Anthropogenic trace metals in an ice core at Vestfonna,Svalbard, Norway

1　IntroductionAnicecoreobtainedfrom polarglaciersoricesheetsisoneofthemostimportantarchivestoreconstructpaleoclimaticandpaleoatmosphericcondition .Informationonpale o environmentcanbeextractedfromicecoresaschemicaland/orphysicalsignals.Amongthechemicalsignals,heavymetalsarenotedassignalsofterrestrialenvironmentalchangeandanthropogenicpollution (e.g .Murozumietal.1 969;NgandPatterson 1 981 ;Hongetal.1 994) .SinceconcentrationsofmostofthemetalsinpolarsnowincentralGreen landareatorbelowthepptl…     

Performance of Mortar and Chemical Grout Injection into Surrounding Soil When Slurry Pipe-jacking Method is Used

Small-diameter shallow tunnels are often being built by using the slurry pipe-jacking method. This system involves the pushing or thrusting of a drivage machine and concrete pipes into the ground. Chemical grout injection into the surrounding soil around the tunnel is carried out after the drivage and pushing processes are finished. The purpose of the chemical grout injection is to maintain permanent stability of the surrounding soil. However, the behavior of the chemical grouting material in the surrounding soil around the tunnel and the amount of optimum injection is not clearly understood. From these points of view, this paper discusses the performance of the chemical grouting material, when it is injected into the surrounding soil around the tunnel, by means of 2-D Eulerian–Lagrangian seepage analysis. Moreover, the effectiveness of the chemical grout injection was evaluated by using the non-linear finite element method. This investigation show when the range of the grouted zone is designed; it is necessary that the relationship between Young’s modulus of the soil/grouted zone and the confining stress be taken into consideration in order to establish effective, economical and safe chemical grout injection system. Understanding the performance of the seepage/dispersion behavior of the chemical grout and the characteristics of soil/ grouted zone is also important.     

Monitoring of Over Cutting Area and Lubrication Distribution in a Large Slurry Pipe Jacking Operation

Slurry pipe jacking was firmly established as a special method for the non-disruptive construction of the underground pipelines of sewage systems. Pipe jacking, in its traditional form, has occasionally been used for short railways, roads, rivers, and other projects. Basically the system involves the pushing or thrusting of concrete pipes into the ground by a number of jacks. In slurry pipe jacking, during the pushing process, mud slurry and lubricant are injected into the face and the over cutting area that is between the concrete pipes and the surrounding soil. Next, the slurry fills voids and the soil stabilizes due to the created slurry cake around the pipes. Fillings also reduce the jacking force or thrust during operation. When the drivage and pushing processes are finished, a mortar injection into the over cutting area is carried out in order to maintain permanent stability of the surrounding soil and the over cutting area. Successful lubrication around the pipes is extremely important in a large diameter slurry pipe jacking operation. Control of lubrication and gaps between pipes and soil can prevent hazards such as surface settlement and increases in thrust. Also, to find voids around the pipes after the jacking process, in order to inject mortar for permanent stabilizing, an investigation around the pipes is necessary. To meet these aims, this paper is concerned with the utilization of known methods such as the GPR (Ground Penetrating Radar) system and borehole camera to maintain control of the over cutting area and lubricant distribution around the pipes during a site investigation. From this point of view, experiments were carried out during a tunnel construction using one of the largest cases of slurry pipe jacking in Fujisawa city, Japan. The advantages and disadvantages of each system were clarified during the tests.     

Spatial partitioning between species of the phytoplankton-feeding guild on an estuarine intertidal sand flat and its implication on habitat carrying capacity

