Actinic flux and photolysis frequency comparison computations using the model PHOTOGT

The accurate radiative transfer model GOMETRAN, initially designed to yield radiances at TOA in the wavelength range 240–790 nm, has been extended to allow for the computation of actinic fluxes down to 175 nm and for the calculation of photolysis frequencies in the atmosphere. The capability of the extended model PHOTOGT (PHOTOGOMETRAN) is demonstrated in a number of successful comparison studies both with recent experiments (ground-based, balloonborne, airborne) and model calculations of radiances, actinic fluxes and photolysis frequencies in the stratosphere and troposphere. In an atmospheric case study, the impact of new quantum yield data for the O₃ » O₂+O(¹ d) photodissociation channel on the photolytic production of O(¹ d) atoms in the lower atmosphere has been quantified.     

Managanese and iron in the White Sea: Sedimentation and diagenesis

Iron and manganese in bottom sediments studied along the sublatitudinal transect from Kandalaksha to Arkhangelsk are characterized by various contents and forms depending on sedimentation environments, grain size of sediments, and diagenetic processes. The latter include redistribution of reactive forms leading to enrichment in Fe and Mn of the surface sediments, formation of films, incrustations, and ferromanganese nodules. Variations in the total Fe content (2–8%) are accompanied by changes in the concentration of its reactive forms (acid extraction) and the concentration of dissolved Fe in the interstitial water (1–14 μM). Variations in the Mn content in sediments (0.03–3.7%) and the interstitial water (up to 500 μM) correspond to a high diagenetic mobility of this element. Changes in the valence of chemical elements results in the redox stratification of sediment strata with maximum concentrations of Fe, Mn, and sulfides. Organic matter of sediments with a considerable terrestrial constituent is oxidized by bottom water oxygen mainly at the sediment surface or in anaerobic conditions within the sediment strata. The role of inorganic components in organic matter oxidation changes from surface sediments, where manganese oxyhydroxide dominates among oxidants, to deeper layers, where sulfate of interstitial water serves as the main oxidant. Differences in river runoff and hydrodynamics are responsible for geochemical asymmetry of the transect. The deep Kandalaksha Bay serves as a sediment trap for manganese (Mn content in sediments varies within 0.5–0.7%), whereas the sedimentary environment in the Dvina Bay promotes its removal from sediments (Mn 0.05%).     

Cloud bottom altitude determination from a satellite

The letter is devoted to the introduction of a new technique to derive the cloud bottom height (CBH) from satellite measurements of the cloud reflectance in the oxygen A-band. The information on the cloud top height needed in the retrieval of the CBH must be obtained from separate measurements to insure small biases in the retrieved CBH. Such measurements can be performed by a space-based lidar.     

Aleksandr Georgievich Rozanov (on his 70th birthday)

Chronicle

Aleksandr Georgievich Rozanov (on his 70th birthday)     

Precambrian-Cambrian boundary: recent state of knowledge

The principle of biostratigraphic delimitation of the type lower boundary of the Cambrian System has become generally accepted, despite a lack of recent results which further support this approach. The detection of the most ancient Vendian Ediacara softbodied forms and Cambrian skeletal fauna in a large number of localities worldwide has been the only obvious trend in recent investigations.The present agreement that the base of the Tommotion Stage is the most satisfactory position for the Precambrian—Cambrian boundary is based on the idea that the best type section of the boundary is to be found in the Siberian platform. Such a decision is based largely on the unsatisfactory nature of the arguments for alternative positions.     

Box and Gaussian plume models of the exhaust composition evolution of subsonic transport aircraft in- and out of the flight corridor

A box and a Gaussian plume model including gas-phase photochemistry and with plume dispersion parameters estimated from the few available plume observations are proposed and used for evaluation of photochemical transformations of exhausts from a single subsonic transport aircraft. The effects of concentration inhomogeneities in the plume cross section on the photochemical sources and sinks in the plume are analyzed for various groups of compounds. The influence of these inhomogeneities on the rate and on the mass of ambient air entrainment into the plume are studied also by comparing the box and the Gaussian plume model simulations during the first hours of their life. Due to the enterance of HO_X and NO_X from ambient air into the plume with rates varying from the wind shear and turbulence conditions, the rate of emitted NOX oxidation in the plume is dependent on these and also on the background concentration levels of HO_X and NO_X.     

Influence of strong sudden stratospheric warmings on ozone in the middle stratosphere according to millimeter wave observations

This paper reports the study data on variations in the ozone content in the middle stratosphere over Moscow based on millimeter wavelength observations during a range of midwinter sudden stratospheric warmings that occurred in the past two decades. The relation of ozone with planetary waves and the intensity of the polar stratospheric vortex has been established. The ozone vertical distribution has been monitored with a highly sensitive spectrometer with a two-millimeter wave band. The discovered phenomena of a relatively long-term lower ozone content in December in the considered cold half-year periods are related to the higher amplitude of the planetary wave with n = 1. Such phenomena preceded the development of strong midwinter stratospheric warmings, which, in turn, were accompanied by a significant increase in the ozone content in January. This ozone enrichment was related to the lower amplitude of the wave with n = 1 and higher amplitude of the wave with n = 2 and was accompanied by geopotential H _c.v. growth in the polar vortex center. Specific features of variations in the ozone content under the influence of the major atmospheric processes are observed not only in certain cold half-year periods but are also well seen in the general averaged pattern for winters with strong stratospheric warmings.     

Studying chemical exchange across the water-bed interface in Golubaya Bay,the Black Sea

The results of first application of automated bottom station for studying chemical exchange across the water-bed interface (IO RAS lander) were obtained for the case of sediments in the northwestern Black Sea near Gelendzhik (Golubaya Bay). The lander is equipped with bottom chambers, sensors of environmental characteristics, and samplers, allowing fluxes of chemical elements through the water-bed interface to be determined directly. Bottom sediments were represented by organogenous silts containing hydrogen sulfide. The high activity of diagenetic processes resulted in a higher consumption of O₂ by sediments (the flux from the bottom water was 130 mM/(m²/day), high fluxes of biogenic elements (P, Si,) and metals (Mn, Fe). At the same time, fluxes across the water-bed interface were evaluated based on the difference between concentrations of these elements in the near-bed and silt water (Fick’s law). The obtained data demonstrate the priority of direct measurements of fluxes (lander) over the calculation method. The first application of the lander suggests the need for methodological improvements both of engineering character and in chemical-analytical support.     

To the problem of stage subdivision of the Lower Cambrian

It was a serious mistake when subdivision stratotypes had been disposed of in practice of constructing the General stratigraphic scale, because they cannot be substituted by the boundary stratotypes. A subdivision stratotype and respective GSSP are complementary parts characterizing any stratigraphic unit. The best candidates for stage stratotypes of the Lower Cambrian are certainly sections of the Lena-Aldan region in the Siberian platform, which have been studied in detail during many years, are well exposed, and contain abundant and diverse fossils, being insignificantly disturbed by tectonic dislocations. Nomenclature, stage and boundary stratotypes of the Siberian standard can be successfully used therefore for stratigraphic subdivision of the Lower Cambrian.