Recent and fossil resins from New Zealand and Australia

The carbon-13 nuclear magnetic resonance spectra of fossil resins from New Zealand and Australia have been compared with those of modern and semifossilized materials. The great majority of the fossilized samples have strong spectral similarities to modern Agathis resins and to North American fossil resins, which have been attributed to Agathis. The Agathis-related spectra are different from those of modern Hymenaea and Araucaria. A small subgroup of Late Cretaceous resins from Australia and Papua New Guinea appears to derive from a different botanical source and shows strong resemblances to Claiborne amber from Arkansas. The spectral resonances of the exomethylene carbons degrade over time and on average provide an approximate measure of the geological age of Agathis-related fossil resins. © 1993 John Wiley & Sons, Inc.     

31P solid-state nuclear magnetic resonance spectroscopy of aluminum phosphate minerals

This study examines the links between ³¹P solidstate NMR studies of aluminum phosphate minerals and their crystallographic structures. We found that ³¹P isotropic chemical shift values, _iso, carry little information about mineral structures. There seems to be no relation between the chemical shift anisotropy, =₃₃–₁₁ (₃₃>₂₂> ₁₁), and indicies of phosphate-tetrahedra distortion. ³¹P¹H heteronuclear magnetic dipole interactions, on the other hand, carry important information about hydrous phosphate mineral structures, information that should prove to be quite valuable in studies of phosphate adsorbed on mineral surfaces. This interaction can be measured through a variety of qualitative and quantitative experiments. It appears that spin diffusion is so rapid that subtle differences in hydrogen-bonding environments cannot be resolved.     

Pleistocene succession of the central interior United States

The Quaternary of the continental interior of the United States is characterized by deposits from glacial ice, with associated outwash and eolian deposits, and by alluvial deposits produced by the same climatic pulses. Erosional incision of valleys occurred early in the glacial pulse, outwash deposition during the waning phase of the pulse, and soil formation during times of relative stability between the glacial pulses. These features of deposition, erosion, and soil formation are presented in a series of curves. One way the marine record could be correlated with that of the continental interior is to compare and match the physical records of both environments.     

Infrared Spectroscopy from San Fernando Observatory: He I 1083 nm, O I 1316 nm, and Fe I 1565 nm

Imaging spectroscopy of the Sun was carried out at the California State University Northridge San Fernando Observatory using an InGaAs near-IR video camera. Using the Sii 1082.71 nm and Hei 1083.03 nm lines the Evershed effect is measured simultaneously in the photosphere and the chromosphere for three sunspots; the speed of the Evershed flow is measured to be between 3 to 8 times greater in the Hei line than in the Sii line, and the direction is radially inward in the chromosphere and outward in the photosphere. Telluric absorption lines prevented a meaningful measurement of Oi 1128.7 nm limb emission, but an upper limit of 20×10^–3 B is measured for chromospheric limb emission at Oi 1316.3 nm. Zeeman splitting in Fei 1564.9 nm was observed in six sunspot umbrae, and a linear relationship between magnetic field and umbral continuum intensity is confirmed.     

Modeling global Hammond landform regions from 250‐m elevation data

In 1964, E.H. Hammond proposed criteria for classifying and mapping physiographic regions of the United States. Hammond produced a map entitled “Classes of Land Surface Form in the Forty‐Eight States, USA”, which is regarded as a pioneering and rigorous treatment of regional physiography. Several researchers automated Hammond?s model in GIS. However, these were local or regional in application, and resulted in inadequate characterization of tablelands. We used a global 250 m DEM to produce a new characterization of global Hammond landform regions. The improved algorithm we developed for the regional landform modeling: (1) incorporated a profile parameter for the delineation of tablelands; (2) accommodated negative elevation data values; (3) allowed neighborhood analysis window (NAW) size to vary between parameters; (4) more accurately bounded plains regions; and (5) mapped landform regions as opposed to discrete landform features. The new global Hammond landform regions product builds on an existing global Hammond landform features product developed by the U.S. Geological Survey, which, while globally comprehensive, did not include tablelands, used a fixed NAW size, and essentially classified pixels rather than regions. Our algorithm also permits the disaggregation of “mixed” Hammond types (e.g. plains with high mountains) into their component parts.     

Mooring developments for autonomous ocean-sampling networks

Two general-purpose mooring designs have been developed to support autonomous underwater vehicle (AUV) operations in autonomous ocean sampling networks (AOSNs). These moorings provide two-way communications between investigators and AUVs docked on the moorings or conducting survey operations some distance from the moorings. A deep-water design that incorporates an AUV dock and recharging station was built for use in the Labrador Sea during the winter of 1997/1998. This severe winter environment required a robust design that could operate unattended for six months while isolating the dock from surface wave motion. A much lighter, easier-to-deploy design was developed for use in coastal waters to extend the nearshore AOSN operating area by extending the communications network. This coastal design has been deployed without the dock component and has typically been configured for use in a small network of moorings maintained with a small research vessel. The deep-water mooring has been deployed successfully on two occasions, for short periods of time. The coastal moorings have been deployed a number of times and have proven to be quite effective. This paper describes the two moorings in detail and provides information on their performance so that interested investigators can utilize the technology where it meets their needs     

31P and 27Al solid-state nuclear magnetic resonance study of taranakite

High-resolution ²⁷Al solid-state nuclear magnetic resonance (NMR) spectroscopy indicates that aluminum in taranakite is probably restricted to six-coordinate sites. High-resolution ³¹P solid-state NMR spectroscopy reveals that phosphate groups exist in two environments in taranakite. The rate of ¹H-induced dipolar dephasing of the ³¹P signals in cross-polarization, magic-angle-spinning NMR spectra of taranakite suggests that one or more oxygens of one of two phosphates are directly protonated. The same experiments suggests that the oxygens of the second form of phosphate are not directly protonated but may be hydrogen-bond receptors. The ratio of protonated phosphate to non-protonated phosphate, as measured from ³¹P single-pulse excitation, magic-angle-spinning spectra, is approximately one to three. Current address: Department of Soil Science, 1525 Observatory Drive, University of Wisconsin-Madison, Madison, WI 53706, USA     

A Spectroscopic Redshift for the Cl 0024+16 Multiple Arc System: Implications for the Central Mass Distribution

We show that the energy-level splitting that arises from grain rotation ensures that paramagnetic dissipation acts at its maximum rate, i.e., the conditions for paramagnetic resonance are automatically fulfilled. We refer to this process as "resonance relaxation." The differences between the predictions of classical Davis-Greenstein relaxation and resonance relaxation are most pronounced for grains rotating faster than 1 GHz, i.e., in the domain in which classical paramagnetic relaxation is suppressed. This mechanism can partially align even very small grains, resulting in linearly polarized microwave emission that could interfere with efforts to measure the polarization of the cosmic microwave background.     

Recent developments in ocean data telemetry at Woods HoleOceanographic Institution

The Woods Hole Oceanographic Institution is developing techniques for telemetering oceanographic data from the deep ocean to the laboratory in near real time. Three general approaches that provide a link between subsurface instruments and surface buoys equipped with satellite transmitters are being pursued. These approaches are: cabled systems that use electromechanical cables to connect subsurface instruments to a central controller; high data rate acoustic modems to transfer information between multiple remote units and a central controller; and inductive modems that use standard mechanical mooring lines as the transmission medium between instruments deployed on the mooring and a central controller. These telemetry systems are targeted for general use by the oceanographic community and are designed to be power efficient, low in cost, and capable of integration with most oceanographic data collection systems