The spatial distribution of volatiles in the Martian hydrolithosphere

In order to quantify the spatial distribution of volatiles on Mars, 2600 fluidized ejecta craters have been systematically measured, classified and mapped over the planet Mars, using 1 : 2 M scale USGS photomosaics. The latitudinal distribution of ejecta craters reveals that flower ejecta deposits (Type 1), together with low mobility ejecta, are frequently observed in the equatorial region and on ridged plains. Rampart craters (Type 2), with high mobility ejecta, occur at mid latitudes and exhibit a spatial relationship with polygonal patterns and pseudocrater areas. The increase of ejecta mobility with latitude attests for a concentration of volatiles at high latitudes. Statistical analysis shows that cratered uplands and ridged plains contain less volatile material near the surface than the underlying materials. In Chryse Planitia and Utopia Planitia the statistical study and the spatial relationships between polygonally fractured patterns, pseudocraters and the great number of high mobility ejecta deposits suggest the presence of a water-rich alluvial deposit close to the surface near the mouth of Chryse and Elysium channels. This result explains, on a more quantitative basis, the idea that fractured patterns were preferentially developed in a volatile-rich sedimentary deposits. The behaviour of volatiles, at 41 S, 257 W near Reull Vallis, exhibits a strong anomaly, with the presence of an abnormally volatile rich layer close to the surface.     

Chromium speciation in oxide-type compounds: application to minerals,gems, aqueous solutions and silicate glasses

Cr K-edge XANES spectra were obtained for a variety of Cr-bearing model compounds containing Cr(II), Cr(III), Cr(IV), Cr(V) and Cr(VI), in which the Cr-site symmetry is D4h, Oh and Td. The centroid position of the pre-edge feature is a better indicator of the Cr valence than the edge position. In Cr-rich oxides, higher-energy transitions must be excluded in order to refine a robust valence for Cr. The pre-edge for chromates is not unique and varies as a function of the CrO₄ ^2? moiety distortion, which is often related to Cr-polymerization (monochromate vs. dichromate). Both the analogy with the Mn K-pre-edge information and ab initio FEFF calculations of the pre-edge feature for Cr(III) and Cr(VI) confirm the experimental trends. This methodology is applied to the Cr K-edge pre-edge feature collected in gems (emerald, spinel and ruby), the layered minerals fuchsite and kämmererite, two Cr-bearing aqueous solutions and a set of sodo-calcic silicate glasses used for bottling sparkling white wine. In emerald and fuchsite, the Cr-site is differently distorted than its ruby or spinel counterpart. In a Cr(III)-bearing aqueous solution and sodo-calcic glass, no evidence for Cr(III) with Td and C3v symmetry is detected. However, minor amounts of chromate moieties (most likely monomeric) are detected in a glass synthesized in air. Preliminary spectra for the wine bottle glass suggest that only trace amounts of chromates might possibly be present in these glasses.     

Preserving the Ocean Circulation: Implications for Climate Policy

Climate modelers have recognized the possibility of abrupt climate changes caused by a reorganization of the North Atlantic's current pattern (technically known as a thermohaline circulation collapse). This circulation system now warms north-western Europe and transports carbon dioxide to the deep oceans. The posited collapse of this system could produce severe cooling in northwestern Europe, even when general global warming is in progress. In this paper we use a simple integrated assessment model to investigate the optimal policy response to this risk. Adding the constraint of avoiding a thermohaline circulation collapse would significantly reduce the allowable greenhouse gas emissions in the long run along an optimal path. Our analysis implies that relatively small damages associated with a collapse (less than 1% of gross world product) would justify a considerable reduction of future carbon dioxide emissions.     

Developing the ability to model acid-rock interactions and mineral dissolution during the RMA stimulation test performed at the Soultz-sous-Forêts EGS site,France

The Soultz Enhanced Geothermal System (EGS) reservoir's response to chemical stimulation is assessed by numerical simulation of coupled thermo-hydraulic-chemical processes. To assess chemical interactions between host rocks and a mixture of HCl and HF as well as its potential effects on the Soultz EGS reservoir, new modelling efforts using the FRACHEM code have been initiated. This article presents the model calibration and results. Simulations consider realistic conditions with available data sets from the EGS system at Soultz. Results indicate that the predicted amount of fracture sealing minerals dissolved by injection of a mixture of acids Regular Mud Acid (RMA) was consistent with the estimated amount from the test performed on GPK4 well at Soultz EGS site. Consequently reservoir porosity and permeability can be enhanced especially near the injection well by acidizing treatment.     

