An experimental investigation of LNAPL migration in an unsaturated/saturated sand

Accidental spills of hydrocarbons, such as Light Non-Aqueous Phase Liquids (LNAPLs), are one of the most common sources of subsurface contamination. Migration of LNAPL in a porous medium is influenced by various factors such as the number of fluids present in the unsaturated/saturated zones and the proportion of pores occupied by each fluid. The results for relationship between matric suction and degree of saturation are presented in this paper for water–air, water–LNAPL and LNAPL–air systems in a sand. A simple and reliable setup using Buchner funnel was designed to obtain these relations. It was found that the relationship between matric suction head and degree of saturation is hysteretic for all the fluid systems (water–air, water–LNAPL and LNAPL–air). Furthermore, the amount of hysteresis depended upon the fluid system, with the maximum hysteresis occurring for water–air system. The results suggest that the amount of trapped air depends upon the reversal degree of saturation from drying to wetting.     

Barite deposition resulting from phototrophic sulfide-oxidizing bacterial activity

Barite (BaSO₄) deposits generally arise from mixing of soluble barium-containing fluids with sulfate-rich fluids. While the role of biological processes in modulating barium solubility has been shown, no studies have shown that the biological oxidation of sulfide to sulfate leads to barite deposition. Here we present an example of microbially mediated barite deposition in a continental setting. A spring in the Anadarko Basin of southwestern Oklahoma produces water containing abundant barium and sulfide. As emergent water travels down a stream to a nearby creek, sulfate concentration increases from 0.06 mM to 2.2 mM while Ba²⁺ concentration drops from 0.4 mM to less than 7 μM. Stable isotope analysis, microbial activity studies, and in situ experiments provide evidence that as sulfide-rich water flows down the stream, anaerobic, anoxygenic, phototrophic bacteria play a dominant role in oxidizing sulfide to sulfate. Sulfate then precipitates with Ba²⁺ producing barite as travertine, cements, crusts, and accumulations on microbial mats. Our studies suggest that phototrophic sulfide oxidation and concomitant sulfur cycling could prove to be important processes regulating the cycling of barium in continental sulfur-containing systems.     

Le Viséen supérieur d'Azarhare (Maroc central) : environnements de dépôt,datation et évolution diagénétique

The unexplored area of Azarhare in central Morocco is studied thanks to three sections composed of five lithological facies Main biostratigraphical and sedimentological results concern (1) the identification of Late Visean biozones, with important presence of problematic algae Ungdarella, (2) the regional extension of deposit sequences SD5, SD6 and SD7 previously defined, (3) and an analysis of the diagenetic kaolinite. To cite this article: A. Karim et al., C. R. Geoscience 337 (2005).     

Tensionless–frictionless interaction of flexible annular foundation with a transversely isotropic multi‐layered half‐space

A transversely isotropic multi‐layered half‐space, with axis of material symmetry perpendicular to the free surface, supports a flexible either annular or solid circle foundation. The contact area of the foundation and the half‐space is considered to be both frictionless and tensionless. The foundation is assumed to be affected by a vertical static axisymmetric load. Detailed analysis of the interaction of these two systems with different thickness of layers is the target of this paper. With the use of ring load Green's functions for both the foundation and the continuum half‐space, an integral equation accompanied with some inequalities is introduced to model the complex BVP. With the incorporation of ring‐shape FEM, we are capable of capturing both regular and singular solution smoothly. The validity of the combination of the analytical and numerical method is proved with comparing the results of this paper with a number of benchmark cases of both linear and nonlinear interaction of circular and annular foundation with half‐space. Some new illustrations are presented to portray the aspect of the anisotropy and layering of the half‐space. Copyright © 2014 John Wiley & Sons, Ltd.     

