Oil-weathering behavior in Arctic environments

Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup.     

Geotechnical aspects of fine-grained mass flow deposits: California Continental Borderland

Seismic reflection profiling demonstrates the importance of mass movement in the north-central California Borderland. Bulk properties of surficial hemipelagic sediments in the Santa Barbara, Santa Cruz, and San Nicolas basins show that different types of mass-transported sediments have different properties, although their general sedimentologic characteristics are very similar. Slump deposits have moderate water contents (48% wet weight basis), high plasticity indices (46%), and moderate activities (1.6). For debris flows these values are low: 28%, 5%, and 0.3, respectively, and for other types (liquefied flow, mudflows, and turbidities) the values are high: 54 to 63%, 49 to 58%, and 1.2 to 1.5, respectively.     

A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.     

Nutrient-chlorophyll trajectories across trophic gradients

We estimate the response of chl-a (mg · m^–3) to changes in concentrations of total phosphorus (TP) by calculating the slopeS = chl-a/TP in chl-a =f(TP) graphs. Results show that in years where algae are P-limited oligotrophic lakes respond less (median slope 0.21) to changes in nutrient concentrations than eutrophic lakes, (median slope 0.31) and these again less than hypereutrophic lakes, (median slope 1.02). We find no saturation value for the slope within the TP range considered (6–480 mg · m^–3). Chl-a in eutrophic lakes responds more frequently to non-nutrient factors than oligotrophic and hypereutrophic lakes. Results obtained by replacing TP with a new nutrient parameter, TP = 0.056 · TP · IN^0.226, in which inorganic nitrogen, IN, is factored in, suggest that nitrogen has an influence on chl-a in oligotrophic lakes. Blue-green algae respond less to changes in TP than other algal species, e.g., diatoms.     

Helium isotopes in ferromanganese crusts from the central Pacific Ocean

Helium isotopes have been measured in samples of two ferromanganese crusts (VA13/2 and CD29-2) from the central Pacific Ocean. With the exception of the deepest part of crust CD29-2 the data can be explained by a mixture of implanted solar- and galactic cosmic ray-produced (GCR) He, in extraterrestrial grains, and radiogenic He in wind-borne continental dust grains. ⁴He concentrations are invariant and require retention of less than 12% of the in situ He produced since crust formation. Loss has occurred by recoil and diffusion. High ⁴He in CD29-2 samples older than 42 Ma are correlated with phosphatization and can be explained by retention of up to 12% of the in situ-produced ⁴He. ³He/⁴He of VA13/2 samples varies from 18.5 to 1852 R_a due almost entirely to variation in the extraterrestrial He contribution. The highest ³He/⁴He is comparable to the highest values measured in interplanetary dust particles (IDPs) and micrometeorites (MMs). Helium concentrations are orders of magnitude lower than in oceanic sediments reflecting the low trapping efficiency for in-falling terrestrial and extraterrestrial grains of Fe-Mn crusts. The extraterrestrial ³He concentration of the crusts rules out whole, undegassed 4-40 μm diameter IDPs as the host. Instead it requires that the extraterrestrial He inventory is carried by numerous particles with significantly lower He concentrations, and occasional high concentration GCR-He-bearing particles.     

Global occurrence of tellurium-rich ferromanganese crusts and a model for the enrichment of tellurium

Hydrogenetic ferromanganese oxyhydroxide crusts (Fe-Mn crusts) precipitate out of cold ambient ocean water onto hard-rock surfaces (seamounts, plateaus, ridges) at water depths of about 400 to 4000 m throughout the ocean basins. The slow-growing (mm/Ma) Fe-Mn crusts concentrate most elements above their mean concentration in the Earth’s crust. Tellurium is enriched more than any other element (up to about 50,000 times) relative to its Earth’s crustal mean of about 1 ppb, compared with 250 times for the next most enriched element.We analyzed the Te contents for a suite of 105 bulk hydrogenetic crusts and 140 individual crust layers from the global ocean. For comparison, we analyzed 10 hydrothermal stratabound Mn-oxide samples collected from a variety of tectonic environments in the Pacific. In the Fe-Mn crust samples, Te varies from 3 to 205 ppm, with mean contents for Pacific and Atlantic samples of about 50 ppm and a mean of 39 ppm for Indian crust samples. Hydrothermal Mn samples have Te contents that range from 0.06 to 1 ppm. Continental margin Fe-Mn crusts have lower Te contents than open-ocean crusts, which is the result of dilution by detrital phases and differences in growth rates of the hydrogenetic phases.Correlation coefficient matrices show that for hydrothermal deposits, Te has positive correlations with elements characteristic of detrital minerals. In contrast, Te in open-ocean Fe-Mn crusts usually correlates with elements characteristic of the MnO₂, carbonate fluorapatite, and residual biogenic phases. In continental margin crusts, Te also correlates with FeOOH associated elements. In addition, Te is negatively correlated with water depth of occurrence and positively correlated with crust thickness. Q-mode factor analyses support these relationships. However, sequential leaching results show that most of the Te is associated with FeOOH in Fe-Mn crusts and ≤10% is leached with the MnO₂.Thermodynamic calculations indicate that Te occurs predominantly as H₅TeO₆⁻ in ocean water. The speciation of Te in ocean water and charge balance considerations indicate that Te should be scavenged by FeOOH, which is in agreement with our leaching results. The thermodynamically more stable Te(IV) is less abundant by factors of 2 to 3.5 than Te(VI) in ocean water. This can be explained by preferential (not exclusive) scavenging of Te(IV) by FeOOH at the Fe-Mn crust surface and by Fe-Mn colloids in the water column. We propose a model in which the extreme enrichment of Te in Fe-Mn crusts is likely the result of an oxidation reaction on the surface of FeOOH. A similar oxidation process has been confirmed for Co, Ce, and Tl at the surface of MnO₂ in crusts, but has not been suggested previously to occur in association with FeOOH in Fe-Mn crusts. Mass-balance considerations indicate that ocean floor Fe-Mn deposits are the major sink for Te in the oceans. The concentration and redox chemistry of Te in the global ocean are likely controlled by scavenging on Fe-Mn colloids in the water column and Fe-Mn deposits on the ocean floor, as is also the case for Ce.     

