Interplay between erosion and tectonics in the Western Alps

Bedrock fission‐track analysis, high‐resolution petrography and heavy mineral analyses of sediments are used to investigate the relationships between erosion and tectonics in the Western Alps. Along the Aosta Valley cross‐section, exhumation rates based on fission‐track data are higher in the fault‐bounded western block than in the eastern block (0.4–1.5 vs. 0.1–0.3 mm yr⁻¹). Erosion rates based on the analysis of bed‐load in the Dora Baltea drainage display the same pattern and have similar magnitudes in the relative sub‐basins (0.4–0.7 vs. 0.04–0.08 mm yr⁻¹). Results highlight that climate, relief and lithology are not the controlling factors of erosion in the Western Alps. The main driving force behind erosion is instead tectonics that causes the differential upward motion of crustal blocks.     

Risk assessment strategies for the reactivation of earth flows in the Northern Apennines (Italy)

The aim of this paper is to analyze the reactivation mechanism of ancient earth flows, with a view to gleaning information that can subsequently be utilized to formulate a risk-reduction strategy. All considerations made herein are the result of direct experience and observation of actual events which have occurred over the past few decades in the Northern Apennines. Particular attention has been paid to the analysis of the evolution of landslides during actual reactivation, acknowledging a typical, recurring succession of events that precede the failure of the slope. The hazard assessment of these large landslide bodies, which are of slope scale, constitutes a thorny problem, especially in view of the inapplicability of traditional deterministic models such as limit equilibrium stability analysis. Nevertheless, a site-specific assessment of probability of reactivation of these large and ancient earth flows is fundamental to effective land-use planning.     

Impacts of Present and Future Climate Variability on Agriculture and Forestry in the Temperate Regions: Europe

Agriculture and forestry will be particularly sensitive to changes in mean climate and climate variability in the northern and southern regions of Europe. Agriculture may be positively affected by climate change in the northern areas through the introduction of new crop species and varieties, higher crop production and expansion of suitable areas for crop cultivation. The disadvantages may be determined by an increase in need for plant protection, risk of nutrient leaching and accelerated breakdown of soil organic matter. In the southern areas the benefits of the projected climate change will be limited, while the disadvantages will be predominant. The increased water use efficiency caused by increasing CO₂ will compensate for some of the negative effects of increasing water limitation and extreme weather events, but lower harvestable yields, higher yield variability and reduction in suitable areas of traditional crops are expected for these areas. Forestry in the Mediterranean region may be mainly affected by increases in drought and forest fires. In northern Europe, the increased precipitation is expected to be large enough to compensate for the increased evapotranspiration. On the other hand, however, increased precipitation, cloudiness and rain days and the reduced duration of snow cover and soil frost may negatively affect forest work and timber logging determining lower profitability of forest production and a decrease in recreational possibilities. Adaptation management strategies should be introduced, as effective tools, to reduce the negative impacts of climate change on agricultural and forestry sectors.     

Prediction of river water temperature: a comparison between a new family of hybrid models and statistical approaches

River water temperature is a key physical variable controlling several chemical, biological and ecological processes. Its reliable prediction is a main issue in many environmental applications, which however is hampered by data scarcity, when using data‐demanding deterministic models, and modelling limitations, when using simpler statistical models. In this work we test a suite of models belonging to air2stream family, which are characterized by a hybrid formulation that combines a physical derivation of the key equation with a stochastic calibration of parameters. The air2stream models rely solely on air temperature and streamflow, and are of similar complexity as standard statistical models. The performances of the different versions of air2stream in predicting river water temperature are compared with those of the most common statistical models typically used in the literature. To this aim, a dataset of 38 Swiss rivers is used, which includes rivers classified into four different categories according to their hydrological characteristics: low‐land natural rivers, lake outlets, snow‐fed rivers and regulated rivers. The results of the analysis provide practical indications regarding the type of model that is most suitable to simulate river water temperature across different time scales (from daily to seasonal) and for different hydrological regimes. A model intercomparison exercise suggests that the family of air2stream hybrid models generally outperforms statistical models, while cross‐validation conducted over a 30‐year period indicates that they can be suitably adopted for long‐term analyses. Copyright © 2016 John Wiley & Sons, Ltd.     

