Impact-generated atmospheres over Titan, Ganymede, and Callisto

The competition between impact erosion and impact supply of volatiles to planetary atmospheres can determine whether a planet or satellite accumulates an atmosphere. In the absence of other processes (e.g., outgassing), we find either that a planetary atmosphere should be thick, or that there should be no atmosphere at all. The boundary between the two extreme cases is set by the mass and velocity distributions and intrinsic volatile content of the impactors. We apply our model specifically to Titan, Callisto, and Ganymede. The impacting population is identified with comets, either in the form of stray Uranus-Neptune planetesimals or as dislodged Kuiper belt comets. Systematically lower impact velocities on Titan allow it to retain a thick atmosphere, while Callisto and Ganymede get nothing. Titan's atmosphere may therefore be an expression of a late-accreting, volatile-rich veneer. An impact origin for Titan's atmosphere naturally accounts for the high D/H ratio it shares with Earth, the carbonaceous meteorites, and Halley. It also accounts for the general similarity of Titan's atmosphere to those of Triton and Pluto, which is otherwise puzzling in view of the radically different histories and bulk compositions of these objects.     

Coupled atmosphere-ocean models of Titan's past

We have developed a coupled atmosphere and ocean model of Titan's surface. The atmospheric model is a 1-D spectrally-resolved radiative-convective model. The ocean thermodynamics are based upon solution theory. The ocean, initially composed of CH4, becomes progressively enriched in ethane over time. The partial pressures of N2 and CH4 in the atmosphere are dependent on the ocean temperature and composition. We find that the resulting system is stable against a runaway greenhouse. Accounting for the decreased solar luminosity, we find that Titan's surface temperature was about 20 K colder 4 Gyr ago. Without an ocean, but only small CH4 lakes, the temperature change is 12 K. In both cases we find that the surface of Titan may have been ice covered about 3 Gyr ago. In the lakes case condensation of N2 provides the ice, whereas in the ocean case the ocean freezes. The dominant factor influencing the evolution of Titan's surface temperature is the change in the solar constant--amplified, if an ocean is present, by the temperature dependence of the solubility of N2. Accretional heating can dramatically alter the surface temperature; a surface thermal flux of 500 erg cm-2 sec-1, representative of small levels of accretional heating, results in a approximately 20 K change in surface temperatures.     

Saturn's rings: Particle composition and size distribution as constrained by observations at microwave wavelengths: II. Radio interferometric observations

The sizes, composition, and number of particles comprising the rings of Saturn may be meaningfully constrained by a combination of radar- and radio-astronomical observations. In a previous paper, we have discussed constraints obtained from radar observations. In this paper, we discuss the constraints imposed by complementary “passive” radio observations at similar wavelengths. First, we present theoretical models of the brightness of Saturn's rings at microwave wavelengths (0.34–21.0 cm), including both intrinsic ring emission and diffuse scattering by the rings of the planetary emission. The models are accurate simulations of the behavior of realistic ring particles and are parameterized only by particle composition and size distribution, and ring optical depth. Second, we have reanalyzed several previously existing sets of interferometric observations of the Saturn system at 0.83-, 3.71-, 6.0-, 11.1-, and 21.0-cm wavelengths. These observations all have spatial resolution sufficient to resolve the rings and planetary disk, and most have resolution sufficient to resolve the ring-occulted region of the disk as well. Using our ring models and a realistic model of the planetary brightness distribution, we are able to establish improved constraints on the properties of the rings. In particular, we find that: (a) the maximum optical depth in the rings is ～ 1.5 ± 0.3 referred to visible wavelengths; (b) a significant decrease in ring optical depth from λ3.7 to λ21.0 cm allows us to rule out the possibility that more than ～30% of the cross section of the rings is composed of particles larger than a meter or so; this assertion is essentially independent of uncertainties in particle adsorption coefficient; and (c) the ring particles cannot be primarily of silicate composition, independently of particle size, and the particles cannot be primarily smaller than ～0.1 cm, independently of composition.     

Properties of the clouds of Venus,as inferred from airborne observations of its near-infrared reflectivity spectrum

We have measured the shape and absolute value of Venus' reflectivity spectrum in the 1.2-to 4.0-μm spectral region with a circular variable filter wheel spectrometer having a spectral resolution of 1.5%. The instrument package was mounted on the 91-cm telescope of NASA Ames Kuiper Airborne Observatory, and the measurements were obtained at an altitude of about 41,000 feet, when Venus had a phase angle of 86°. Comparing these spectra with synthetic spectra generated with a multiple-scattering computer code, we infer a number of properties of the Venus clouds. We obtain strong confirmatory evidence that the clouds are made of a water solution of sulfuric acid in their top unit optical depth and find that the clouds are made of this material down to an optical depth of at least 25. In addition, we determine that the acid concentration is 84 ± 2% H_2SO4 by weight in the top unit optical depth, that the total optical depth of the clouds is 37.5 ± 12.5, and that the cross-sectional weighted mean particle radius lies between 0.5 and 1.4 μm in the top unit optical depth of the clouds. These results have been combined with a recent determination of the location of the clouds' bottom boundary [Marov et al., Cosmic Res.14, 637–642 (1976)] to infer additional properties about Venus' atmosphere. We find that the average volume mixing ratio of H₂SO₄ and H₂O contained in the cloud material both equal approximately 2× 10^?6. Employing vapor pressure arguments, we show that the acid concentration equals 84 ± 6% at the cloud bottom and that the water vapor mixing ratio beneath the clouds lies between 6 × 10^?4 and 10^?2.     

