Heavy metal analyses in the marine environment - approaches to quality control

The validity of analyses of elements in the femto- and picomolar ranges in waters and sediments can be assessed on the basis of several criteria: an evaluation of the chemical technique; the use of primary standards and intercalibration exercises; and chemical and geochemical coherence of the results. Herein are reported analyses of ruthenium, platinum, palladium, rhenium, iridium and gold in oceanic samples. The gold concentrations in surface seawaters, at least 25 times less than those previously reported, are in accord with the concentrations of their periodic table neighbors as well as with crustal and sedimentary contents. The remarkable concentration of rhenium in seawater, in relation to its very low crustal abundance, can be explained by the inertness of the perrhenate ion.     

Variability in concentration of suspensates in an estuarine environment

Three data sets of suspensate concentrations, collected under different sampling plans, were analyzed to develop a minimal sampling period, consistent with a predetermined precision. Individual samples collected during any part of a given day were within ±50% of the daily average. In the main channel of the estuary, a monthly sampling scheme closely approximated a weekly pattern; however, seasonal sampling was unsatisfactory. Outside the main channel, weekly, monthly, and seasonal sampling patterns did not differ greatly. Variability in suspensate concentrations must be considered when calculating sediment flux in estuarine and coastal waters.     

Heave compensation and formation strength evaluation from downhole acceleration measurements while coring

In order to evaluate the efficiency of heave compensation in the Ocean Drilling Program, we developed a device measuring the acceleration of the core barrels. First results show that heave compensation limits bit motion to 10% of the surface heave. We also use the acceleration data to characterize the formation. On rotary corers, acceleration amplitudes decrease with increasing hardness of the formation. Comparison with geophysical logs shows that this relationship can resolve cm-scale features. On piston corers, the maximum acceleration is characteristic of the sediment shear strength. Easy and fast to deploy, this tool allows to characterize formations before any sample analysis.     

Io's sodium emission cloud and the voyager 1 encounter

Io's neutral sodium emission cloud was monitored during the period of Voyager 1 encounter from two independent ground-based sites. Observations from Table Mountain Observatory verified the continued existence of the “near-Io cloud” (d < 1.5 × 10⁵ km, for 4πI > 1 kR; R denotes Rayleigh) while those from Wise Observatory showed a deficiency in the weaker emission at greater distances from Io. The sodium cloud has been monitored from both observatories for several years. These and other observations demonstrate that the behavior of the cloud is complex since it undergoes a variety of changes, both systematic and secular, which can have both time and spatial dependencies. The cloud also displays some characteristics of stability. Table Mountain images and high-dispersion spectra (resolution $\text{～0.2}\text{A}\text{?}$) indicate that the basic shape and intensity of the “near cloud” have remained relatively constant at least since imaging observations began in 1976. Wise Observatory low-dispersion spectra (resolution $\text{～1}\text{A}\text{?}$) which have been obtained since 1974 demonstrate substantial variability of the size and intensity of the “far cloud” (d ? 1.5 × 10⁵ km) on a time scale of months or less. Corresponding changes in the state of the plasma associated with the Io torus are suggested, with the period of Voyager 1 encounter represented as a time of unusually high plasma temperature and/or density. Dynamic models of the sodium cloud employing Voyager 1 plasma data provide a reasonable fit to the Table Mountain encounter images. The modeling assumptions of anisotropic ejection of neutral sodium atoms from the leading, inner hemisphere of Io with a velocity distribution characteristic of sputtering adequately explain the overall intensity distribution of the “near cloud”. During the Voyager 1 encounter period there appeared a region of enhanced intensity projecting outward from Io's orbit and inclined to the orbital plane. This region is clearly distinguished from the sodium emission normally aligned with the plane of Io's orbit. The process responsible for this phenomenon is not yet understood. Similar but less pronounced features are also present in several Table Mountain images obtained over the past few years.     

Attenuation differences in layer 2A in intermediate- and slow-spreading oceanic crust