HOLOCENE CARBONATE PRECIPITATES ON PRECAMBRIAN BEDROCK IN THE HIGH ARCTIC: AGE AND POTENTIAL FOR PALAEOCLIMATIC INFORMATION

ABSTRACT. Crusts of white carbonate precipitate occur commonly on the upper surfaces of glacially sculptured Precambrian granites and gneisses in east-central Ellesmere Island. Radiocarbon dating of 21 such carbonate precipitates, from elevations between 50 m and 1050 m a.s.l., has yielded only Holocene ages. Two samples from Ellesmere Island, plus one from Inglefield Land, Greenland, have calibrated ages over 5000 years, the rest are younger. The formation of these deposits, mainly calcite and characterized by unusually heavy δ¹³C ratios (+3.36 to +15.18‰), has apparently been aided in some cases by the presence of bacteria, and some crusts seem to have developed where Ca-bearing minerals are more prevalent. In the case of Bache Peninsula and Cape Herschel, where the carbonate crusts are particularly abundant, the presence of calcareous till may have played a role as well. The carbonate crusts may be related to the presence of small, thin carapace ice caps, when such features formed at lower elevations than those at which they exist today. The more extensive cover of ice and snow is postulated to have existed during the latter, cooler part of the Holocene, especially during the period from 2500 to 100 years ago, deduced as a period of low melt from ice core studies on the Agassiz Ice Cap, 200 km to the north. The existence of carapace ice caps at lower elevations also agrees with the radiocarbon evidence for outlet glacier advances during the last 2000 years on both east and west margins of the Prince of Wales Icefield. Alternatively, the white carbonate crusts may be, to a large degree, the result of weathering processes. In either case they provide minimum ages for the exposed, ice-sculptured rock surfaces on which they occur.     

Assessing the effects of land cover and future climate conditions on the provision of hydrological services in a medium‐sized watershed of Portugal

The separated and combined effects of land‐cover scenarios and future climate on the provision of hydrological services were evaluated in Vez watershed, northern Portugal. Soil and Water Assessment Tool was calibrated against daily discharge, sediments and nitrates, with good agreements between model predictions and field observations. Four hypothetical land‐cover scenarios were applied under current climate conditions (eucalyptus/pine, oak, agriculture/vine and low vegetation). A statistical downscaling of four General Circulation Models, bias‐corrected with ground observations, was carried out for 2021–2040 and 2041–2060, using representative concentration pathway 4.5 scenario. Also, the combined effects of future climate conditions were evaluated under eucalyptus/pine and agriculture/vine scenario. Results for land cover revealed that eucalyptus/pine scenario reduced by 7% the annual water quantity and up to 17% in the summer period. Although climate change has only a modest effect on the reduction of the total annual discharge (?7%), the effect on the water levels during summer was more pronounced, between ?15% and ?38%. This study shows that climate change can affect the provision of hydrological services by reducing dry season flows and by increasing flood risks during the wet months. Regarding the combined effects, future climate may reduce the low flows, which can be aggravated with eucalyptus/pine scenario. In turn, peak flows and soil erosion can be offset. Future climate may increase soil erosion and nitrate concentration, which can be aggravated with agriculture scenario. Results moreover emphasize the need to consider both climate and land‐cover impacts in adaptation and land management options at the watershed scale. Copyright © 2015 John Wiley & Sons, Ltd.     

Projected rainfall and temperature changes over Malaysia at the end of the 21st century based on PRECIS modelling system

This study investigates projected changes in rainfall and temperature over Malaysia by the end of the 21st century based on the Intergovernmental Panel on Climate Change (IPCC) Special Report on Emission Scenarios (SRES) A2, A1B and B2 emission scenarios using the Providing Regional Climates for Impacts Studies (PRECIS). The PRECIS regional climate model (HadRM3P) is configured in 0.22° × 0.22° horizontal grid resolution and is forced at the lateral boundaries by the UKMO-HadAM3P and UKMOHadCM3Q0 global models. The model performance in simulating the present-day climate was assessed by comparing the modelsimulated results to the Asian Precipitation - Highly-Resolved Observational Data Integration Towards Evaluation (APHRODITE) dataset. Generally, the HadAM3P/PRECIS and HadCM3Q0/PRECIS simulated the spatio-temporal variability structure of both temperature and rainfall reasonably well, albeit with the presence of cold biases. The cold biases appear to be associated with the systematic error in the HadRM3P. The future projection of temperature indicates widespread warming over the entire country by the end of the 21st century. The projected temperature increment ranges from 2.5 to 3.9°C, 2.7 to 4.2°C and 1.7 to 3.1°C for A2, A1B and B2 scenarios, respectively. However, the projection of rainfall at the end of the 21st century indicates substantial spatio-temporal variation with a tendency for drier condition in boreal winter and spring seasons while wetter condition in summer and fall seasons. During the months of December to May, ~20-40% decrease of rainfall is projected over Peninsular Malaysia and Borneo, particularly for the A2 and B2 emission scenarios. During the summer months, rainfall is projected to increase by ~20-40% across most regions in Malaysia, especially for A2 and A1B scenarios. The spatio-temporal variations in the projected rainfall can be related to the changes in the weakening monsoon circulations, which in turn alter the patterns of regional moisture convergences in the region.