Groundwater potential assessment in a sedimentary terrain,southwestern Nigeria

Geoelectrical resistivity techniques are increasingly being applied in addressing a wide range of hydrological, environmental, and geotechnical problems. This is due to their effectiveness in near-surface characterization. In the present study, a suite of vertical electrical soundings (VESs) was integrated with 2D geoelectrical resistivity and time-domain induced polarization (IP) imaging to characterize the near-surface and delineate the underlying aquifer in a sedimentary terrain. The geophysical survey was conducted as part of preliminary studies to evaluate the potential of groundwater resource in Iyana-Iyesi and Canaan Land area of Ota, southwestern Nigeria. A high-yield confined sandy aquifer overlain by a low-yield aquitard was delineated; overlying the aquitard is a very resistive and thick layer that is predominantly composed of kaolinitic swelling clay intercalated with phosphate mineral.     

Modeling African equatorial ionosphere using ordinary Kriging interpolation technique for GNSS applications

The ability to model the ionosphere accurately for single frequency users in satellite applications has gained some appreciable usage, most especially during quiet conditions in a mild (middle latitudes) ionosphere. However, solving the problem of ionosphere for single frequency user of Global Navigation Satellite Systems (GNSS) in equatorial ionization anomaly (EIA) region is of a great concern for space scientists and engineers. Several methodologies have been used to develop models that describe global or regional maps for ionosphere errors in order to mitigate the effect of the errors on GNSS systems. Global or regional ionosphere Maps have been known to be an efficient tool to monitor the delay introduced by the ionosphere in the satellite signals. This research uses the conventional Planar fit and ordinary Kriging methodologies to assess a regional map for ionosphere correction in equatorial African sector. The result obtained is an indication that modified Kriging methodology describes the EIA ionosphere corrections better compared with ordinary Kriging and Planar fit methodologies.     

Comparison between IRI-2001 predictions and observed measurements of hmF2 over three high latitude stations during different solar activity periods

The monthly median values of the height of peak electron density of the F2-layer (hmF2) derived from ionosonde measurements at three high latitude stations, namely Narssarssuaq (NAR) (61.2 °N, 314.6 °E), Sondrestrom (SON) (67°N, 309.1°E) and College (COL) (69.9°N, 212.2°E) were analyzed and compared with the International Reference Ionosphere (IRI-2001) model, using Comité Consultatif International des Radio communications) (CCIR and Union Radio-Scientifique Internationale (URSI) options. The analysis covers hmF2 values for March Equinox (February, March, April), June Solstice (May, June, July), September Equinox (August, September, October), and December Solstice (November, December, January), during periods of high (2000–2001), medium (2004–2005) and low (2007–2008) solar activity. Generally, the IRI-2001 prediction follow fairly well the diurnal and seasonal variation patterns of the observed values of hmF2 at all the stations. However, IRI-2001 overestimates and underestimates hmF2 at different times of the day for all solar activity periods and in all the seasons considered. The percentage deviation never exceeded 20%, except during DEC SOLS at COL and SON and during MARCH EQUI at SON during low solar activity period. For all solar activity periods considered, both the URSI and CCIR options of the IRI-2001 model give hmF2 values close to the ones measured, but the URSI option performed better than the CCIR option.     

Comparisons of observed ionospheric F2 peak parameters with IRI-2001 predictions over South Africa

The monthly means of the ionospheric F2 peak parameters (foF2 and hmF2) over three stations in South Africa (Grahamstown, 33.3°S, 26.5°E, Madimbo, 22.4°S, 26.5°E, and Louisvale, 28.5°S, 21.2°E) were analyzed and compared with IRI-2001, using CCIR (Comité Consultatif International des Radio communications) and URSI (Union Radio-Scientifique Internationale coefficients) options. The analysis covers a few selected quiet and disturbed days during various seasons represented by the months of January, April, July and October 2003. IRI-2001 generally overestimates hmF2 for both quiet and disturbed days and it overestimates and underestimates foF2 at different times for all the stations. In general, foF2 is predicted more accurately by IRI-2001 than hmF2, and on average, the CCIR option performed better than the URSI option when predicting both foF2 and hmF2.In general, the model generates good results, although some improvements are still necessary to be implemented in order to obtain better predictions. There are no significant differences in the model predictions of hmF2 and foF2 for quiet and disturbed days.     