The fishery yield of Manila clams, Ruditapes philippinarum, increased considerably in the 1970s but has decreased rapidly since the middle 1980s on extensive intertidal sand flats in Ariake Sound (Kyushu, Japan). A survey conducted in 2004 on a 3.4-km² sand flat located in the central part of the Sound (Shirakawa sand flat) revealed four dominant species: two thalassinidean shrimps (Upogebia major and Nihonotrypaea japonica), which are deep-reaching burrow dwellers with strong bioturbation activities, and two bivalves (Mactra veneriformis and R. philippinarum). All four species belong to a phytoplankton (diatom)-feeding guild. In the late 1970s, the Manila clam population prevailed in high densities over the entire sand flat, whereas its distribution was restricted to the lowest quarter of the shore in 2004. In contrast, the population sizes and zones of occurrence of the other phytoplankton feeders have expanded in the absence of R. philippinarum, perhaps an indication of competitive release. After establishment, effects of the thalassinidean shrimps on sediment stability appear to have further reduced clam abundances. Across the sand flat in 2004, wet weight population biomass estimates for N. japonica, U. major, M. veneriformis, and R. philippinarum (whole body for shrimps and soft tissue for bivalves) were 304, 111, 378, and 234 tonnes, respectively. Based on Manila clam fishery yield records from Shirakawa, the carrying capacity of the Shirakawa sand flat in the late 1970s was estimated to be two times greater than the sum value for the whole phytoplankton-feeding guild in 2004. It is hypothesized that (1) the amount of phytoplankton determines the carrying capacity for the benthic community on the Shirakawa sand flat, with both phytoplankton and benthic biomass at maxima in the late 1970s, and (2) the subsequent increases in competition for space have caused further declines in the Manila clam population biomass to approximately one-eighth of its past value.     

Instabilities in the consumption and production for cobalt

Cobalt is obtained mainly as a byproduct of the mining and metallurgical processing of copper and nickel. The amount of minable cobalt has a characteristic supply limit, which is dependent upon demand for copper and nickel. It is considered that cobalt consumption will be affected by the amount mined in the near future, because world demand has been gradually increasing, while the production from copper sulfide ores in Zaire and Zambia, major producing countries, has decreased for political, economical and technological reasons. The world demand for cobalt has surpassed the world mine production, and cobalt sales from the National Defense Stockpile of the United States and exports from Russia and cobalt recovered from stockpiled intermediates contributed to the supply in 1994. It is concluded, from a statistical point of view, that this trend of shortage and high prices for cobalt will continue in the near future.     

Measurements of stable carbon isotopic composition of ethane and propane over the western North Pacific and eastern Indian Ocean: A useful indicator of atmospheric transport process

Stable carbon isotopic composition of ethane and propane over the western North Pacific and eastern Indian Ocean between 31°N and 26°S was investigated from February through March 2004. The isotopic composition of ethane ranged from −28 to −18‰ and showed a gradual increase from north to south. Conversely, that of propane was between −31 and −24‰; it showed no systematic latitudinal variation. Investigation of the ethane/propane ratio indicates that ethane and propane that originated from northern mid-latitude countries in the eastern part of Eurasia were both transported into the western North Pacific region. However, the results of the isotopic analyses indicate the contribution of oceanic emission to the atmospheric propane during transport, although that contribution can not be discerned for ethane. A ship based stationary observation conducted in the western equatorial North Pacific showed that the isotopic composition of ethane varied from −25 to −19‰ and showed clear systematic diurnal variation: propane ranged between −32 to −26‰ and no such isotopic diurnal signal was observed. The diurnal variation for ethane is explained by entrainment of free tropospheric air, whereas the variation for propane was influenced by oceanic emissions as well as the entrainment. The contribution of oceanic emissions to the atmospheric propane inventory was considered from our isotopic observation. Isotopic composition of dissolved propane is estimated to be less than −38‰, and the contribution up to 79% was calculated when the isotopic composition of dissolved propane is assumed to be −40‰. Our study demonstrates that isotopic analysis can be more useful than ratio-based analysis to improve our present understanding of transport processes, especially for impact of the oceanic emissions on the atmospheric distribution of low level C₂–C₅ non-methane hydrocarbons such as propane in the remote marine atmosphere.     

Lithological and physical properties of core samples from the Sagara oil field: Oil occurrence in Sagara core samples

Abstract   A drilling and coring investigation of the Sagara oil field, central Honshu, Japan, was conducted to contribute to the understanding of hydrocarbon migration processes in a forearc basin. Core samples were analyzed to determine lithology, physical properties (specifically gas permeability) and the characteristics of oil occurrence. Gas permeability values greater than approximately 10⁻¹¹ m² constitute the basic precondition for any lithology to serve as a potential fluid conduit or reservoir in the Sagara oil field. Cores recovered from the 200.6-m-deep borehole were primarily composed of alternating siltstone, sandstone and conglomerate, all of which are correlated to the late Miocene Sagara Group. Both sandstone and conglomerate can be classified into two types, carbonate-cemented and poorly to non-cemented, based on matrix material characteristics. Oil stains are generally absent in the former lithology and more common in the latter. Variations in physical properties with respect to gas permeability values are directly related to the presence and character of carbonate cement, with higher permeabilities common in poorly to non-cemented rocks. The relationships between lithology, oil-staining, cementation and permeability indicate that cementation preceded oil infiltration and that cementation processes exerted significant control on the evolution of the reservoir.     

