Behaviour of a rupture of the 21 June 2000 earthquake in South Iceland as revealed in an asphalted car park

A major earthquake (M=6.6) occurred on 21 June 2000, in South Iceland. This paper presents an unusual example of left-lateral strike-slip displacement recorded in a newly asphalted car park surface through a mechanically consistent pattern of open fissures and pressure ridges resulting from simple shear and rotation. Measurement of these features allows accurate reconstruction of the local deformation. The behaviour of the asphalt layer resembles that of analogue physical models, especially in terms of rotations induced by shear deformation. It is finally shown that through a wide range of scales some basic patterns associating rotation and opposite senses of strike-slip exist in the South Iceland Seismic Zone.     

Re-Os Isotopic Measurements at the Femtomole Level in Natural Samples

Here we describe a new chemical separation method for Os and an improved mass spectrometric procedure for Re and Os. This technique is based on the selective extraction of OsO₄ from aqueous solution in liquid bromine. Among other advantages, this procedure avoids the cumbersome distillation procedure for Os and uses only commercial "off the shelf" PFA teflon labware. Blank levels for 0.5 g sample sizes are: 0.06 pg and 0.5 pg for Os and Re respectively. Samples containing as little as 1 pg g⁻¹ Os can be analysed reliably with this method. Adaptation to other dissolution methods is also discussed.     

Relations entre les données isotopiques océaniques et l'histoire des grandes faunes européennes plio-pleistocenes

This study is the first test of correlation between the results obtained on the large Plio-Pleistocene European faunas and the main climatic stages (cold as well as temperate) demonstrated in marine isotopic records. In particular, there are cold stages which often explain the disappearance of some species, as well as climatic events that promote the substitution of some species by other groups. A rather evident parallelism appears between the European succession of large faunal associations and paleoclimatic stages revealed in oceanic areas, but some discordance occurs in the later periods. Faced with the great diversification of the Quaternary faunas, probably due to the multiplicity of climatic environments, and with global information from oceanic records, only local biostratigraphic studies will allow precise reconstruction of the different biotopes.     

Determination of predevelopment denudation rates of an agricultural watershed (Cayaguás River, Puerto Rico) using in-situ-produced Be in river-borne quartz

Accurate estimates of watershed denudation absent anthropogenic effects are required to develop strategies for mitigating accelerated physical erosion resulting from human activities, to model global geochemical cycles, and to examine interactions among climate, weathering, and uplift. We present a simple approach to estimate predevelopment denudation rates using in-situ-produced cosmogenic ¹⁰Be in fluvial sediments. Denudation processes in an agricultural watershed (Cayaguás River Basin, Puerto Rico) and a matched undisturbed watershed (Icacos River Basin) were compared using ¹⁰Be concentrations in quartz for various size fractions of bed material. The coarse fractions in both watersheds bear the imprint of long subsurface residence times. Fine material from old shallow soils contributes little, however, to the present-day sediment output of the Cayaguás. This confirms the recent and presumably anthropogenic origin of the modern high denudation rate in the Cayaguás Basin and suggests that pre-agricultural erosional conditions were comparable to those of the present-day Icacos.     

Sunken wood habitat for thiotrophic symbiosis in mangrove swamps

Large organic falls to the benthic environment, such as dead wood or whale bones, harbour organisms relying on sulfide-oxidizing symbionts. Nothing is known however, concerning sulfide enrichment at the wood surface and its relation to wood colonization by sulfide-oxidizing symbiotic organisms.In this study we combined in situ hydrogen sulfide and pH measurements on sunken wood, with associated fauna microscopy analyses in a tropical mangrove swamp. This shallow environment is known to harbour thiotrophic symbioses and is also abundantly supplied with sunken wood. A significant sulfide enrichment at the wood surface was revealed. A 72 h sequence of measurements emphasized the wide fluctuation of sulfide levels (0.1–>100 μM) over time with both a tidal influence and rapid fluctuations. Protozoans observed on the wood surface were similar to Zoothamnium niveum and to vorticellids. Our SEM observations revealed their association with ectosymbiotic bacteria, which are likely to be sulfide-oxidizers. These results support the idea that sunken wood surfaces constitute an environment suitable for sulfide-oxidizing symbioses.     

