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K–Ar dating of illitic minerals is commonly used in studies of diagenetic series applied to oil prospecting. In spite of a great number of specialized papers, some problems remain unresolved. These are mostly due to a misunderstanding of the argon accumulation process during illitization. Criteria for identifying detrital–authigenic mineral mixtures, crystal ripening, fast precipitation or continuous nucleation‐growth processes are discussed using K–Ar data available in the literature. Using different parameters, such as Δage (ageK–Ar ? agestrati), Δcryst (diagenetic ageK–Ar ? agestrati) or Δfrac (ageK–Arfraction ?ageK–Arfinest), it is shown that the K–Ar age significance depends on the illite nucleation–growth processes. A ‘diagenetic age’ is obtained when these processes are rapid (the K2O accumulation period is shorter than 2σ). If lower than this value, the K–Ar ratio depends on the proportions of new and old particles, respectively, which are controlled by the relative rates of nucleation, crystal growth and ripening. 相似文献
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High levels of Cd and Zn in Jamaican soils observed in geochemical surveys are related to the presence of phosphorites of possible Late-Miocene or Pliocene age. The trace element and REE geochemistry of the phosphorites, together with SEM studies, indicate a guano origin for the phosphorites. No specific host minerals for Cd could be identified in the fossiliferous phosphorite which is characterized by uniquely high levels of Cd, Zn, Ag, Be, U and Y. However, in the soil Cd is present in lithiophorite and a complex history of pedological development is preserved in the aluminous–goethite present in the soil. The unique guano signature is preserved in the soil despite the fact that guanos themselves have either not been observed or have been destroyed by continuing karst and soil development. The phosphorite geochemical signature can be traced in the data of a 1988 island-wide soil geochemical survey, identifying areas where the Palaeo-environment that supported bird ‘rookeries’ existed in the Late-Miocene or Pliocene. 相似文献
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Patricia Stoffyn-Egli 《Geo-Marine Letters》1987,7(4):223-231
The oldest sediment most recently recovered from the Arctic Ocean is a biosiliceous ooze nearly devoid of nonbiogenic particles and exhibiting small-scale color changes. Color variations are due to changes in iron and manganese content. These elements are probably of local hydrothermal origin, and the Mn precipitation may be bacteria-mediated. An iron silicate phase seems to form at the expense of biogenic silica. The ooze deposited slowly until a sudden sediment input, probably a volcanigenic deposit now weathered to clay minerals, induced dissolution of siliceous microfossils. This clay layer contains calcium phosphate microspheres enriched in rare earth elements. 相似文献
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An analysis of the rotation of coronal holes (CHs) spanning 18 years was done based on data from theCatalogue of Coronal Holes (Sanchez-Ibarra and Barraza-Paredes, 1992). A differential rotation of CHs is confirmed for the totality of CHs, but a different behavior was found when those were separated as equatorial or isolated, and polar hole extensions, such as in theCatalogue. Isolated CHs show a typical differential rotation, but polar hole extensions display two different types of behavior: a rotation rate below 40° ± 5° of heliographic latitude, increasing to the equator, and a rotation rate above the same heliographic latitude but increasing to the poles. Also discussed here is how this last result agrees with other studies that indicate the mostly rigid rotation of the corona at higher latitudes. 相似文献