Prospect Analysis and Hydrocarbon Reservoir Volume Estimation in an Exploration Field,Shallow Offshore Depobelt,Western Niger Delta,Nigeria

Natural Resources Research - The daunting challenge in the exploration and production of oil and gas in the face of continual rise in the world’s energy consumption has long been how to...     

Modelling blue and green water availability under climate change in the Beninese Basin of the Niger River Basin,West Africa

The aim of this study was to quantify climate change impact on future blue water (BW) and green water (GW) resources as well as the associated uncertainties for 4 subbasins of the Beninese part of the Niger River Basin. The outputs of 3 regional climate models (HIRHAM5, RCSM, and RCA4) under 2 emission scenarios (RCP4.5 and RCP8.5) were downscaled for the historical period (1976–2005) and for the future (2021–2050) using the Statistical DownScaling Model (SDSM). Comparison of climate variables between these 2 periods suggests that rainfall will increase (1.7% to 23.4%) for HIRHAM5 and RCSM under both RCPs but shows mixed trends (?8.5% to 17.3%) for RCA4. Mean temperature will also increase up to 0.48 °C for HIRHAM5 and RCSM but decrease for RCA4 up to ?0.37 °C. Driven by the downscaled climate data, future BW and GW were evaluated with hydrological models validated with streamflow and soil moisture, respectively. The results indicate that GW will increase in all the 4 investigated subbasins, whereas BW will only increase in one subbasin. The overall uncertainty associated with the evaluation of the future BW and GW was quantified through the computation of the interquartile range of the total number of model realizations (combinations of regional climate models and selected hydrological models) for each subbasin. The results show larger uncertainty for the quantification of BW than GW. To cope with the projected decrease in BW that could adversely impact the livelihoods and food security of the local population, recommendations for the development of adequate adaptation strategies are briefly discussed.     

The exceptionally stable cobalt(III)–desferrioxamine B complex

The biogeochemistry of trivalent iron, manganese, and cobalt in the oceans is dominated by soluble complexes formed with high-affinity organic ligands that are believed to be microbial siderophores or similar biogenic chelating agents. Desferrioxamine B (DFOB), a trihydroxamate siderophore found in both terrestrial and marine environments, has served as a useful model for a large class of microbial siderophores in studies of 1:1 complexes formed with trivalent iron and manganese. However, no data exist concerning DFOB complexes with Co(III), which we hypothesize should be as strong as those with Fe(III) and Mn(III) if the current picture of the ocean biogeochemistry of the three trivalent metals is accurate. We investigated the complexation reaction between DFOB and Co(III) in aqueous solution at seawater pH using base and redox titrations, and then characterized the resulting 1:1 complex Co(III)HDFOB⁺ using X-ray absorption, resonance Raman spectroscopy, and quantum mechanical structural optimizations. We found that the complex stability constant for Co(III)HDFOB⁺ (log K _{[Co(III)HDFOB⁺]} = 37.5 ± 0.4) is in fact five and seven orders of magnitude larger than that for Fe(III)HDFOB⁺ (log K_{[Fe(III)HDFOB⁺]} = 32.02) and Mn(III)HDFOB⁺ (log K_{[Mn(III)HDFOB}⁺_] = 29.9), respectively. Spectroscopic data and the supporting theoretical structural optimizations elucidated the molecular basis for this exceptional stability. Although not definitive, our results nevertheless are consistent with the evolution of siderophores as a response by bacteria to oxygenation, not only because of sharply decreasing concentrations of Fe(III), but also of Co(III).