The formation of saturn's satellites and rings,as influenced by saturn's contraction history

We have used Pollack et al.'s 1976 calculations of the quasi-equilibrium contraction of Saturn to study the influence of the planet's early high luminosity on the formation of its satellites and rings. Assuming that the condensation of ices ceased at the same time within Jupiter's and Saturn's primordial nebulae, and using limits for the time of cessation derived for Jupiter's system by Pollack and Reynolds (1974) and Cameron and Pollack (1975), we arrive at the following tentative conclusions. Titan is the innermost satellite at whose position a methane-containing ice could condense, a result consistent with the presence of methane in this satellite's atmosphere. Water ice may have been able to condense at the position of all the satellites, a result consistent with the occurrence of low-density satellites close to Saturn. The systematic decrease in the mass of Saturn's regular satellites with decreasing distance from Saturn may have been caused partially by the larger time intervals for the closer satellites between the start of contraction and the first condensation of ices at their positions and between the start of contraction and the time at which Saturn's radius became less than a satellite's orbital radius. Ammonia ices, principally NH₄SH, were able to condense at the positions of all but the innermost satellites.Water ice may bave been able to condense in the region of the rings close to the end of the condensation period. We speculate that the rings are unique to Saturn because on the one hand, temperatures within Jupiter's Roche limit never became cool enough for ice particles to form before the end of the condensation period and on the other hand, ice particles formed only very early within Uranus' and Neptune's Roche limits, and were eliminated by gas drag effects that caused them to spiral into the planet before the gas of these planets' nebula was eliminated. Gas drag would also have eliminated any rocky particles initially present inside the Roche limit.We also derive an independent estimate of several million years for the time between the start of the quasi-equilibrium contraction of Saturn and the cessation of condensation. This estimate is based on the density and mass characteristics of Saturn's satellites. Using this value rather than the one found for Jupiter's satellites, we find that the above conclusions about the rings and the condensation of methane-and ammonia-containing ices remain valid.     

Formation of iron-containing colloids by the weathering of phyllite

The formation of colloids during the weathering of phyllite was investigated by exposing ground phyllite to Milli-Q water. Secondary mineral colloids of 10¹–10² nm were detected in significant concentrations. At pH of about 8.5, the solution concentration of these colloids reached up to 10 mg/L (however, acidification to pH 4.0 prevented the formation of the colloids). The mineralogical composition of the secondary mineral colloids is assumed to be a mixture of ferrihydrite, manganese oxyhydroxides, aluminosilicates, amorphous Al(OH)₃ and gibbsite with possible additions of iron silicates and␣iron-alumino silicates. The colloids were stable over longer periods of time (at least several weeks), even in the presence of suspended ground rock. Direct formation of iron-containing secondary mineral colloids at the rock–water interface by the weathering of rock material is an alternative to the well-known mechanism of iron colloid formation in the bulk of water bodies by mixing of different waters or by aeration of anoxic waters. This direct mechanism is of relevance for colloid production during the weathering of freshly crushed rock in the unsaturated zone as for instance crushed rock in mine waste rock piles. Colloids produced by this mechanism, too, can influence the transport of contaminants such as actinides because these colloids have a large specific surface area and a high sorption affinity.     

Reproductive cycles of Mytilus edulis L. on the west and east coasts of Iceland

Studies evaluating the reproductive pattern of Mytilus edulis L. were conducted in western and eastern Iceland at two sites at about the same latitude but with different temperature regimes. Mussels were sampled once or sometimes twice a month during two years in Breidifjördur, western Iceland and one year at Mjoifjördur, eastern Iceland. Gonad development was monitored by microscopic observation of thin sections of the gonads. The initiation of gonad development was observed in January in Breidifjördur while in Mjoifjördur some of the animals started developing gonads in October, a month before spawning was over in the population. Spawning started in late June or July, peaked in August and continued until November at both sites. Nutrient reserve stores seemed to be limited and used for initiation of gonad development in winter but were not sufficient for maturation of the gonads. The main growth of the gonads occured in spring in conjunction with phytoplankton blooming and renewal of food resources.     

Correlation of seismic activity and fumarole temperature at the Mt. Merapi volcano (Indonesia) in 2000

In this paper we present densely sampled fumarole temperature data, recorded continuously at a high-temperature fumarole of Mt. Merapi volcano (Indonesia). These temperature time series are correlated with continuous records of rainfall and seismic waveform data collected at the Indonesian–German multi-parameter monitoring network. The correlation analysis of fumarole temperature and precipitation data shows a clear influence of tropical rain events on fumarole temperature. In addition, there is some evidence that rainfall may influence seismicity rates, indicating interaction of meteoric water with the volcanic system. Knowledge about such interactions is important, as lava dome instabilities caused by heavy-precipitation events may result in pyroclastic flows. Apart from the strong external influences on fumarole temperature and seismicity rate, which may conceal smaller signals caused by volcanic degassing processes, the analysis of fumarole temperature and seismic data indicates a statistically significant correlation between a certain type of seismic activity and an increase in fumarole temperature. This certain type of seismic activity consists of a seismic cluster of several high-frequency transients and an ultra-long-period signal (<0.002 Hz), which are best observed using a broadband seismometer deployed at a distance of 600 m from the active lava dome. The corresponding change in fumarole temperature starts a few minutes after the ultra-long-period signal and simultaneously with the high-frequency seismic cluster. The change in fumarole temperature, an increase of 5 °C on average, resembles a smoothed step. Fifty-four occurrences of simultaneous high-frequency seismic cluster, ultra-long period signal and increase of fumarole temperature have been identified in the data set from August 2000 to January 2001. The observed signals appear to correspond to degassing processes in the summit region of Mt. Merapi.