Decoupling of arsenic and iron release from ferrihydrite suspension under reducing conditions: a biogeochemical model

High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis. Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted. Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant, or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction revealed vivianite Fe(II)₃(PO₄)₂.8H₂O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results. The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully applied to recent experimental results on the release of arsenic from Bengal delta sediments.     

Ccte d'Ivoire-Ghana margin: seismic imaging of passive rifted crust adjacent to a transform continental margin

During May 1990 and January-February 1991, an extensive geophysical data set was collected over the Côte d'Ivoire-Ghana continental margin, located along the equatorial coast of West Africa. The Ghana margin is a transform continental margin running subparallel to the Romanche Fracture Zone and its associated marginal ridge—the Côte d'Ivoire-Ghana Ridge. From this data set, an explosive refraction line running ∼ 150 km, ENE-WSW between 3°55'N, 3°21'W and 4°23'N, 2°4'W, has been modelled together with wide-angle airgun profiles, and seismic reflection and gravity data. This study is centred on the Côte d'Ivoire Basin located just to the north of the Côte d'Ivoire-Ghana Ridge, where bathymetric data suggest that a component of normal rifting occurred, rather than the transform motion observed along the majority of the equatorial West African margin.
Traveltime and amplitude modelling of the ocean-bottom seismometer data shows that the continental Moho beneath the margin rises in an oceanward direction, from ∼ 24 km below sea level to ∼ 17 km. In the centre of the line where the crust thins most rapidly, there exists a region of anomalously high velocity at the base of the crust, reaching some 8 km in thickness. This higher-velocity region is thought to represent an area of localized underplating related to rifting. Modelling of marine gravity data, collected coincident with the seismic line, has been used to test the best-fitting seismic model. This modelling has shown that the observed free-air anomaly is dominated by the effects of crustal thickness, and that a region of higher density is required at the base of the crust to fit the observed data. This higher-density region is consistent in size and location with the high velocities required to fit the seismic data.     

Glacial survival of blockfields on the Varanger Peninsula, northern Norway

For more than hundred years it has been debated whether blockfields in mountain summit areas can be used to delimit the vertical extent of Pleistocene ice sheets. In this study the relationship between blockfields, developed in quartzites and sandstones on the Varanger Peninsula, northern Norway, and glacially derived features have been evaluated. Erratics and circular ablation moraines are superimposed on the blockfields and lateral meltwater channels are eroded into them. Glacial striations and other signs of glacial sculpturing are restricted to low-lying areas with channelled ice flow. Relative ages of the blockfields and the features in them are inferred, and the first measurements of in-situ produced cosmogenic nuclides from the Varanger Peninsula are reported. We conclude that the blockfields have survived underneath at least one thick, cold-based ice sheet. Thus, these blockfields cannot be used as indicators of ice-free conditions as previously suggested for southern Norway. Our results have implications for the potential for land surface preservation beneath ice sheets and for glacial reconstructions in northern Fennoscandia.     

TEM evidence for intracellular accumulation of lead by bacteria in subsurface environments

We monitored near-surface atmospheric fallout (15-cm above ground) and soil solution (at 15, 35 and 55 cm below ground) derived nanoparticles over an 8-month period by collecting the particles directly onto TEM grids in anthropogenically-influenced (vineyard) and pristine (native forest) sites in France. Particle clusters trapped on the grid were selected randomly and individual particles were binned into eight different groups (euhedral clays, weathered clays, salts, oxi-hydroxides, bacteria, non-living organic matter, aggregates and undetermined). Bacteria represent 9–23% of the collected nanoparticle area (ave. 9.4% and 18% for two atmospheric collection sites and ave. 23% for soil infiltration samples). Bacteria were most often associated with non-living organic matter and comprised a variety of morpho-types. Interestingly, 45% of all the bacteria analyzed by transmission electron microscopy and electron dispersive spectroscopy (TEM-EDX) showed the presence of intracellular grains significantly enriched in lead and phosphorus. Intracellular sequestration of Pb into polyphosphate bodies has been observed in the laboratory, but this is the first observation of this phenomenon in a natural environment. Furthermore, this suggests that microbial-bound Pb may be an important transport mechanism in subsurface environments.     

Correspondence analysis applied to volcanic aerosols

A statistical analysis of volcanic aerosol based on 1,083 variables including concentration, grain-size and site variabilities establishes correlations between sites and among chemical elements.Variation curves of element concentration show parallel behaviour. High coefficients of correlation between anions and cations confirm associations between elements.