The variability of ruthenium in chromite from chassignite and olivine‐phyric shergottite meteorites: New insights into the behavior of PGE and sulfur in Martian magmatic systems

The Martian meteorites comprise mantle‐derived mafic to ultramafic rocks that formed in shallow intrusions and/or lava flows. This study reports the first in situ platinum‐group element data on chromite and ulvöspinel from a series of dunitic chassignites and olivine‐phyric shergottites, determined using laser‐ablation ICP‐MS. As recent studies have shown that Ru has strongly contrasting affinities for coexisting sulfide and spinel phases, the precise in situ analysis of this element in spinel can provide important insights into the sulfide saturation history of Martian mantle‐derived melts. The new data reveal distinctive differences between the two meteorite groups. Chromite from the chassignites Northwest Africa 2737 (NWA 2737) and Chassigny contained detectable concentrations of Ru (up to ~160 ppb Ru) in solid solution, whereas chromite and ulvöspinel from the olivine‐phyric shergottites Yamato‐980459 (Y‐980459), Tissint, and Dhofar 019 displayed Ru concentrations consistently below detection limit (<42 ppb). The relatively elevated Ru signatures of chromite from the chassignites suggest a Ru‐rich (~1–4 ppb) parental melt for this meteorite group, which presumably did not experience segregation of immiscible sulfide liquids over the interval of mantle melting, melt ascent, and chromite crystallization. The relatively Ru‐depleted signature of chromite and ulvöspinel from the olivine‐phyric shergottites may be the consequence of relatively lower Ru contents (<1 ppb) in the parental melts, and/or the presence of sulfides during the crystallization of the spinel phases. The results of this study illustrate the significance of platinum‐group element in situ analysis on spinel phases to decipher the sulfide saturation history of magmatic systems.     

Analytical models of contaminant transport in coastal aquifers

The Henry formulation, which couples subsurface flow and salt transport via a variable-density flow formulation, can be used to evaluate the extent of sea water intrusion into coastal aquifers. The coupling gives rise to nontrivial flow patterns that are very different from those observed in inland aquifers. We investigate the influence of these flow patterns on the transport of conservative contaminants in a coastal aquifer. The flow is characterized by two dimensionless parameters: the Péclet number, which compares the relative effects of advective and dispersive transport mechanisms, and a coupling parameter, which describes the importance of the salt water boundary on the flow. We focus our attention on two regimes – low and intermediate Péclet number flows. Two transport scenarios are solved analytically by means of a perturbation analysis. The first, a natural attenuation scenario, describes the flushing of a contaminant from a coastal aquifer by clean fresh water, while the second, a contaminant spill scenario, considers an isolated point source.     

Calibration of a chalcogenide glass membrane ion-selective electrode for the determination of free Fe in seawater: I. Measurements in UV photooxidised seawater

Calibration of a chalcogenide glass membrane, Fe(III)ISE [Fe_2.5(Ge₂₈Sb₁₂Se₆₀)_97.5], in buffered saline media has been undertaken in order to assess the suitability of this ISE for seawater analyses. The electrode slopes in saline citrate and salicylate buffers were 26.3 and 28.2 mV/decade, respectively, for Fe³⁺ concentrations ranging from 10⁻¹⁰ M to less than 10⁻²⁵ M Fe³⁺. The calibration lines in the citrate and salicylate buffers were essentially collinear with the response in unbuffered chloride-free standards containing >10⁻⁵ M Fe³⁺, demonstrating that the response of the FeISE is unaffected by chloride ions. A mechanism involving a combination of charge transfer and ion-exchange of Fe(III), at the electrode diffusion layer, can be used to explain the ≈30 mV/decade slope of the FeISE. The response of the FeISE in UV photooxidised seawater containing 8 nM total Fe was measured as the pH was changed from 8.27 to 3.51. The slope of the response was 24.2 mV/decade [Fe³⁺] calculated as a function of pH using Fe(III) hydrolysis constants for seawater. Moreover, the response was essentially collinear with that in citrate buffers and in unbuffered solutions containing >10⁻⁵ M Fe³⁺ and the slope for the combined data was 26.2 mV/decade. This study was restricted to organic-free seawater because the certainty in Fe(III)–ligand stability constants is insufficient to warrant the selection of an ideal calibration buffer system, and there is evidence that powerful chelating ligands (e.g., EDTA along with humic and fulvic acids) may alter the response of the Fe(III)ISE. The Fe dissolution rate of the FeISE in UV photooxidised seawater was found to be 1.6×10⁻² nmol Fe/min, as measured by cathodic stripping voltammetry (CSV). This would contaminate a 100-ml sample by 0.8–1.6 nM Fe over a typical measurement period of 5–10 min obtained using a stability criterion of 0.5 mV/min. Various methods are proposed for reducing the level of contamination in open ocean samples that contain sub-nanomolar concentrations of iron. The FeISE has the potential to detect free Fe³⁺ at concentrations typically found in natural seawater.     