In situ seismic attenuationQ⁻¹logs are derived from borehole velocity profiles and reveal sharp boundaries between morphologies of the extrusive volcanic layers in intermediate- and slow-spreading oceanic crust.Q⁻¹logs are calculated from the scattering attenuation associated with vertical velocity heterogeneity in Ocean Drilling Program Holes 504B and 896A and in Hole 395A, located in 5.9–7.3 Ma crust on the Pacific and Atlantic plates, respectively. Our results strongly tie crustal properties to seismic measurables and observed geological structures: we find that the scattering attenuation can be used to identify the extrusive volcanic sequence because it is closely related to changes in the degree of vertical heterogeneity. We interpret a distinct decrease in the Q⁻¹log at the transition below the extrusive volcanic layer to correspond with the seismic layer 2A/2B boundary. The boundary is located at 465 m depth below the sea floor in both Hole 395A and 504B, although this is likely to be a coincidence of the sediment thickness at these sites. Layer 2A is estimated to be approximately 150 m thick in Hole 504B and > 300 m thick in Hole 395A. Cyclic sequences of high-porosity pillows and low-porosity massive units in the uppermost 100 m of volcanics in Hole 395A result in large velocity heterogeneities which cause > 5 times more attenuation in this layer than in Hole 504B. In Hole 896A, by contrast, fewer pillows, more massive flows, and a greater volume of carbonate veins decrease the velocity heterogeneity and attenuation significantly over only 1 km distance from Hole 504B. We conclude that the attenuation in the extrusive volcanics of the ocean crust is largely controlled by variation in local heterogeneity and morphology as well as by subsequent hydrothermal alteration. The observed differences inQ⁻¹profiles and layer 2A thickness at these sites may be attributed to variations in the volume and duration of volcanic activity at mid-ocean spreading centers for these Pacific and Atlantic ridge segments.     

Student Learning in an Introductory GIS Course: Using a Project‐Based Approach

Introductory courses in Geographic Information Science (GIS) expose students to the concepts and practices necessary for future academic and professional use of GIS tools. Traditional GIS courses balance lectures in the theories of GIS with pre‐built and pre‐packaged lab activities to learn the practices of GIS. This article presents a case study of an experimental introductory course in which students conducted novel, independent project‐based group research under the supervision of graduate or advanced undergraduate students enrolled in the course, culminating in a class presentation and publication quality paper. Surveys and interviews indicated that students reacted more positively to project‐based group research than to traditional activities. Students felt the projects better prepared them for ‘real world’ applications of GIS, and recommend project‐based group research in other GIS coursework. Additionally, our findings indicate that students appreciate interactions with peers of varying skill levels and experiences, as these broaden their capabilities to work with other GIS users.     

A comparison of network model creation algorithms based on the quality of wayfinding results

Various network model creation algorithms have been introduced to demonstrate a better approximation of the actual walking pattern and to provide a better wayfinding guide. However, it is under‐investigated which algorithm creates the most appropriate indoor navigation network model in the context of wayfinding applications. Due to the lack of discussion, some studies unconsciously extended an algorithm designed for creating an outdoor navigation network model to indoor space applications. This is problematic because indoor space has different spatial contexts from outdoor space, such as non‐linear space and no‐designated walking space. Our solution is to select five well‐known algorithms that have been introduced, to reproduce the algorithm for the automated construction of the indoor navigation network model, and to evaluate the applicability of algorithms for indoor wayfinding applications. This article compares the quality of wayfinding results from the output of the indoor navigation network model against two criteria: route efficiency (i.e., length) and route simplicity (i.e., number of directions). Our statistical analysis illustrates that the visibility graph algorithm is the most appropriate for indoor wayfinding applications.     

A probabilistic framework for improving reverse geocoding output

Reverse geocoding, which transforms machine‐readable GPS coordinates into human‐readable location information, is widely used in a variety of location‐based services and analysis. The output quality of reverse geocoding is critical because it can greatly impact these services provided to end‐users. We argue that the output of reverse geocoding should be spatially close to and topologically correct with respect to the input coordinates, contain multiple suggestions ranked by a uniform standard, and incorporate GPS uncertainties. However, existing reverse geocoding systems often fail to fulfill these aims. To further improve the reverse geocoding process, we propose a probabilistic framework that includes: (1) a new workflow that can adapt all existing address models and unitizes distance and topology relations among retrieved reference data for candidate selections; (2) an advanced scoring mechanism that quantifies characteristics of the entire workflow and orders candidates according to their likelihood of being the best candidate; and (3) a novel algorithm that derives statistical surfaces for input GPS uncertainties and propagates such uncertainties into final output lists. The efficiency of the proposed approaches is demonstrated through comparisons to the four commercial reverse geocoding systems and through human judgments. We envision that more advanced reverse geocoding output ranking algorithms specific to different application scenarios can be built upon this work.     

The influence of natural organic matter on the adsorption properties of mineral particles in lake water

The adsorption characteristics of sediment particles from a prealpine Swiss lake were compared with those of γ-aluminum oxide. Under lake water conditions, i.e. with particle concentration of 2–16 mg/1 and DOC concentrations of 1–4 mg/1 at pH=8, the adsorption of copper, zinc and orthophosphate is reduced significantly by the presence of natural organic matter (NOM). It is postulated that the binding sites of the natural mineral surfaces are occupied almost completely by NOM under natural conditions. A simple ligand exchange model can explain the observed phenomena.