The geochemistry of lead in rivers,estuaries and the continental shelf of the Southeastern United States

Transport by southeastern rivers has insignificant influence on the lead concentration of southeastern shelf waters. If the rate of mobilization and transport of lead by these rivers is representative of uncontaminated fluvial transport during the Pleistocene, only about 5% of the prehistoric output of lead to the North Atlantic can be accounted for by river input.Lead concentrations in southeastern shelf waters are similar to those of North Atlantic Water from the upper 1000 m, which is probably similar to the intrusion source water for the shelf. Atmospheric inputs to the shelf of the same magnitude as observed for the Western North Atlantic are difficult to reconcile given the residence time of shelf waters and their lead concentration unless the rate of loss of lead to shelf sediments is about the same as the atmospheric flux.     

Optimal deflection of NEOs en route of collision with the Earth

Recently, a method for the n-body analysis of the velocity change required to deflect a hazardous near-Earth object (NEO) was presented by Carusi et al. [Carusi, A., Valsecchi, G.B., D'Abramo, G., Boattini A., 2002. Icarus 159, 417-422]. We extent this method in order to optimize the velocity change vector instead of its along-track magnitude. From an application of both methods to a fictitious NEO we find Carusi's parallel approach to be reasonable for phases of unperturbed two-body motion. But, for orbit phases inhering third-body perturbations, i.e., for planetary close approaches or prior to a collision, the results obtained from the new method show the radial component of deflection impulse to play a major role. We show that a fivefold greater efficiency can be achieved by a deflection impulse being non-parallel to orbital velocity. The new method is applied to two possible 99942 Apophis impact trajectories in order to provide constraints for future Apophis deflection mission analysis.     

“Comet‐tail” ejecta streaks: A predicted cratering landform unique to Titan

Abstract— A model for an impact ejecta landform peculiar to Saturn's moon Titan is presented. Expansion of the ejecta plume from moderate‐sized craters is constrained by Titan's thick atmosphere. Much of the plume is collimated along the incoming bolide's trajectory, as was observed for plumes from impacts on Jupiter of P/Shoemaker‐Levy‐9, but is retained as a linear, diagonal ejecta cloud, unlike on Venus where the plume “blows out.” On Titan, the blowout is suppressed because the vertically‐extended atmosphere requires a long wake to reach the vacuum of space, and the modest impact velocities mean plume expansion along the wake is slow enough to allow the wake to close off. Beyond the immediate ejecta blanket around the crater, distal ejecta is released into the atmosphere from an oblique line source: this material is winnowed by the zonal wind field to form streaks, with coarse radar‐bright particles transported less far than fine radar‐dark material. Thus, the ejecta form two distinct streaks faintly reminiscent of dual comet tails, a sharply W‐E radar‐dark one, and a less swept and sometimes comma‐shaped radar‐bright one.     

Initial interpretation of Titan plasma interaction as observed by the Cassini plasma spectrometer: Comparisons with Voyager 1

The Cassini plasma spectrometer (CAPS) instrument made measurements of Titan's plasma environment when the Cassini Orbiter flew through the moon's plasma wake October 26, 2004 (flyby TA). Initial CAPS ion and electron measurements from this encounter will be compared with measurements made by the Voyager 1 plasma science instrument (PLS). The comparisons will be used to evaluate previous interpretations and predictions of the Titan plasma environment that have been made using PLS measurements. The plasma wake trajectories of flyby TA and Voyager 1 are similar because they occurred when Titan was near Saturn's local noon. These similarities make possible direct, meaningful comparisons between the various plasma wake measurements. They lead to the following: (A) The light and heavy ions, H⁺and N⁺/O⁺, were observed by PLS in Saturn's magnetosphere in the vicinity of Titan while the higher mass resolution of CAPS yielded H⁺ and H₂⁺as the light constituents and O⁺/CH₄⁺ as the heavy ions. (B) Finite gyroradius effects were apparent in PLS and CAPS measurements of ambient O⁺ ions as a result of their absorption by Titan's extended atmosphere. (C) The principal pickup ions inferred from both PLS and CAPS measurements are H⁺, H₂⁺, N⁺, CH₄⁺ and N₂⁺. (D) The inference that heavy pickup ions, observed by PLS, were in narrow beam distributions was empirically established by the CAPS measurements. (E) Slowing down of the ambient plasma due to pickup ion mass loading was observed by both instruments on the anti-Saturn side of Titan. (F) Strong mass loading just outside the ionotail by a heavy ion such as N₂⁺ is apparent in PLS and CAPS measurements. (G) Except for the expected differences due to the differing trajectories, the magnitudes and structures of the electron densities and temperatures observed by both instruments are similar. The high-energy electron bite-out observed by PLS in the magnetotail is consistent with that observed by CAPS.     

