Nonlinear effects manifested in infrasonic signals in the region of a geometric shadow

Nonlinear effects manifested in infrasonic signals passing through different atmospheric heights and recorded in the region of a geometric shadow have been studied. The source of infrasound was a surface explosion equivalent to 20–70 t of TNT. The frequencies of the spectral maxima of infrasonic signals, which correspond to the reflections of acoustic pulses from atmospheric inhomogeneities at different heights within the stratosphere-mesosphere-lower thermosphere layer, were calculated using the nonlinear-theory method. A satisfactory agreement between experimental and calculated data was obtained.     

Experimental study of arsenic speciation in vapor phase to 500°C: implications for As transport and fractionation in low-density crustal fluids and volcanic gases

The stoichiometry and stability of arsenic gaseous complexes were determined in the system As-H₂O ± NaCl ± HCl ± H₂S at temperatures up to 500°C and pressures up to 600 bar, from both measurements of As^(III) and As^(V) vapor-liquid and vapor-solid partitioning, and X-ray absorption fine structure (XAFS) spectroscopic study of As^(III)-bearing aqueous fluids. Vapor-aqueous solution partitioning for As^(III) was measured from 250 to 450°C at the saturated vapor pressure of the system (P_sat) with a special titanium reactor that allows in situ sampling of the vapor phase. The values of partition coefficients for arsenious acid (H₃AsO₃) between an aqueous solution (pure H₂O) and its saturated vapor (K = mAs_vapor /mAs_liquid) were found to be independent of As^(III) solution concentrations (up to ∼1 to 2 mol As/kg) and equal to 0.012 ± 0.003, 0.063 ± 0.023, and 0.145 ± 0.020 at 250, 300, and 350°C, respectively. These results are interpreted by the formation, in the vapor phase, of As(OH)₃(gas), similar to the aqueous As hydroxide complex dominant in the liquid phase. Arsenic chloride or sulfide gaseous complexes were found to be negligible in the presence of HCl or H₂S (up to ∼0.5 mol/kg of vapor). XAFS spectroscopic measurements carried out on As^(III)-H₂O (±NaCl) solutions up to 500°C demonstrate that the As(OH)₃ complex dominates As speciation both in dense H₂O-NaCl fluids and low-density supercritical vapor. Vapor-liquid partition coefficients for As^(III) measured in the H₂O-NaCl system up to 450°C are consistent with the As speciation derived from these spectroscopic measurements and can be described by a simple relationship as a function of the vapor-to-liquid density ratio and temperature. Arsenic^(III) partitioning between vapor and As-concentrated solutions (>2 mol As/kg) or As₂O₃ solid is consistent with the formation, in the vapor phase, of both As₄O₆ and As(OH)₃. Arsenic^(V) (arsenic acid, H₃AsO₄) vapor-liquid partitioning at 350°C for dilute aqueous solution was interpreted by the formation of AsO(OH)₃ in the vapor phase.The results obtained were combined with the corresponding properties for the aqueous As(III) hydroxide species to generate As(OH)₃(gas) thermodynamic parameters. Equilibrium calculations carried out by using these data indicate that As(OH)₃(gas) is by far the most dominant As complex in both volcanic gases and boiling hydrothermal systems. This species is likely to be responsible for the preferential partition of arsenic into the vapor phase as observed in fluid inclusions from high-temperature (400 to 700°C) Au-Cu (-Sn, -W) magmatic-hydrothermal ore deposits. The results of this study imply that hydrolysis and hydration could be also important for other metals and metalloids in the H₂O-vapor phase. These processes should be taken into account to accurately model element fractionation and chemical equilibria during magma degassing and fluid boiling.     

Internal Gravity and Infrasound Waves during the Hurricane of May 29, 2017, in Moscow

Izvestiya, Atmospheric and Oceanic Physics - Data on internal gravity and infrasound waves recorded during the passage of both warm and cold fronts throughout Moscow, which are associated with the...     

Modeling of vertical sounding ionograms for nonmonotonous ionospheric layers

The problem of radiosignal reflection from a plane layered isotropic ionosphere has been considered. The vertical sounding ionograms for ionospheric layers with a complicated structure have been modeled. It has been demonstrated that the structure of reflected signals depends on the degree of ionospheric irregularities. Diffuse reflection of radiosignals, caused by the vertical irregularity of the ionosphere, has been detected.     

Vertical Propagation of Acoustic-Gravity Waves from Atmospheric Fronts into the Upper Atmosphere

Izvestiya, Atmospheric and Oceanic Physics - The empirical approximations of atmospheric pressure-field oscillations were constructed based on observational data on atmospheric pressure variations...     

Space and time variations in the fine structure of the upper atmosphere according to acoustic sounding data

The results of studying variations in the fine layered structure of the upper atmosphere (heights of 20–140 km) according to data obtained from acoustic sounding within the range of infrasonic waves are given. The sources of infrasounds were surface explosions equivalent to 10 kg to 70 t of TNT. These explosions were set off in different seasons in different regions of Russia. Experimental data obtained in 1981–2011 have been analyzed. It has been found that the fine structure in the form of vertically distributed layered formations occurs in the upper atmosphere in all seasons. Moreover, the vertical distribution of both air-temperature and wind-velocity inhomogeneities in the upper atmosphere may be invariable over a time interval of no less than several hours. It has also been found that, throughout the entire atmospheric thickness from the stratopause to the lower thermosphere heights (up to 140 km), the instantaneous height distribution of layered air-temperature and wind-velocity inhomogeneities may remain almost unchanged during a time interval of no less than 20 min.     

Studying internal gravity waves generated by atmospheric fronts over the Moscow region

Internal gravity wave (IGW) data obtained during the passage of atmospheric fronts over the Moscow region in June–July 2015 is analyzed. IGWs were recorded using a group of four microbarographs (developed at the Obukhov Institute of Atmospheric Physics, Russian Academy of Sciences) located at distances of 7 to 54 km between them. Regularities of variations in IGW parameters (spatial coherence, characteristic scales, propagation direction, horizontal propagation velocity, and amplitudes) before, during, and after the passage of an atmospheric front over the observation network, when the observation network finds itself inside the cyclone and outside the front, are studied. The results may be useful in studying the relationships between IGW effects in different physical fields at different atmospheric heights. It is shown that, within periods exceeding 30 min, IGWs are coherent between observation points horizontally spaced at distances of about 60 km (coherence coefficient is 0.6–0.9). It is also shown that there is coherence between wave fluctuations in atmospheric pressure and fluctuations in horizontal wind velocity within the height range 60–200 m. A joint analysis of both atmospheric pressure and horizontal wind fluctuations has revealed the presence of characteristic dominant periods, within which cross coherences between fluctuations in atmospheric pressure and wind velocity have local maxima. These periods are within approximate ranges of 20–29, 37–47, 62–72, and 100–110 min. The corresponding (to these dominant periods) phase propagation velocities of IGWs lie within an interval of 15–25 m/s, and the horizontal wavelengths vary from 52 to 99 km within periods of 35 to 110 min, respectively.