We evaluated levels of serotonin (5HT) and dopamine (DOPA) in muscle and digestive glands of the mussel, Perna perna, collected at different times of day; exposed to air for 24 h, followed by re-submersion; and after exposure to different metals. Mussels collected at different periods of day showed little oscillation in 5HT and DOPA levels. Mussels exposed to metals showed significant changes in 5HT and DOPA levels in digestive gland and muscle, as did mussels exposed to air. Our data suggest that analyses of 5HT and DOPA in tissues of mussels could serve as a tool to evaluate the presence and effects of heavy metal contamination in mussels. Care in data interpretation is required, however, since other environmental factors such as exposure of mussels to air (i.e. at low tides) can also cause changes in DOPA and 5HT levels. Additional research is necessary to separate such natural environmental effects from effects of contaminants. 相似文献
This work aimed to evaluate, in vitro, the capability of roots of two salt marsh plants to release low molecular weight organic acids (LMWOAs) and to ascertain whether Cu contamination would stimulate or not organic acids exudation. The sea rush Juncus maritimus and the sea-club rush Scirpus maritimus, both from the lower Douro river estuary (NW Portugal), were used. Plants were collected seasonally, four times a year in 2004, during low tide. After sampling, plant roots were washed for removal of adherent particles and immersed for 2 h in a solution that matched salinity (3) and pH (7.5) of the pore water from the same location to obtain plant exudates. In one of the seasons, similar experiments were carried out but spiking the solution with different amounts of Cu in order to embrace the range between 0 and 1600 nM. In the final solutions as well as in sediment pore water LMWOAs were determined by high performance liquid chromatography. Plants were able to release, in a short period of time, relatively high amounts of LMWOAs (oxalate, citrate, malate, malonate, and succinate). In the sediment pore water oxalate, succinate and acetate were also detected. Therefore, plant roots probably contributed to the presence of some of these organic compounds in pore water. Exudation differed between the plant species and also showed some seasonally variation, particularly for S. maritimus. The release of oxalate by J. maritimus increased with Cu increase in the media. However, exudation of the other LMWOAs did not seem to be stimulated by Cu contamination in the media. This fact is compatible with the existence of alternative internal mechanisms for Cu detoxification, as denoted by the fact that in media contaminated with Cu both plant species accumulated relatively high amounts (29–83%) of the initially dissolved Cu. This study expands our knowledge on the contribution of globally dominant salt marsh plants to the release of LMWOAs into the environment. 相似文献
Heat and bromide were compared as tracers for examining stream/ground water exchanges along the middle reaches of the Santa Clara River, California, during a 10-hour surface water sodium bromide injection test. Three cross sections that comprise six shallow (<1 m) piezometers were installed at the upper, middle, and lower sections of a 17 km long study reach, to monitor temperatures and bromide concentrations in the shallow ground water beneath the stream. A heat and ground water transport simulation model and a closely related solute and ground water transport simulation model were matched up for comparison of simulated and observed temperatures and bromide concentrations in the streambed. Vertical, one-dimensional simulations of sediment temperature were fitted to observed temperature results, to yield apparent streambed hydraulic conductivities in each cross section. The temperature-based hydraulic conductivities were assigned to a solute and ground water transport model to predict sediment bromide concentrations, during the sodium bromide injection test. Vertical, one-dimensional simulations of bromide concentrations in the sediments yielded a good match to the observed bromide concentrations, without adjustment of any model parameters except solute dispersivities. This indicates that, for the spatial and temporal scales examined on the Santa Clara River, the use of heat and bromide as tracers provide comparable information with respect to apparent hydraulic conductivities and fluxes for sediments near streams. In other settings, caution should be used due to differences in the nature of conservative (bromide) versus nonconservative (heat) tracers, particularly when preferential flowpaths are present. 相似文献
An applied Fourier transform computation for the hydrodynamic wave-resistance coefficient is shown, oriented to potential flows with a free surface and infinity depth. The presence of a ship-like body is simulated by its equivalent pressure disturbance imposed on the un-perturbed free surface, where a linearized free surface condition is used. The wave-resistance coefficient is obtained from the wave-height downstream. Two examples with closed solutions are considered: a submerged dipole, as a test-case, and a parabolic pressure distribution of compact support. In the three dimensional case, a dispersion relation is included which is a key resource for an inexpensive computation of the wave pattern far downstream like fifteen ship-lengths. 相似文献
The application of Principal Component and Discriminant analysis to the major and minor oxides of recent volcanics from the Central Andes (S-Peru, N-Chile, Bolivia and Argentina) illustrates a variation in chemical composition related to geographical distribution, mainly in terms of TiO2 and K2O. A relationship between chemistry and distance from the Peru-Chile trench, dependent on P, Ti and Sr content of some cenozoic lavas from Southern Peru is also illustrated, by means of Multilinear Standardized Regressions and Partial Correlation analysis.
Zusammenfassung Die Anwendung zweier statistischer Methoden (Principal Component und Discriminant Analysis) zur Erfassung der Oxidverteilung in den rezenten Vulkaniten der zentralen Anden (S-Peru, N-Chile, Bolivien und Argentinien) hat gezeigt, daß die Variation der chemischen Zusammensetzung, hauptsächlich bei TiO2 und K2O, abhängig von der geographischen Position der Ausbruchzentren ist.Eine Beziehung zwischen Geochemie und Entfernung vom Peru-Chile Tief-Seegraben für die rezenten Laven in S-Peru wird ferner mit multilinearen standardisierten Regressionen und Korrelationsanalysen, mit Schwerpunkt bei den Elementen P, Ti und Sr, aufgezeigt.
