The reliability of analytical data for tributyltin (TBT) in sea water and its implications on water quality criteria

To investigate the reliability of analytical data for tributyltin (TBT) in sea water, split water samples were distributed to ten laboratories in six countries. The sub-surface samples comprised: (i) an offshore (0·5 km) water sample, (ii) the same sample but spiked with an undisclosed quantity of TBT standard compound (175 ng TBT⁺ liter⁻¹), and (iii) a sample taken from a yacht marina. The seven acceptable data sets were in good agreement for the spiked sample (178 ± 26 ng TBT⁺ liter⁻¹) but showed a greater variation in concentrations reported for the yacht marina sample (366 ± 93 ng TBT⁺ liter⁻¹). Atomic absorption and gas chromatographic-flame photometric detection techniques produced results of similar accuracy and precision. Samples acidified with 1 ml of 10% (v/v) acetic acid appeared stable for more than 2 weeks when stored refrigerated and in darkness. Analyses of the offshore seawater sample revealed TBT contamination (9 ± 7 ng TBT⁺ liter⁻¹) indicating dispersion of the compound to the shelf waters off Monaco. The spread in values reported by the laboratories demonstrates inherent difficulties in obtaining good precision below approximately 20 ng TBT⁺ liter⁻¹. This observation is discussed with respect to the setting and enforcing of water quality standards.     

Vertical structure of the field of current velocities in the northwest part of the Black Sea based on the <Emphasis Type="Italic">LADCP</Emphasis> data for May 2004

The profiles of absolute current velocity obtained by using a lowered acoustic doppler current profiler (LADCP) are presented. In the course of the BSERP-3 expedition, the measurements were carried out in the regions of the Rim Current, anticyclonic eddy, and northwest shelf. In the core of the Rim Current, a unidirectional motion of waters is traced in layers below the main pycnocline down to depths greater than 500 m. Its characteristic velocity can be as high as 0.08 m/sec. It is shown that the direct action of the eddy is detected in the shelf region at distances larger than 20 km from the outer edge of the shelf in the zone bounded by an isobath of 100 m. The formation of multilayer vertical structures in the field of current velocities is revealed in the region of interaction of the anticyclonic eddy with irregularities of the bottom on the side of the shelf. A two-layer structure of currents with specific features in the layer of formed seasonal pycnocline is observed in the region of the shelf down to an isobath of 100 m. The profiles of the moduli of vertical shears of currents averaged over the casts ensemble are presented for the abyssal and shelf parts of the sea. It is shown that the shears induced by the geostrophic currents and wave processes in the region of the main pycnocline are comparable. Below the pycnocline, the shears are mainly determined by the wave processes. Translated from Morskoi Gidrofizicheskii Zhurnal, No. 6, pp. 25–37, November–December, 2008.     

Phytoplankton production and seasonal biomass variation of seagrass,Ruppia maritima L., in a tropical Mexican lagoon with an ephemeral inlet

Plankton metabolism andRuppia maritima biomass were measured seasonally during 1982–83 in El Verde Lagoon, a small coastal lagoon with an ephemeral inlet on the Pacific Coast of Mexico. Total net aquatic primary production was 521 g C m^?2 y^?1. The water column was slightly heterotrophic, with an annual P/R ratio of 0.89. Our analysis indicates that tropical and subtropical coastal lagoons with restricted or seasonal inlets have generally higher net aquatic primary productivity levels than lagoons with permanently open inlets. We hypothesize that this is due to retention of nutrients and plankton stocks during the dry season. The seasonal pattern of water column metabolism was related to rainfall and riverflow, with higher values generally occurring during the wet season. Net production and respiration were about three times lower during the 1982 dry season as compared to the 1983 dry season which received considerable rains due to abnormal climatic conditions. The biomass ofR. maritima ranged from zero to 620 g dry wt m^?2. Growth occurred only during the dry season and there were two distinct biomass peaks representing two separate crops. The second crop was heavily epiphytized with nitrogen-fixing algae. There was an apparent succession in dominance of water column productivity over the year, withRuppia dominating during the dry season and phytoplankton more important during the wet season.     

