Comparison of arsenic concentrations in simultaneously-collected groundwater and aquifer particles from Bangladesh,India, Vietnam,and Nepal

One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.     

Considerations for conducting incubations to study the mechanisms of As release in reducing groundwater aquifers

Microbial Fe reduction is widely believed to be the primary mechanism of As release from aquifer sands in Bangladesh, but alternative explanations have been proposed. Long-term incubation studies using natural aquifer material are one way to address such divergent views. This study addresses two issues related to this approach: (1) the need for suitable abiotic controls and (2) the spatial variability of the composition of aquifer sands. Four sterilization techniques were examined using orange-colored Pleistocene sediment from Bangladesh and artificial groundwater over 8 months. Acetate (10 mM) was added to sacrificial vials before sterilization using either (1) 25 kGy of gamma irradiation, (2) three 1-h autoclave cycles, (3) a single addition of an antibiotic mixture at 1× or (4) 10× the typical dose, and (5) a 10 mM addition of azide. The effectiveness of sterilization was evaluated using two indicators of microbial Fe reduction, changes in diffuse spectral reflectance and leachable Fe(II)/Fe ratios, as well as changes in P-extractable As concentrations in the solid phase. A low dose of antibiotics was ineffective after 70 days, whereas autoclaving significantly altered groundwater composition. Gamma irradiation, a high dose of antibiotics, and azide were effective for the duration of the experiment.     

Development of Tide–Surge Interaction Model for the Coastal Region of Bangladesh

In this paper, a two-dimensional, vertically integrated hydrodynamic model is developed taking into account entrained air bubbles during storm surges as well as incorporating inverted barometer, and river and land dynamics. The model is specifically designed for the coastal region of Bangladesh. A nested scheme method with a fine mesh scheme (FMS), capable of incorporating the complex coastline and all major offshore islands accurately, nested into a coarse mesh scheme (CMS) covering up to 15° N latitude in the Bay of Bengal is used. To incorporate the small and big offshore islands in the Meghna estuarine region with its complex coastline accurately, a very fine mesh scheme (VFMS) is again nested into the FMS. Along the northeast corner of the VFMS, the Meghna river discharge is taken into account. The coastal and island boundaries are approximated through proper stair steps. The model equations are solved by a semi-implicit finite difference technique using a staggered C-grid. A stable appropriate tidal condition over the model domain is generated by applying tidal forcing with the four major tidal constituents M ₂, S ₂, K ₁, and O ₁ along the southern open boundary of the CMS. This tidal regime is introduced as the initial state of the sea for nonlinear interaction of tide and surge. The model is applied to simulate water levels due to the interaction of tide and surge associated with the cyclones April 1991 and Aila at different coastal and island locations along the coast of Bangladesh. The results are found to be quite satisfactory with root mean square error of ～0.50 m as calculated for both the storm events. Tests of sensitivities on water levels are carried out for air bubbles, offshore islands, river discharge, inverse barometer, and grid resolution. The presence of air bubbles increases simulated water levels a little bit in our model, and the contribution of air bubbles in increasing water level is found around 2 %. Further, water levels are found to be influenced by offshore islands, river discharge, inverse barometer as well as grid resolution.     

Dark energy cosmological models with cosmic string

In this paper we have studied the anisotropic Kantowski-Sachs, locally rotationally symmetric (LRS) Bianchi type-I and LRS Bianchi type-III geometries filled with dark energy and one dimensional cosmic string in the Saez-Ballester theory of gravitation. To get physically valid solution we take hybrid expansion law of the average scale factor which is a product of power and exponential type of functions that results in time dependent deceleration parameter (\(q\)). The equation of state parameter of dark energy (\(\omega _{\mathit{de}}\)) has been discussed and we have observed that for the three models it crosses the phantom divide line (\(\omega _{\mathit{de}} = -1\)) and shows quintom like behavior. The density of dark energy (\(\rho _{\mathit{de}}\)) is an increasing function of redshift and remains positive throughout the evolution of the universe for the three models. Moreover in Kantowski-Sachs and LRS Bianchi type-I geometries the dark energy density dominates the string tension density (\(\lambda \)) and proper density (\(\rho \)) throughout the evolution of the universe. The physical and geometrical aspects of the statefinder parameters (\(r,s\)), squared speed of sound (\(v_{s}^{2} \)) and \(\omega _{\mathit{de}}\)–\(\omega ^{\prime }_{\mathit{de}}\) plane are also discussed.     

