Geological structure, evolution stages, and petroliferous complexes of the Gulf of Mexico basin

The Gulf of Mexico basin occupies a vast region encompassing the southern continental margin of North America, a considerable part of the Greater Antilles, and the intervening Sigsbee Deep with the oceanic crust. In the north, the basin is contiguous with spurs of the Hercynian Appalachians, the Mississippi Interior and Permian basins. The Mississippi Fan, one of the largest in the world, governs the bottom topography and structure in the eastern Gulf of Mexico. The abyssal basin is surrounded in many areas by steep continental slopes passing in places into escarpments: Sigsbee, Campeche, and others. It is only in the Yucatan Peninsula region that the continental slope merges with a wide shelf. The Cuban-North Haiti meganticlinorium frames the basin on the Cuba Island side.     

Source rocks in sedimentary basins of continental margins in the early paleozoic

During the Paleozoic, epochs with the relatively cold climate alternated with epochs marked by significant warming. Moreover, cooling epochs were characterized by the substantial sea level fall, while warming was accompanied by its rapid rise. In many basins located at margins of Laurentia, Baltica, and the North China continental block, such an alternation is reflected in the structure of sedimentary sequences and the lateral/vertical distribution of reservoirs, confining beds, and source rocks. Despite the fact that sediments with high concentrations of sapropelic OM accumulated in different periods, their distribution areas on continents and their margins became highly reduced during cold epochs, when these sediments filled mostly rift troughs and foreland basins. After the colonization of land by higher plant communities in the Carboniferous and Permian sediments deposited during cold epochs, the humic material became an important constituent of OM in the source rock sequences.     

Continental margins: Global belts of oil and gas accumulation

Most of recent oil- and gas-bearing basins are incorporated in the group of five belts of oil-and-gas accumulation. They are confined to continent/ocean transition zones, which existed in the Cenozoic. Three belts (Tethyan, Gondwanan, and Laurasian) are latitudinal structures that include continental margins in the Atlantic, Indian, and Arctic oceans. The other two belts are elongated in the N-S direction and located in the western and eastern peripheral parts of the Pacific Ocean. Taken together, they unite basins with 75 to 80% of oil reserves discovered to date in our planet.     

A set of optical methods for studying marine phytoplankton

The results of integrated optical measurements of Black Sea water samples using a spectrophotometer, laser spectrometer, and fluorometer with pulse-modulated excitation light are discussed. A linear correlation between the intensities of chlorophyll absorption at 673 nm and chlorophyll fluorescence (680–750 nm) is observed. Phycoerythrin-containing organisms are recorded in phytoplankton in layers below 20 m. The data of 1-week monitoring of phytoplankton abundance and functional activity in Golubaya Bay with a Mega-25 flow fluorometer are described.     

Phenomenological model of phase transformations of gas hydrates in porous media: Visco-plastic consolidated skeleton

We develop a phenomenological model to describe the behavior of natural porous media saturated with phases that can experience phase transformations which result in changes of the strength, rheology, and transport properties of the medium. A porous medium saturated with gas hydrates cementing the grains of a mineral skeleton is an example of such behavior. On a decrease in pressure or increase in temperature, hydrates in such a medium dissociate into gas and water. The resulting fluid acts as a lubricant between the skeleton grains: the elastic response is changed by the viscous response, and the processes of consolidation and multiphase filtration in the deforming skeleton are initiated.     

Oil source rocks at mesozoic and cenozoic continental margins: Communication 2. Oil source rocks at continental margins in the second half of the cretaceous and in the Cenozoic

Oil source rocks represent sequences with the C_org content ranging from 3–5 to 15–20%. Sedimentary sections of large petroliferous basins usually include one or two such sequences, which generated liquid and gaseous hydrocarbons (HCs) during their long-term subsidence to the elevated temperature zone. The middle episode of the Late Cretaceous was marked by the accumulation of sediments with a high C_org content in different areas of the World Ocean. However, truly unique settings favorable for accumulation of the sapropelic organic matter (OM) appeared at continental margins that primarily faced the Tethys Ocean. The La Luna Formation is one of the best known source rock sequences responsible for the generation of liquid HCs in basins of the Caribbean region. In the Persian Gulf, the Kazhdumi Formation composed of marls and clayey limestones is considered the main oil-generating sequence. In the Paleogene after closure of the Tethys, the Pacific continental margins became the main domains that accumulated source rocks. The maximal deposition of sapropelic OM in this region corresponded to the early-middle Eocene. In the Neogene, the accumulation of source sediments was associated with deltas and submarine fans of large rivers and with upwelling zones. In basins of the Californian borderland, the main oil-generating sequences are represented by siliceous rocks of the Monterey Formation. They were deposited in a regional upwelling zone related to the cold California Current.     

