from the Alcamayo River on 10th April 2004 destroyed a part of the town of Aguas Calientes, resulting in 11 victims, and with serious affects to the tourist flow to the Machupicchu inka citadel. On the same day, as well as in January and March 2004, other similar phenomena occurred on the Cedrobamba and Leonchayoq Rivers, affecting the railway and an electrical tower, and disrupting the train service.     

23,000 yr of vegetation history of the Upper Lerma, a tropical high-altitude basin in Central Mexico

Pollen analysis on a 9.54-m sediment core from lake Chignahuapan in the upper Lerma basin, the highest intermontane basin in Central Mexico (2570 m asl), documents vegetation and limnological changes over the past ∼23,000 ¹⁴C yr. The core was drilled near the archaeological site of Santa Cruz Atizapán, a site with a long history of human occupation, abandoned at the end of the Epiclassic period (ca. 900 AD). Six radiocarbon AMS dates and two well-dated volcanic events, the Upper Toluca Pumice with an age of 11,600 ¹⁴C yr B.P. and the Tres Cruces Tephra of 8500 ¹⁴C yr B.P., provide the chronological framework for the lacustrine sequence. From ca. 23,000 ¹⁴C yr B.P. to ca. 11,600 ¹⁴C yr B.P. the plant communities were woodlands and grasslands based on the pollen data. The glacial advances MII-1 and MII-2 correlate with abundant non-arboreal pollen, mainly grasses, from ca. 21,000 to 16,000 ¹⁴C yr B.P., and at ca. 12,600 ¹⁴C yr B.P. During the late Pleistocene, lake Chignahuapan was a shallow freshwater lake with a phase of lower level between 19,000 and 16,000 ¹⁴C yr B.P. After 10,000 ¹⁴C yr B.P., tree cover in the area increased, and a more variable lake level is documented. Late Holocene (ca. 3100 ¹⁴C yr B.P.) deforestation was concurrent with human population expansion at the beginning of the Formative period (1500 B.C.). Agriculture and manipulation of the lacustrine environment by human lakeshore populations appear at 1200 ¹⁴C yr B.P. (550 A.D.) with the appearance of Zea mays pollen and abundant charcoal particles.     

Trends in Extreme Mean Sea Level Quantiles from Satellite Altimetry

Satellite altimetry allows the study of sea-level long-term variability on a global and spatially uniform basis. Here quantile regression is applied to derive robust median regression trends of mean sea level as well as trends in extreme quantiles from radar altimetry time series. In contrast with ordinary least squares regression, which only provides an estimate on the rate of change of the mean of data distribution, quantile regression allows the estimation of trends at different quantiles of the data distribution, yielding a more complete picture of long-term variability. Trends derived from basin-wide averaged regional mean sea level time series are robust and similar for all quantiles, indicating that all parts of the data distribution are changing at the same rate. In contrast, trends are not robust and diverge across quantiles in the case of local time series. Trends are under- (over-)estimated in the western (eastern) equatorial Pacific. Furthermore, trends in the lowermost quantile (0.05) are larger than the median trend in the western Pacific, while trends in the uppermost quantile (0.95) are lower than the median trend in the eastern Pacific. These differences in trends in extreme mean sea level quantiles are explained by the exceptional effect of the strong 1997–1998 El Niño–Southern Oscillation (ENSO) event.     

Environmental limitations on recruitment from seed in invasive Spartina densiflora on a southern European salt marsh

The South American cordgrass, Spartina densiflora, has invaded a range of different habitats that can support different native species assemblages on salt marshes in the Gulf of Cadiz, Spain. Little is known about the mechanisms of invasion. We examined the potential for seed germination and recruitment in a field transplant experiment, representing a wide range of environments, on elevational gradients across marshes with muddy and sandy sediments. The biotic resistance of native, perennial vegetation (where present) to recruitment of the alien was also investigated. Spartina densiflora seeds were able to germinate over a greater than 2-m range of elevation in the tidal frame. Germination success on unvegetated muddy sediments was related to sediment redox potential, with poor germination at strongly negative redox potentials on the lower sites. On sandy, well-drained sediments, germination was apparently constrained by water availability at the highest elevations. Comparison of vegetated and cleared plots on the upper marsh showed that there was a negative relationship between the presence of Atriplex portulacoides and germination on the muddy sediments. Recruitment (survival of seedlings for 12 weeks) was seen only on unvegetated muddy sediments at the highest elevation. Hence the invasive success and wide elevational tolerance of S. densiflora on the marshes of the Gulf of Cadiz are not reflected in its short-term ability to become established from its prolific seed production. Colonization of sub-optimal habitats may be largely by vegetative propagules and clonal growth.     

Magnotospheric imaging of high latitude ion outflows

High latitude ion outflows mostly consist of upward streaming O⁺ and He⁺ emanating from the ionosphere. At heights above 1000 km, these flows consist of cold and hot components which resonantly scatter solar extreme ultraviolet (EUV) light, however, the ion populations respond differently to Doppler shifting resulting from the large relative velocities between the ions and the Sun. The possibility of optical detection of the Doppler effect on the scattering rate will be discussed for the O⁺ (83.4 nm) ions. We have contrasted the EUV solar resonance images of these outflows by simulations of the 30.4 nm He⁺ and 83.4 nm O⁺ emissions for both quiet and disturbed geomagnetic conditions. Input data for the 1000 km level has been obtained from the EICS instrument aboard the Dynamics Explorer satellite. Our results show emission rates of 50 and 56 milli-Rayleighs at 30.4 nm for quiet and disturbed conditions and 65 and 75 milli-Rayleighs at 83.4 nm for quiet and disturbed conditions, respectively, obtained for a polar orbiting satellite and viewing radially outward. We also find that an imager at an equatorial distance of 9 R_E or more is in a favorable position for detecting ion outflows, particularly when the plasmapause is depressed in latitude. However, an occultation disk is necessary to obscure the bright plasmaspheric emissions.     

Analysis of daily rainfall processes in lower extremadura (Spain) and homogenization of the data

Summary In this paper we analyze, from the point of view of stochastic processes, daily rainfall data recorded at the Badajoz Observatory (Southwestern Spain) since the beginning of the century. We attempt to identify any periodicities or trends in the daily rainfall occurrences and their dependence structure, and attempt to select the appropriate point stochastic model for the daily rainfall series.Standard regression analysis, graphical methods and the Cramer statistic show a rise in the number of cases of light rain (between 0.1 and 5 mm/d) and a decline in the number of cases of moderate to heavy rain (> 5 mm/d) in the daily rainfall at least at the 5% significance level.That the homogenization process was satisfactory is shown by the mean interarrival time of the homogenized series and the test of the rate of homogenized daily rainfall occurrences. Our analysis also shows that the behavior of the spectra of the homogenized daily rainfall counts is completely different from that of a Poisson process, so that the hypothesis of a non-homogeneous Poisson process is rejected.With 7 Figures     

Decoupling of arsenic and iron release from ferrihydrite suspension under reducing conditions: a biogeochemical model

High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis. Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted. Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant, or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction revealed vivianite Fe(II)₃(PO₄)₂.8H₂O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results. The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully applied to recent experimental results on the release of arsenic from Bengal delta sediments.