Flood hazard and risk analysis in the southwest region of Bangladesh

Flood hazard and risk assessment was conducted to identify the priority areas in the southwest region of Bangladesh for flood mitigation. Simulation of flood flow through the Gorai and Arial Khan river system and its floodplains was done by using a hydrodynamic model. After model calibration and verification, the model was used to simulate the flood flow of 100‐year return period for a duration of four months. The maximum flooding depths at different locations in the rivers and floodplains were determined. The process in determining long flooding durations at every grid point in the hydrodynamic model is laborious and time‐consuming. Therefore the flood durations were determined by using satellite images of the observed flood in 1988, which has a return period close to 100 years. Flood hazard assessment was done considering flooding depth and duration. By dividing the study area into smaller land units for hazard assessment, the hazard index and the hazard factor for each land unit for depth and duration of flooding were determined. From the hazard factors of the land units, a flood hazard map, which indicates the locations of different categories of hazard zones, was developed. It was found that 54% of the study area was in the medium hazard zone, 26% in the higher hazard zone and 20% in the lower hazard zone. Due to lack of sufficient flood damage data, flood damage vulnerability is simply considered proportional to population density. The flood risk factor of each land unit was determined as the product of the flood hazard factor and the vulnerability factor. Knowing the flood risk factors for the land units, a flood risk map was developed based on the risk factors. These maps are very useful for the inhabitants and floodplain management authorities to minimize flood damage and loss of human lives. Copyright © 2005 John Wiley & Sons, Ltd.     

Socio-economic drivers of deforestation in Roghani Valley,Hindu-Raj Mountains,Northern Pakistan

Deforestation and associated ecological disturbances are the issues of global concern.Researchers have investigated a number of driving forces which accelerate the rate of deforestation at local and regional levels.These include poverty,population growth,market demand and prices,political instability,agricultural expansion and changes in property right and ownership regimes.This paper seeks to explore the impacts of population growth,changing tenure system and other socioeconomic factors on the forest cover of Roghani Valley,located in Hindu Raj Mountains,Northern Pakistan.The present study is mainly based on information collected through participatory observation,selfadministered interviews and questionnaire survey.Geographical Information System（GIS） database is also used for mapping and quantification.The results reveal that in the past three to four decades the study area has been subjected to severe deforestation and about half of the forest area has been converted into barren land.Thus,the area under natural forests decreased from 2099 to 1444 hectares in four decades.This large-scale deforestation is attributed to both proximate and under lying causes particularly traditional land tenure system and demographic development.Consequently,forest resources have been degraded and a number of plant species have disappeared from the forests of the study area while several others are in the process of disappearance.     

Holistic approach of GIS based Multi-Criteria Decision Analysis (MCDA) and WetSpass models to evaluate groundwater potential in Gelana watershed of Ethiopia

Appropriate quantification and identification of the groundwater distribution in a hydrological basin may provide necessary information for effective management, planning and development of groundwater resources. Groundwater potential assessment and delineation in a highly heterogeneous environment with limited Spatiotemporal data derived from Gelana watershed of Abaya Chamo lake basin is performed, using integrated multi-criteria decision analysis (MCDA), water and energy transfer between soil and plant and atmosphere under quasi-steady state (WetSpass) models. The outputs of the WetSpass model reveal a favorable structure of water balance in the basin studied, mainly using surface runoff. The simulated total flow and groundwater recharge are validated using river measurements and estimated baseflow at two gauging stations located in the study area, which yields a good agreement. The WetSpass model effectively integrates a water balance assessment in a geographical information system (GIS) environment. The WetSpass model is shown to be computationally reputable for such a remote complex setting as the African rift, with a correlation coefficient of 0.99 and 0.99 for total flow and baseflow at a significant level of p-value<0.05, respectively. The simulated annual water budget reveals that 77.22% of annual precipitation loses through evapotranspiration, of which 16.54% is lost via surface runoff while 6.24% is recharged to the groundwater. The calibrated groundwater recharge from the WetSpass model is then considered when determining the controlling factors of groundwater occurrence and formation, together with other multi-thematic layers such as lithology, geomorphology, lineament density and drainage density. The selected five thematic layers through MCDA are incorporated by employing the analytical hierarchy process (AHP) method to identify the relative dominance in groundwater potential zoning. The weighted factors in the AHP are procedurally aggregated, based on weighted linear combinations to provide the groundwater potential index. Based on the potential indexes, the area then is demarcated into low, moderate, and high groundwater potential zones (GWPZ). The identified GWPZs are finally examined using the existing groundwater inventory data (static water level and springs) in the region. About 70.7% of groundwater inventory points are coinciding with the delineated GWPZs. The weighting comparison shows that lithology, geomorphology, and groundwater recharge appear to be the dominant factors influence on the resources potential. The assessment of groundwater potential index values identify 45.88% as high, 39.38% moderate, and 14.73% as low groundwater potential zones. WetSpass model analysis is more preferable in the area like Gelana watershed when the topography is rugged, inaccessible and having limited gauging stations.