Resume L'application de deux méthodes statistiques multivariées (Principal Component et Discriminant Analysis) à la distribution des éléments majeurs et mineurs dans les roches volcaniques récentes des Andes centrales (S-Pérou, N-Chili, Bolivie et Argentine) montre une variation de la composition chimique en fonction de la distribution géographique, surtout en ce qui concerne TiO2 et K2O.Une relation entre la variation de composition chimique de quelques laves récentes du Pérou du Sud et la distance du fossé océanique du Pérou-Chili est aussi montrée, à l'aide des Regressions Multilinéaires Standardisées et de l'Analyse de Corrélation partielle. Cette relation concerne spécialment les teneurs en P, Ti et Sr des laves étudiées.
— Principal Component, Discriminant Analysis ( , , ) , . . . iO2, K2, . - . T Sr
Changes in magmatic assemblages and crystal stability as a response of CO2-flushing in basaltic systems have rarely been directly addressed experimentally, making the role of CO2 in magma dynamics still controversial and object of scientific debate. We conducted a series of experiments to understand the response of magmas from Etna volcano to CO2 flushing. We performed a first experiment at 300 MPa to synthesize a starting material composed of crystals of some hundreds of µm and melt pools. This material is representative of an initial magmatic assemblage composed of plagioclase, clinopyroxene and a water-undersaturated melt with 1.6 wt% H2O. In a second step, the initial assemblage was equilibrated at 300 and 100 MPa with fluids having different XCO2fl (CO2/(H2O + CO2)). At low XCO2fl (< 0.2 to 0.4), plagioclase is completely dissolved and clinopyroxene show dissolution textures. For relatively high XCO2fl (0.9 at 300 MPa), the flushing of a CO2-rich fluid phase leads to an increase of the amount of clinopyroxene and a decrease of the abundance of plagioclase at 300 MPa. This decrease of plagioclase proportion is associated with a change in An content. Our experiments demonstrate that flushing basaltic systems with fluids may drastically affect crystal textures and phase equilibria depending on proportions of H2O and CO2 in the fluid phase. Since texture and crystal proportions are among the most important parameters governing the rheology of magmas, fluid flushing will also influence magma ascent to the Earth’s surface. The experimental results open new perspectives to decipher the textural and compositional record of minerals observed in volcanic rocks from Mt. Etna, and at the same time offer the basis for interpreting the information preserved in minerals from other basaltic volcanoes erupting magmas enriched in CO2. 相似文献
Coastal regions are dynamic areas that often lie at the junction of different natural hazards. Extreme events such as storm surges and high precipitation are significant sources of concern for flood management. As climatic changes and sea-level rise put further pressure on these vulnerable systems, there is a need for a better understanding of the implications of compounding hazards. Recent computational advances in hydraulic modelling offer new opportunities to support decision-making and adaptation. Our research makes use of recently released features in the HEC-RAS version 5.0 software to develop an integrated 1D–2D hydrodynamic model. Using extreme value analysis with the Peaks-Over-Threshold method to define extreme scenarios, the model was applied to the eastern coast of the UK. The sensitivity of the protected wetland known as the Broads to a combination of fluvial, tidal and coastal sources of flooding was assessed, accounting for different rates of twenty-first century sea-level rise up to the year 2100. The 1D–2D approach led to a more detailed representation of inundation in coastal urban areas, while allowing for interactions with more fluvially dominated inland areas to be captured. While flooding was primarily driven by increased sea levels, combined events exacerbated flooded area by 5–40% and average depth by 10–32%, affecting different locations depending on the scenario. The results emphasise the importance of catchment-scale strategies that account for potentially interacting sources of flooding.
The dynamics of the North Atlantic subpolar gyre (SPG) are assessed under present and glacial boundary conditions by investigating the SPG sensitivity to surface wind-stress changes in a coupled climate model. To this end, the gyre transport is decomposed in Ekman, thermohaline, and bottom transports. Surface wind-stress variations are found to play an important indirect role in SPG dynamics through their effect on water-mass densities. Our results suggest the existence of two dynamically distinct regimes of the SPG, depending on the absence or presence of deep water formation (DWF) in the Nordic Seas and a vigorous Greenland?CScotland ridge (GSR) overflow. In the first regime, the GSR overflow is weak and the SPG strength increases with wind-stress as a result of enhanced outcropping of isopycnals in the centre of the SPG. As soon as a vigorous GSR overflow is established, its associated positive density anomalies on the southern GSR slope reduce the SPG strength. This has implications for past glacial abrupt climate changes, insofar as these can be explained through latitudinal shifts in North Atlantic DWF sites and strengthening of the North Atlantic current. Regardless of the ultimate trigger, an abrupt shift of DWF into the Nordic Seas could result both in a drastic reduction of the SPG strength and a sudden reversal in its sensitivity to wind-stress variations. Our results could provide insight into changes in the horizontal ocean circulation during abrupt glacial climate changes, which have been largely neglected up to now in model studies. 相似文献