The seagrass skeletal assemblage from modern to fossil and from tropical to temperate: Insight from Maldivian and Mediterranean examples

Seagrasses are marine angiosperms that form extensive submarine meadows in the photic zone where carbonate producing biota dwell as epiphytes on the leaves or as infaunal forms, and act as prolific carbonate sediment factories. Because seagrasses have a low preservation potential and records of exceptionally well‐preserved and plant material from marine settings are rare, these palaeoenvironments are difficult to identify in the rock record. Consequently, sedimentological and palaeontological proxies are the main indicators of the presence of seagrass‐dominated ecosystems. This work investigates the skeletal assemblage of Modern (Maldivian and western Mediterranean) and fossil (Eocene; Apula and Oman carbonate platforms and Oligocene; Malta platform) seagrass examples to characterize the skeletal assemblage of modern and fossil seagrasses. Two main types of grains, calcareous algae and foraminifera, constitute around 50% of the bioclastic sediment in both tropical Maldivian and temperate Mediterranean scenarios. However, in the tropical setting they are represented by green algae (Halimeda), while in the Mediterranean they are represented by corallinacean red algae. In contrast, in the Eocene examples, the foraminifera are the most conspicuous group and the green algae are also abundant. The opposite occurs in the Maltese Chattian, which is dominated by coralline algae (mean 42%), although the foraminifera are still abundant. It is suggested to use the term foralgal to identify the seagrass skeletal assemblage. To discriminate between red algae and green algae dominance, the introduction of the prefixes ‘GA’ (green algae) and ‘RA’ (red algae) is proposed. The investigated examples provide evidence that the green algae–foralgal assemblage is typical of tropical, not excessively dense seagrass meadows, characterized by a well‐illuminated substrate to support the development and calcification of the Halimeda thallus. Contrarily, the red algae‐foralgal assemblage is typical of high density tropical to subtropical seagrass meadows which create very dense oligophotic conditions on the sea floor or in temperate settings where Halimeda cannot calcify.     

The response of braided planform configuration to flow variations,bed reworking and vegetation: the case of the Tagliamento River,Italy

Morphological features of braided rivers (bars, channels and pools) experience major changes in area, shape and spatial distribution as a response to (i) the pulsation of discharge during a flood and (ii) the bed evolution induced by floods. In this work, at‐a‐station relationships between water level and planform configuration were investigated on the Tagliamento River, a large gravel‐bed braided river in northeast Italy, over a 2‐year study period comprising three bankfull events and several small‐to‐medium floods. The analysis was performed on two 1‐km‐long reaches, characterized by different riparian vegetation cover. Ground‐based images with an hourly temporal resolution were acquired using software‐controlled, digital cameras. Bars, channels, pools and vegetated patches were manually digitized on more than 100 rectified images. Sequences of constant‐level images spanning the study period were used to quantify the impact of floods on the stability of at‐a‐station relationships and on the turnover rate of water bodies. The analysis shows that wetted area increased almost linearly with water level in both reaches. The average number of branches per cross‐section peaked at intermediate flow levels, increasing from 2 at low flow up to 6–7. The number of branches displayed the largest fluctuations over time, with significant changes produced also by moderate floods. Turnover rates were high in both reaches, with more than 30% of wetted areas at low flow converting into bare gravel in less than 2 months. Vegetation colonization was found to limit the mobility of the low flow channels over time by concentrating the flow in fewer, deeper anabranches. The number of channels per cross‐section was 30–40% less in the vegetated reach and the proportion of low flow water bodies in the same position after 12 months increased from 3% to 14%. Copyright © 2012 John Wiley & Sons, Ltd.