Early Proterozoic,basaltic andesite tuff-breaccia: downslope,subaqueous mass transport of phreatomagmatically-generated tephra

At Bear Lake, in the Flin Flon-Snow Lake greenstone belt of Manitoba, 400⁺ m of thick-to very thick-bedded, generally ungraded, basaltic andesite tuff-breccia, breccia, and lapilli-tuff are intercalated with pillowed lava flows in the upper part of an early Proterozoic submarine basaltic andesite shield volcano. The fragmental rocks comprise angular, amygdaloidal blocks and lapilli, many with partial chilled selvages, in a matrix of blocky, non-amygdaloidal to highly amygdaloidal vitric basaltic andesite ash and small lapilli. Minor thin-to medium-bedded, commonly normally graded tuff occurs in the upper part of the sequence. Clasts in fragmental beds consistently have higher amygdule contents than intercalated lava flows. Although similar to pillow-fragment breccias, the Bear Lake fragmental rocks were produced by extended surtseyan-type, phreatomagmatic eruptions, with associated fire fountain activity, at a progressively subsiding, shallow water vent. Periodic tephra slumping generated debris flows that transported particles down the uppe, gentle slope of the volcano to a depositional site at a water depth of less than 1 km. Turbidity currents probably carried much fine tephra to deeper water; tuff was deposited in the preserved section only after explosive volcanism ceased.     

Creating a global warming implementation regime

This paper proposes a global warming implementation regime which addresses the issues of equity, flexibility, cost minimization, and population growth. Previously proposed international policy instruments, such as country by country targets, carbon taxes, and tradable permits, face major difficulties as stand alone proposals. The key element of the regime proposed here is to combine annual tradable permits which are allocated based on population in a fixed year with a small carbon tax ($5–10/tonne) on emissions in excess of permits. Both permits and carbon taxes are applied to national level governments, which in turn would use whatever mix of policies desired to reduce national emissions. It is suggested that the initial number of permits correspond to total global emissions in the base year; over time, the number of permits could be reduced and the tax rate increased if improved scientific knowledge so dictates. By allocating permits based on population the equity concerns of developing countries are addressed, while taxing emissions in excess of permit holdings removes the rigidity of a quota system and limits resource transfers by effectively capping the permit trading price, which is a major concern of industrialized countries. To accommodate the difficulties of countries which have not yet achieved the demographic transition, the permit allocation scheme could be subject to a one-time adjustment after 10–15 years based on some weighting of the initial and then-current populations. The proposed scheme is based on the premise that there is a large potential for reducing emissions in developed countries or limiting emission increases in developing countries, and the intention is to create competition between national level governments in implementing cost-effective emission reduction.     

Simulation of the extreme waves generated by typhoon Bolaven (1215) in the East China Sea and Yellow Sea

Record-breaking high waves occurred during the passage of the typhoon Bolaven (1215) (TYB) in the East China Sea (ECS) and Yellow Sea (YS) although its intensity did not reach the level of a super typhoon. Winds and directional wave measurements were made using a range of in-situ instruments mounted on an ocean tower and buoys. In order to understand how such high waves with long duration occurred, analyses have been made through measurement and numerical simulations. TYB winds were generated using the TC96 typhoon wind model with the best track data calibrated with the measurements. And then the wind fields were blended with the reanalyzed synoptic-scale wind fields for a wave model. Wave fields were simulated using WAM4.5 with adjustment of C_d for gust of winds and bottom friction for the study area. Thus the accuracy of simulations is considerably enhanced, and the computed results are also in better agreement with measured data than before. It is found that the extremely high waves evolved as a result of the superposition of distant large swells and high wind seas generated by strong winds from the front/right quadrant of the typhoon track. As the typhoon moved at a speed a little slower than the dominant wave group velocity in a consistent direction for two days, the wave growth was significantly enhanced by strong wind input in an extended fetch and non-linear interaction.     

Diet and gill morphology of the East Coast redeye round herring Etrumeus wongratanai off KwaZulu-Natal,South Africa

Stomach content analyses and measurements of gillraker morphology were used to assess the diet and feeding ecology of the East Coast redeye round herring Etrumeus wongratanai and provide data for comparisons with other small pelagic fishes off South Africa. Samples were collected by jigging from a kayak off Scottburgh, KwaZulu-Natal (KZN), over the period July 2013–May 2014. In total, 66 stomachs (containing 4 407 prey items) and 66 gill arches were examined. Stomach content analyses indicated that East Coast redeye round herring, at the time of sampling, fed on large (1 500–2 500?µm) particles, with ～2 500?µm particles making the greatest contribution to dietary carbon. The species feeds on larger particles than do anchovy Engraulis encrasicolus and sardine Sardinops sagax, but on particles of a similar size to those consumed by West Coast redeye round herring Etrumeus whiteheadi. There were significant differences in mean gillraker gaps between East Coast redeye round herring and both sardine and anchovy, but not between East Coast and West Coast redeye round herring. The differences in gillraker gaps between East Coast redeye round herring, sardine and anchovy are indicative of resource partitioning through differential feeding, based on zooplankton size. The data suggest that there is no resource partitioning between East and West coast redeye round herring, indicating that competition is likely to occur between them. However, such competition is minimised by limited spatial overlap between these two species.     