Continental margins: Global belts of oil-and-gas accumulation. The Caribbean-pacific belt

Among petroliferous regions of the world, a specific place is occupied by sedimentary basins confined to continental margins at the eastern periphery of the Pacific Ocean and in the Caribbean Sea. In the Cenozoic and Quaternary, this region was dominated by tectonic activity manifested as compression, movements along large fault systems (primarily, strike-slip faults), formation of mountain chains, appearance of thick accretion prisms and foothills, and development of volcanism at certain stages. The petroliferous structures of the region are mainly represented by fore-arc sedimentary basins complicated in some places by fore- and backdeeps.     

Petroliferous basins at continental margins of paleozoic paleoseas: Communication 2. Petroliferous basins at continental margins in the Rheic, Uralian, and Central Asian paleoseas

The continental block of the Earth’s crust was separated in the Paleozoic into two unequal parts: (i) huge supercontinent Gondwana located at high latitudes of the Southern Hemisphere and (ii) several small continents (Laurentia, Baltica, Siberia, Kazakhstan, South Chinese block, and North Chinese blocks) located at low latitudes south and north of the equator. Morphology of the Paleozoic seas between these blocks was subjected to changes (expansion and contraction) with time. Their closure was provoked by several orogenic (Taconian, Caledonian, Acadian, and Hercynian) phases. At present, relicts of these ancient orogenic structures extend as belts along the boundaries of many petroliferous basins and record the position of past seas. One of the oldest oil-and-gas deposition belts, which appeared in southern Iapetus in the Precambrian/Phanerozoic, was confined to a passive margin of Gondwana. In the Early Paleozoic, small blocks of the continental crust (Avalonia, Armorica, Perunica, Iberica, and others) were successively detached from the passive margin. This process was accompanied by the opening of a new deep basin (Rheic Sea or Paleotethys). The Uralian and Central Asian paleoseas were formed approximately at the same time. Many petroliferous basins existing now were located in the Paleozoic at the margins of these paleoseas.     

Black shales and other sediments with high organic matter contents in Phanerozoic climatic cycles: Communication 2. Black shales during the Pangea existence

According to recent concepts, the Earth surface was permanently transformed during its geological history. Some stages of its evolution were marked by the convergence of separate continental blocks to result in the formation of supercontinents, which resisted successfully centrifugal processes. Other stages were characterized by the opposite tendency: after their long existence, the supercontinents became disintegrated into several large and small blacks, the motion of which was accompanied by opening of new sea basins and closure of former basins with the oceanic crust. The second half of the Paleozoic was marked by amalgamation of large continental blocks. In the Devonian, collision between Laurentia and Baltica culminated in the formation of the Euroamerica continent. After the closure of the Ural paleocean in the terminal Carboniferous–initial Permian, it was united with the Siberian and Kazakhstan continental blocks. These events provided the prerequisites for the formation of a new supercontinent (Pangea), which acquired its final configuration at the end of the Permian. One of its segments located mainly south of the equator included Gondwana. Another segment located northward included Euroamerica, Kazakhstan, Siberian, and two China continental blocks. During its geological history, Pangea suffered many dramatic events including several extinctions of organisms. The most significant event took place in the terminal Permian–initial Triassic and at the transition between the Triassic and Jurassic periods.     

Continental margins as global oil and gas accumulation belts: The West Pacific belt

Most present-day oil- and gas-bearing (petroliferous) basins are localized in one of the five global oil and gas accumulation belts confined to continent-ocean transition zones that existed in the Mesozoic and Cenozoic. Two meridional belts are located in the western and eastern peripheral zones of the Pacific Ocean with intense tectonic activity during the major part of the Mesozoic and Cenozoic. The activity was reflected in extension of the continental crust, spreading of the oceanic crust, rapid subsidence of individual crustal blocks, volcanism, and formation of large batholiths and accretionary prisms. In this belt, the fore-arc, back-arc, inter-arc, and marginal riftogenic sedimentary basins are petroliferous.