Northward younging zircon fission‐track ages from 13 to 2 Ma in the eastern extension of the Kathmandu nappe and underlying Lesser Himalayan sediments distributed to the south of Mt. Everest

This study is concerned with the tectono‐thermal history of the Kathmandu nappe and the underlying Lesser Himalayan sediments (LHS) that are distributed in eastern Nepal. We carried out zircon fission‐track(ZFT) dating and obtained 16 ZFT ages from the eastern extension of the Kathmandu nappe, the Higher Himalayan Crystalline, Kuncha nappe, and the Main Central Thrust (MCT) zone. The ZFT ages of the frontal part of the Kathmandu nappe range from 13.0 ±0.8 Ma to 10.7 ±0.7 Ma and exhibit a northward‐younging tendency. These Middle Miocene ZFT ages indicate that the frontal part of the Kathmandu nappe remained at a temperature above 240 °C until the termination of its southward emplacement at 12–11 Ma. The ZFT ages of the LHS range from 11.1 ±0.9 Ma in the southern part of the Okhaldhunga Window to 2.4 ±0.3 Ma of the augen gneiss in the northern margin and also exhibit a northward‐younging age distribution. The ZFT ages show the northward‐younging linear distribution pattern (?0.16 Ma/km) along the across‐strikesection from the frontal part of the Kathmandu nappe to the root zone, without a significant age gap. This distribution pattern indicates that the Kathmandu nappe, the underlying MCT zone, and the Kuncha nappe cooled from the frontal zone to the root zone as a thermally united geologic body at a temperature below 240 °C. An older ZFT age (456.3 ±24.3 Ma), which was partially reset at the axial part of the Midland anticlinorium in the central part of the Okhaldhunga Window, was explained by downward heating from the “hot” Kathmandu nappe. The above evidence supported a model that southward emplacement of the hot Kathmandu nappe resulted in a thermal imprint on the upper part of the LHS; however, the lower part did not reach 240 °C.     

Regional hazard prediction of rock bursts using microseismic energy attenuation tomography in deep mining

Rock burst prediction is a worldwide challenge that we have long tried to overcome. This study tentatively proposed a method to regionally predict rock burst hazards using microseismic energy attenuation. To verify the feasibility of the proposal, first, the mechanism of microseismic energy propagation and attenuation in rock medium was explored, and dominant attenuation characteristics of microseismic waves were analyzed. Second, a spatial attenuation model of microseismic energy was established, and the average energy attenuation coefficient for each wave path was defined. A 3D seismic energy attenuation inversion algorithm was put forward, and the corresponding computation matrix was developed. Third, a continuous microseismic field investigation was carried out in a deep coal mine. Seismic energy attenuation coefficient was confirmed using the calibrated focus position and energy determination. Based on data discretization processing, energy attenuation inversion and tomography, potential rock burst hazard regions were strictly zoned in mining areas. Finally, regional prediction results obtained from the microseismic energy attenuation were compared with the direct measurement results obtained from the classical drilling dust method to verify the reliability of proposed approach. It turns out that rock burst hazard regions predicted by the microseismic energy attenuation agreed well with the objective hazardous situations. Seismic energy attenuation coefficient is a significant evaluation factor that directly mirrors the inelastic performance of rock medium. Energy attenuation coefficient threshold used for determining the rock burst hazard regions was 3.0 km^?1. Reliability of the seismic energy attenuation inversion and tomography was closely related to the spatial distribution of microseisms in a localized region. The optimum spatial density of microseisms was 0.2 m^?3. Regional rock burst prediction using microseismic energy attenuation is an effective approach for revealing potential hazardous regions in deep mining conditions. This approach improves the pertinence of geological hazard prevention and provides a beforehand reference for targeted hazard management.