Effect of doubling the ensemble size on the performance of ensemble prediction in the warm season using MOGREPS implemented at the KMA

Using the Met Office Global and Regional Ensemble Prediction System (MOGREPS) implemented at the Korea Meteorological Administration (KMA), the effect of doubling the ensemble size on the performance of ensemble prediction in the warm season was evaluated. Because a finite ensemble size causes sampling error in the full forecast probability distribution function (PDF), ensemble size is closely related to the efficiency of the ensemble prediction system. Prediction capability according to doubling the ensemble size was evaluated by increasing the number of ensembles from 24 to 48 in MOGREPS implemented at the KMA. The initial analysis perturbations generated by the Ensemble Transform Kalman Filter (ETKF) were integrated for 10 days from 22 May to 23 June 2009. Several statistical verification scores were used to measure the accuracy, reliability, and resolution of ensemble probabilistic forecasts for 24 and 48 ensemble member forecasts. Even though the results were not significant, the accuracy of ensemble prediction improved slightly as ensemble size increased, especially for longer forecast times in the Northern Hemisphere. While increasing the number of ensemble members resulted in a slight improvement in resolution as forecast time increased, inconsistent results were obtained for the scores assessing the reliability of ensemble prediction. The overall performance of ensemble prediction in terms of accuracy, resolution, and reliability increased slightly with ensemble size, especially for longer forecast times.     

Mass physical properties, sliding and erodibility of experimentally deposited and differently consolidated clayey muds (Approach, equipment, and first results)

On experimentally deposited kaolinite, illite, and Ca-bentonite consolidated under their own load or by additional vertical pressure, the progress of compaction in relation to excess pore water pressure, mass physical properties, gravitational mass movements in a tilted tank, and erodibility under running water in a flume were studied. The very low consolidated sediments near the mud/water interface do not obey the generally used theory in soil mechanics. They show a different, non-linear relationship between void ratio or water content and depth below the sedimentary surface on the one hand, or effective overburden pressure and shear strength on the other. The same is true of other physical properties such as permeability, which changes considerably with depth and time of consolidation. High sedimentation rates on slopes induce shallow sediment flow, whereas at low rates and critical slope angles different types of slope failures including the breaking up of water-rich sediment into sharp boundered blocks are observed. Flume studies on soft clay muds show three different types of erosion: continuously suspending, discontinuous erosion of crumbs or shreds, and wavy deformation of the clay surface with disintegration of particles from the crests. The critical tractive stress depends not only on clay type, void ratio, and shear strength, but significantly also on the ‘geologic history’of the clay (i.e. deposition from thin suspension or dense slurry, fabric, consolidation and swelling generating minute inhomogeneities etc.). The experiments may lead to a better understanding of all mechanical processe's including pore-water flow taking place near or not far below the sediment/ water interface.     

Characteristics of adjoint sensitivity to potential vorticity

Structures of adjoint sensitivities to potential vorticity for specific initial and final norm are investigated for a short-range cyclone forecast in a three-dimensional quasigeostrophic (QG) model. Moreover, adjoint sensitivities to potential vorticity are compared with nonlinear sensitivities calculated for the same cyclogenesis case in the QG model. The adjoint sensitivities using different initial and final norms (e.g., total QG disturbance energy and potential enstrophy) show approximately similar characteristics for the horizontal and vertical structures and evolutions. Consistent with previous studies, the horizontal structure of the adjoint sensitivity is smaller for the energy norm than for the potential enstrophy norm. The dynamical mechanism of cyclone development by adjoint sensitivity coincides with that of nonlinear sensitivity, with slight differences in the region of sensitivity maxima over the upstream (nascent) low for the adjoint (nonlinear) sensitivity. The adjoint sensitivities show different vertical distributions from the nonlinear sensitivities. Consistent with the sensitive regions denoted by singular vectors and error evolution in the QG model, maxima of the adjoint sensitivities are located at both the upper and lower boundaries, with prominent secondary peaks in the lower to mid-troposphere of the domain. The level of the secondary maxima changes depending on the initial and final norm used. The secondary peak is located in the lower to mid- (mid-) troposphere for the total QG disturbance energy (potential enstrophy) as the initial and final norm. Based on the correspondence in the level of the sensitivity maxima in the interior of the domain between the adjoint and nonlinear sensitivities, adjoint sensitivities may serve as an alternative to nonlinear sensitivities given the enormous computing expenses in nonlinear sensitivity calculation.