Relative and absolute ages of individual craters and the rate of infalls on the moon in the post-imbrium period

This paper contains a reasonably successful attempt to determine relative ages and then absolute ages of individual craters younger than Imbrium, and the rate of infalls onto the Moon as a function of time. After the tail of the massive premare bombardment became depleted before 3 aeons (1 aeon = 10⁹ years) ago, there was a period of minimal numbers of infalls. The rate of infalls increased rather steadily from this minimum to the present. The rate in the geologically recent past (0.3 aeon) was about two times that found for the period immediately after the last of the major lave outpourings (3.2 aeons). Absolute ages were determined for large craters (?8 km) from crater counts on the surfaces within and on the rims of the large craters. Key dates were 0 and 0.3 aeon for terrestrial meteoritic craters, 3.2, 3.5, 3.8, and 3.82 aeons for the various mare surfaces according to the determinations of D.E. Wilhelms (1980, Geologic history of the Moon, U.S. Geol. Surv. Prof. Pap.) and 3.85 aeons from the formation of Imbrium.     

Observations on the ecological importance of salt marshes in the Cumberland Basin,a macrotidal estuary in the Bay of Fundy

The Cumberland Basin, a 118 km² estuary at the head of the Bay of Fundy which has an average tidal range of about 11m, contains large tracts of salt marsh (15% of the area below highest high water). Low marsh (below about 0·9 m above mean high water) is composed almost exclusively of Spartina alterniflora while the vegetation on high marsh is more diverse but dominated by Spartina patens. Because of its higher elevation, high marsh is flooded infrequently for short periods by only extreme high tides. Low marsh is inundated much more frequently by water as much as 4m deep for periods as long as 4 h per tide. Temporal variability in the occurrence of extreme tides influences the flooding frequency of high marsh for any given month and year. Using a modification of Smalley's method, the mean annual net aerial primary production (NAPP) of low and high marsh is estimated to be 272 and 172 g C m^?2, respectively. Vegetation turnover times average 1·0 and 2·0 y for low and high marsh, respectively. Because of abundant tidal energy, much of the low marsh production appears to be exported and distributed widely about the estuary. Since high levels of turbidity suppress phytoplankton production, salt marshes produce approximately half of the carbon fixed photosynthetically in the Cumberland Basin. It is concluded that salt marshes play a major ecological role in the Cumberland Basin.     

Coulometric TCO2 analyses for marine studies; an introduction

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.     

Upwelling and river runoff as sources of dissolved nitrous oxide to the Alsea estuary,Oregon

Surface waters of Alsea Bay, an unpolluted estuary on the Oregon coast, were analysed for nitrous oxide, nitrate and nitrite on a weekly or biweekly basis during the summer of 1979. The estuary was found to be a variable source of N₂O to the atmosphere. Large and rapid increases in the concentrations of N₂O, NO₃^?, and NO₂^? occurred at the beginning of the sampling period and are attributed to the influx of nutrient-rich upwelling water into the estuary with the tide. The subsequent decline in concentrations of nitrate, nitrite and nitrous oxide over the remainder of the summer is attributed to a decrease in upwelling intensity, a decline in nitrification rates and to assimilatory nitrate reduction. Measurements of nitrous oxide at six stations along the Alsea River were also made in September and October before and after the onset of the rainy season. Samples taken after flood conditions were established were systematically 50% higher than pre-flood samples. The data suggest that soil runoff results in elevated concentrations of N₂O in rivers.