Discrimination of sedimentary facies by association analysis

The ability of association analysis to discriminate sedimentary facies was tested on Purdy's modal analyses of modern sediments of the Great Bahama Bank. Purdy's data set has served in the past as a standard reference for evaluating various multivariate classification algorithms. In order to adapt Purdy's data to association analysis, the percent abundance of the 12 constituents was converted to binary form by dichotomizing each variable on its mean value. The results obtained by association analysis are virtually identical to those obtained by Purdy and other authors. The same four main sedimentary facies were discriminated; 86% of the samples were identically classified (97% when misclassified borderline cases are counted as matches); the total partition variance of the classification is only negligibly greater (4%); and the grouping of the variables yielded the same four groups. The rank order of the three division-attributes responsible for the sample classification is fines, oolites, and corals. Association analysis has been employed by other authors to differentiate meaningful facies groups in studies of ancient reef carbonates, modern reef sediments, and heavy minerals in stream sediments. In all these studies, the results were found to be compatible with those obtained by using the continuous quantitative measurements, indicating that qualitative binary data may often be sufficient for the purpose of facies discrimination in many branches of geology and that association analysis is an effective method for this purpose.     

An internal variable model for the creep of rocksalt

Summary The creep strain rate of rocksalt, like that of other ductile crystalline materials, can be described by a power law equation of the type ( ) ⁿ , where the active stress is the difference between the total deviatoric applied stress and an internal stress _i . In this paper, the origin and the nature of this internal stress, which develops during inelastic deformation of the material, are discussed. It is shown that this internal stress can serve as an internal (or state) variable in the constitutive model of rocksalt, which reflects the microstructure evolution of the material under the competitive action of hardening and recovery mechanisms.An analysis of experimental data, both our own and those taken from the literature, demonstrates that such a law is able to correctly reproduce rocksalt creep test results in the steady-state domain. The proposed model is in accordance with the macroscopic and microscopic behavior of salt, and with direct measurements of the internal stresses made by others on this material.     

The use of principle component analyses in characterising trace and major elemental distribution in a 55 kyr peat deposit in tropical Australia: Implications to paleoclimate

The Lynch’s Crater peat deposit in NE-Australia is a sensitive environmental archive located in the tropical Southern Hemisphere. This unique deposit illustrates that local and regional changes had a profound effect on the local Australian ecosystem over the past 55 kyr. To obtain a proxy of past climate changes, trace and major element geochemistry analyses were applied to a 13 m peat core from the crater. Principle component analysis (PCA) was used to identify the main factors that control elemental distribution in the peat and to add interpretative strength to the geochemical behavior of selected major and trace elements. For example, Sc, Al, Cu, and Pb were found to be related to increased erosion of the basin soils, and from this, several periods of significant flux from atmospheric input and/or terrigenous run-off were identified. Geochemically mobile elements during rock weathering and pedogenesis, such as Mg, Ca, and Sr helped to identify the peat ombrotrophic-minerotrophic boundary at ∼1.5 m depth and offered important information about fluxes of these nutrients to the mire and their dynamics within the deposit. Arsenic and V comparisons between the peat record (high concentrations in some peat sections) and in local basin rocks (very low concentrations), suggested the presence of a long range, atmospheric dust source early in the formation of the mire. The Lynch’s Crater peat record presents a continuous record of environmental change in tropical Australia and contributes new understanding to geochemical processes in peatlands.     

The impact of shrimp trawling and associated sediment resuspension in mud dominated, shallow estuaries

To address the relative importance of shrimp trawling on seabed resuspension and bottom characteristics in shallow estuaries, a series of disturbance and monitoring experiments were conducted at a bay bottom mud site (2.5 m depth) in Galveston Bay, Texas in July 1998 and May 1999. Based on pre- and post-trawl sediment profiles of ⁷Be; pore water dissolved oxygen and sulfide concentration; and bulk sediment properties, it was estimated that the trawl rig, including the net, trawl doors, and “tickler chain,” excavate the seabed to a maximum depth of approximately 1.5 cm, with most areas displaying considerably less disturbance. Water column profile data in the turbid plume left by the trawl in these underconsolidated muds (85–90% porosity; <0.25 kPa undrained shear strength) demonstrate that suspended sediment inventories of up to 85–90 mg/cm² are produced immediately behind the trawl net; an order of magnitude higher than pre-trawl inventories and comparable to those observed during a 9–10 m/s wind event at the study site. Plume settling and dispersion caused suspended sediment inventories to return to pre-trawl values about 14 min after trawl passage in two separate experiments, indicating particles re-settle primarily as flocs before they can be widely dispersed by local currents. As a result of the passage of the trawl rig across the seabed, shear strength of the sediment surface showed no significant increase, suggesting that bed armoring is not taking place and the trawled areas will not show an increase in critical shear stress.     

Effects on UDP glucuronosyl transferase, glutathione transferase, DT-diaphorase and glutathione reductase activities in rainbow trout liver after long-term exposure to PCB

In the present study, long-term exposure to PCB resulted in marked induction of the xenobiotic biotransformation enzymes UDP glucuronosyl transferase, glutathione transferase and DT-diaphorase (measured as menadione reductase and DCPIP reductase) in rainbow trout 15 or 20 weeks post-injection during the experimental period. The increase of the phase II enzymes were paralleled by a marked increase of the glutathione reductase activity. These results indicate that prolonged exposure to PCB results in increased production of organo-radicals.     

Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas

The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (L_s), ranging from 19 to 93 pM with an average conditional stability constant (K_HgLs) of 10²⁸, and a weak class (L_w) ranging from 1.4 to 9.8 nM with an average K_HgLs of 10²³. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgCl_x, Hg(OH)_x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters.     

Rapid orbit determination of LEO satellites using IGS clock and ephemeris products

Different types of GPS clock and orbit data provided by the International GPS Service (IGS) have been used to assess the accuracy of rapid orbit determination for satellites in low Earth orbit (LEO) using spaceborne GPS measurements. To avoid the need for reference measurements from ground-based reference receivers, the analysis is based on an undifferenced processing of GPS code and carrier-phase measurements. Special attention is therefore given to the quality of GPS clock data that directly affects the resulting orbit determination accuracy. Interpolation of clock data from the available 15 min grid points is identified as a limiting factor in the use of IGS ultra-rapid ephemerides. Despite this restriction, a 10-cm orbit determination accuracy can be obtained with these products data as demonstrated for the GRACE-B spacecraft during selected data arcs between 2002 and 2004. This performance may be compared with a 5-cm orbit determination accuracy achievable with IGS rapid and final products using 5 min clock samples. For improved accuracy, high-rate (30 s) clock solutions are recommended that are presently only available from individual IGS centers. Likewise, a reduced latency and more frequent updates of IGS ultra-rapid ephemerides are desirable to meet the requirements of upcoming satellite missions for near real-time and precise orbit determination.     

Moment-tensor statistics of the 1997 Long Valley microearthquake swarm

Abstract. A simple, fast, moment-tensor inversion method using bandpass-filtered P-amplitudes was used to study the moment-tensor statistics of Long Valley caldera microearthquakes. The events were recorded in the summer of 1997, during a swarm in the caldera. The swarm was associated with geodetic extension, uplift, and subsequent moderate earthquake activity. The moment tensor solutions for 1,993 events were calculated using the new method. The majority of the resulting focal mechanisms appear to be explained in terms of double couple mechanisms. Since some events did exhibit considerable deviation from double-couples, the moment data were studied for their statistical significance. The moments of the actual data were compared to the moments of synthetic data with varying degrees of random noise in their spectra. The results of this study suggested that unless data from more than 20 stations are used and the earthquake epicenter is located inside or very close to the network area, moment-tensor inversion does not correctly resolve the non-double-couple components of microearthquakes. Analysis of the inversion residuals shows that the average noise in the P-wave spectra was close to 20%. The fluctuations of the volumetric components of the moment-tensor are in good agreement with those of the synthetic pure double-couples with 20% of added noise. Thus the moment-tensor statistics suggests that little if any volume change is required to explain the observed seismic energy release in the swarm. However, the statistics do show that a significant compensated-linear-vector-dipole component maybe present in the bulk of the seismicity. Given the network used in this study, such a component could not be precisely resolved for individual earthquakes. This possibility deserves further investigation because of its bearing on the nature of fluid-fault-earthquake processes in swarms.     

Issues of Globalization and Reflexivity in the Japanese Tourism Production System: The Case of Whistler,British Columbia

This article examines contemporary Japanese overseas tourism from a supplier‐side perspective using the concept of production systems. We first outline characteristics of the evolving structure of Japanese overseas tourism, with an emphasis on the global spread of Japanese travel companies. This provides a frame for presenting an empirical account of the transactional relationships in the Japanese package tour production system in Whistler, British Columbia, where Japanese tour operators play a pivotal role. We conclude that the recent expansion of Japanese travel companies is fostering the functional integration of the global tourism production system and exhibits increasing reflexivity.     

Are assemblages of black bream (Acanthopagrus butcheri) in different estuaries genetically distinct?

Samples of the estuarine-spawning teleostAcanthopagrus butcheri were collected from nine estuaries and a coastal lake, located in the Pilbara and South-western drainage divisions of Western Australia and distributed along a coastline covering a distance of nearly 2,000 km. The patterns of allozyme variation in these samples were used to explore the extent to which there was variation in the genetic compositions of black bream assemblages in geographically-isolated estuarine systems, and whether or not any such variation could be related to the geographical location or type of estuary. Although only three of 36 scorable loci (Gpi-1, Ldh andMdh-2) exhibited variation that could be used for analysis, there was considerable variation in allele frequencies at these loci among the different samples (mean F_ST=0.166). Much of the detected variation was attributable to differences between the samples collected from the two drainage divisions, which are located in very different climatic regions. Furthermore, the genetic compositions of samples from neighbouring estuaries were typically more similar to each other than to those of samples collected from more distantly-located systems. However, the assemblages in one west coast and two south coast estuaries, that are closed to the ocean for extensive periods of time during the year, all showed very similar genetic compositions. Nevertheless, it is crucial to recognise that, pairwise comparisons of samples collected from the different estuaries, both within and between the two drainage divisions, almost invariably showed statistically significant differences in allele frequencies at one or more loci. Thus, our results indicate that the local populations of black bream in individual estuaries are genetically distinct, which is probably a consequence of both a limited movement by individuals between estuaries and the effects of differences in regional and local environmental conditions.