邻菲啰啉在测定亚铁中的保护效果

样品在分解过程中 ,亚铁易被空气部分氧化 ,致使测试结果偏低 ,采用在HF H2 SO4溶矿过程中加入邻菲卟罗啉 ,与亚铁形成络合物 ,对保护亚铁具有较好的效果。拟定了在塑料坩埚中加邻菲卟罗啉、H2 SO4及HF ,中高温电热板溶矿 ,容量法测定样品中的亚铁 ,方法精密度为 0 .2 3% ,样品加标准回收率 98.8%～ 10 1.9%。此方法具有较好的应用效果     

AR（P）参数估计协方差方法与其改进型方法的对比研究

定性分析协方差方法及其改进型在ＡＲ（Ｐ）参数估计中的应用，提供了一种估计参数的计算机上机流程图，比较了协方差方法及其改进型谱估计结果。     

量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。     

EFFECT OF LIGHT INTENSITY ON THE TOTAL LIPID AND FATTY ACID COMPOSITION OF SIX STRAINS OF MARINE DIATOMS

The effect of light intensity ( 1500 Ix and 5000 Ix) on the total lipid and fatty acid composition of six strains of marine diatoms Cylindrotheca fusiformis (B211 ), Phaeodactylum tricornutum (Bl14, Bl18 and B221) Nitzschia closterium (B222) and Chaetoceros gracilis (B13) was investigated.The total lipids of B13, Bl14, and B211 grown at 5000 Ix were lower than those grown at 1500 Ix. No evident changes were observed in Bl18, B221 and B222. Fatty acid composition changed considerably at different light intensity although no consistent correlation between the relative proportion of a single FA and light intensity. The major fatty acids of the 6 strains were 14:0, 16:0, 16:l(n- 7) and 20:5(n-3) . Cylindrothecafusiformis had high percentage of 20:4n - 6 (9.2 - 10.9% ) . The total polyunsaturated fatty acid /rl all 6 strains decreased with increasing light intensity. The percentage of the highly unsaturated fatty acid eicosapentaenoic acid (EPA) decreased with increasing light intensity in all strains except Chaetoceros gracilis.     

Modeling X-Ray Photoionized Plasmas Produced at the Sandia Z-Facility

In experiments at the high-power Z-facility at Sandia National Laboratory in Albuquerque, New Mexico, we have been able to produce a low density photoionized laboratory plasma of Fe mixed with NaF. The conditions in the experiment allow a meaningful comparison with X-ray emission from astrophysical sources. The charge state distributions of Fe, Na and F are determined in this plasma using high resolution X-ray spectroscopy. Independent measurements of the density and radiation flux indicate unprecedented values for the ionization parameter ξ = 20–25 erg cm s⁻¹ under nearly steady-state conditions. First comparisons of the measured charge state distributions with X-ray photoionization models show reasonable agreement, although many questions remain.     

基于专家系统决策的多模式控制及其应用

将专家系统技术与常规控制、模糊控制、超前控制、仿人智能操作控制以及计算机控制技术相结合,设计了一种新的基于专家系统决策的多模式控制(MCDBES)。经试验和实际运行结果表明,MCDBES系统对未知数学模型的被控对象,具有良好的控制性能。本文提出的MCDBES已成功地应用于燃油陶瓷窑炉计算机控制系统。     

North European last glacial–interglacial transition (LGIT; 15–9 ka) tephrochronology: extended limits and new events

High‐precision correlation of palaeoclimatic and palaeoenvironmental records is crucial for testing hypotheses of synchronous change. Although radiocarbon is the traditional method for dating late Quaternary sedimentary sequences, particularly during the last glacial–interglacial transition (LGIT; 15–9 ka), there are inherent problems with the method, particularly during periods of climate change which are often accompanied by major perturbations in atmospheric radiocarbon content. An alternative method is the use of tephras that act as time‐parallel marker horizons. Within Europe, numerous volcanic centres are known to have erupted during the LGIT, providing considerable potential for high‐precision correlation independent of past radiocarbon fluctuations. Here we report the first identification of the Vedde Ash and Askja Tephra in Ireland, significantly extending the known provenance of these events. We have also identified two new horizons (the Roddans Port Tephras A and B) and tentatively recognise an additional horizon from Vallensgård Mose (Denmark) that provide crucial additional chronological control for the LGIT. Two phases of the Laacher See Tephra (LST) are reported, the lower Laacher See Tephra (LLST) and probably the C2 phase of the Middle Laacher See Tephra (MLST‐C2) indicating a more northeasterly distribution of this fan than reported previously. Copyright © 2006 John Wiley & Sons, Ltd.     

Evaluation of ferrous and ferric Mössbauer fractions

The Mössbauer fractions f for various ferrous- and/or ferric-containing oxides and oxyhydroxides, silicates and carbonates were evaluated from the experimental temperature dependence of their center shifts, using the Debye approximation for the second-order Doppler shift. It is concluded that ferrous ions exhibit a lower fraction as compared to ferric ions. Using standard mixtures of -Fe₂O₃ with selected Fe²⁺ or Fe³⁺ compounds, it is found that the calculated Fe³⁺ f values are somewhat overestimated with respect to those of Fe²⁺. Possible explanations for this shortcoming are discussed and it is suggested that a different temperature dependence of the intrinsic isomer shift is the most likely reason. This suggestion is corroborated by analyses of hematite and hedenbergite data which are available for temperatures up to 900 K and 800 K respectively.     

Sunspot nests

For the period August 1959–December 1964 the Greenwich Photoheliographic Results were searched for sunspot nests. Such a nest is a sequence of sunspot groups that appear within a small area on the solar surface and that last for several months. The search procedure is described and data for 41 probable sunspot nests are given. At least three quarters of these nests appear to be real, and not chance clusters.The nests are the same type of activity sequences as the Fleckenherde discovered by Becker (1955) and the complexes of activity pointed out by Gaizauskas et al. (1983). The complexes of activity as defined by Bumba and Howard (1965) are different patterns, however; the relation between complexes and the nests is shown.Some properties of the nests are: (i) many nests appear as double structures; (ii) single nests and components of double nests are quite compact: the effective areas are comparable to those of medium-large sunspot groups; (iii) each nest rotates at its own steady rate about the Sun; (iv) the intrinsic scatter in the rotation rates is much larger than the trend in the differential rotation; (v) displacements in latitude are less than a few meters per second; (vi) many nests live for 6 to 15 Carrington rotation periods, the minimum lifetime is not yet determined; (vii) the fraction of the sunspot groups that are members of nests is large (at least 30%).