Post‐Variscan exhumation of the Central Anti‐Atlas (Morocco) constrained by zircon and apatite fission‐track thermochronology

The origin of the Anti‐Atlas relief is one of the currently debated issues of Moroccan geology. To constrain the post‐Variscan evolution of the Central Anti‐Atlas, we collected nine samples from the Precambrian basement of the Bou Azzer‐El Graara inlier for zircon and apatite fission‐track thermochronology. Zircon ages cluster between 340 ± 20 and 306 ± 20 Ma, whereas apatite ages range from 171 ± 7 Ma to 133 ± 5 Ma. Zircon ages reflect the thermal effect of the Variscan orogeny (tectonic thickening of the ca. 7 km‐thick Paleozoic series), likely enhanced by fluid advection. Apatite ages record a complex Mesozoic–Cenozoic exhumation history. Track length modelling yields evidence that, (i) the Precambrian basement was still buried at ca. 5 km depth by Permian times, (ii) the Central Anti‐Atlas was subjected to (erosional) exhumation during the Triassic‐Early Cretaceous, then buried beneath ca. 1.5 km‐thick Cretaceous‐Paleogene deposits, (iii) final exhumation took place during the Neogene, contemporaneously with that of the High Atlas.     

Remote sensing and information value (IV) model for regional mapping of fluvial channels and topographic wetness in the Saudi Arabia

This study aims to map regions of near surface fluvial channels, mega-basins and topographic wetness in Saudi Arabia using remote sensing data and an information value (IV) model, which is a modified approach of weight of evidence. We used the new version of the Shuttle Radar Topographic Mission (SRTM) to delineate the fluvial channels, mega-basin, and slope. These hydrological parameters were used to index the topographic wetness of each mega-basin in the region based on IV in a Geographic Information System. We validated our method using the Space Imaging Radar-C and Landsat 8 images and compared the textural features (fluvial channels) evident from SRTM digital elevation model and to determine whether these patterns were different. Our results revealed that the region is drained by nine tributaries and that the Err Rub Al Khali and Sahba mega-basins have the highest value of the IV and topographic wetness values; the Arran and coastal mega-basins have the lowest value of the IV and topographic wetness values. An integrated approach is timely and economically effective and can be applied throughout the arid and semi-arid regions to help hydrologists and urban developers.     

Application of Discriminant Analysis and Support Vector Machine in Mapping Gold Potential Areas for Further Drilling in the Sari-Gunay Gold Deposit,NW Iran

In this contribution, we used discriminant analysis (DA) and support vector machine (SVM) to model subsurface gold mineralization by using a combination of the surface soil geochemical anomalies and earlier bore data for further drilling at the Sari-Gunay gold deposit, NW Iran. Seventy percent of the data were used as the training data and the remaining 30 % were used as the testing data. Sum of the block grades, obtained by kriging, above the cutoff grade (0.5 g/t) was multiplied by the thickness of the blocks and used as productivity index (PI). Then, the PI variable was classified into three classes of background, medium, and high by using fractal method. Four classification functions of SVM and DA methods were calculated by the training soil geochemical data. Also, by using all the geochemical data and classification functions, the general extension of the gold mineralized zones was predicted. The mineral prediction models at the Sari-Gunay hill were used to locate high and moderate potential areas for further infill systematic and reconnaissance drilling, respectively. These models at Agh-Dagh hill and the area between Sari-Gunay and Agh-Dagh hills were used to define the moderate and high potential areas for further reconnaissance drilling. The results showed that the nu-SVM method with 73.8 % accuracy and c-SVM with 72.3 % accuracy worked better than DA methods.     

Analysis of soil nail walls performance - Case study

This study surveys the performance of temporary soil nail walls with a maximum height of 29.3 m in the Yas project, located in Tehran. Some numerical models, with various modelling approaches, were developed using finite element software and the proper modelling approaches were specified and verified.The modelling results were analysed and compared with the in situ monitored data. The results demonstrate the model’s horizontal deformations are generally greater than the in situ monitored values. To decrease the differences between models and monitored results, the effect of variations of the soil parameters had been surveyed and the limits of needed variations were specified.