From outwash to coastal systems in the Portneuf–Forestville deltaic complex (Québec North Shore): Anatomy of a forced regressive deglacial sequence

Deglacial sequences typically include backstepping grounding zone wedges and prevailing glaciomarine depositional facies. However, in coastal domains, deglacial sequences are dominated by depositional systems ranging from turbiditic to fluvial facies. Such deglacial sequences are strongly impacted by glacio‐isostatic rebound, the rate and amplitude of which commonly outpaces those of post‐glacial eustatic sea‐level rise. This results in a sustained relative sea‐level fall covering the entire depositional time interval. This paper examines a Late Quaternary, forced regressive, deglacial sequence located on the North Shore of the St. Lawrence Estuary (Portneuf Peninsula, Québec, Canada) and aims to decipher the main controls that governed its stratigraphic architecture. The forced regressive deglacial sequence forms a thick (>100 m) and extensive (>100 km²) multiphased deltaic complex emplaced after the retreat of the Laurentide Ice Sheet margin from the study area ca 12 500 years ago. The sedimentary succession is composed of ice‐contact, glaciomarine, turbiditic, deltaic, fluvial and coastal depositional units. A four‐stage development is recognized: (i) an early ice‐contact stage (esker, glaciomarine mud and outwash fan); (ii) an in‐valley progradational stage (fjord head or moraine‐dammed lacustrine deltas) fed by glacigenics; (iii) an open‐coast deltaic progradation, when proglacial depositional systems expanded beyond the valley outlets and merged together; and (iv) a final stage of river entrenchment and shallow marine reworking that affected the previously emplaced deltaic complex. Most of the sedimentary volume (10 to 15 km³) was emplaced during the three‐first stages over a ca 2 kyr interval. In spite of sustained high rates of relative sea‐level fall (50 to 30 mm·year^?1), delta plain accretion occurred up to the end of the proglacial open‐coast progradational stage. River entrenchment only occurred later, after a significant decrease in the relative sea‐level fall rates (<30 mm·year^?1), and was concurrent with the formation and preservation of extensive coastal deposits (raised beaches, spit platform and barrier sands). The turnaround from delta plain accretion to river entrenchment and coastal erosion is interpreted to be a consequence of the retreat of the ice margin from the river drainage basins that led to the drastic drop of sediment supply and the abrupt decrease in progradation rates. The main internal stratigraphic discontinuity within the forced regressive deglacial sequence does not reflect changes in relative sea‐level variations.     

Accuracy assessment of the Mexican National Forest Inventory map: A study in four ecogeographical areas

The accuracy of the Mexican National Forest Inventory (NFI) map is derived in four distinct ecogeographical areas, using an assessment design tailored for the project. A main achievement of the design was to integrate the high diversity of classes encompassed at the most detailed subcommunity level of the classification scheme within a cost‐controlled statistically sound assessment. A hybrid double sampling strategy was applied to the 2.5 million‐ha study area. A total of 5955 reference sites were verified against their NFI map label. The availability of detailed quasi‐synchronous reference data for the 2000 Landsat‐derived NFI and the high diversity of mapped classes allowed a careful thematic analysis on the selected regions, relevant for national extrapolation. Global accuracy estimates of 64–78 per cent were registered among the four ecogeographical areas (two with mainly temperate climate and the other two with mainly tropical climate), with the lower accuracy levels found in areas more densely covered with forests. According to the estimates, the NFI map tends to underestimate the presence of temperate forest (especially oak) and overestimate the presence of tropical forest in the areas investigated. The analysis of confusions reveals difficulties in unambiguously interpreting or labelling forests with secondary vegetation, herbaceous and/or shrub‐like vegetation as well as distinguishing between aquatic vegetation types. The design proved useful from the perspective of accuracy assessments of regional maps in biodiverse regions.     

Coupes équilibrées à travers le massif subalpin de la Chartreuse

Résumé

Pour étudier la tectonique des chaînes subalpines du Nord, et proposer un modèle cinématique régional, nous avons utilisé les résultats d’une expérience géophysique réalisée en 1985, et les observations géologiques de surface publiées à ce jour. Ces données ont été analysées de manière à préciser le style tectonique, le positionnement des failles par rapport aux horizons stratigraphiques et le schéma de branchement des failles. La construction simultanée d’une coupe interprétative, d’une coupe restaurée et d’une carte de branchement des failles a permis d’estimer l’amplitude du raccourcissement par la méthode des coupes équilibrées. Au niveau du Nord de la Chartreuse, la valeur minimale du raccourcissement global est de 14 km, 4 km étant associés au système chevauchant du Jura et 10 km à celui du massif des Bornes et des Bauges. Compte tenu des imprécisions existant sur les données utilisées, trois modèles cinématiques, qui correspondent à une plage de raccourcissement comprise entre 14 et 25 km, sont proposés.     

Sunken wood habitat for thiotrophic symbiosis in mangrove swamps

Large organic falls to the benthic environment, such as dead wood or whale bones, harbour organisms relying on sulfide-oxidizing symbionts. Nothing is known however, concerning sulfide enrichment at the wood surface and its relation to wood colonization by sulfide-oxidizing symbiotic organisms.In this study we combined in situ hydrogen sulfide and pH measurements on sunken wood, with associated fauna microscopy analyses in a tropical mangrove swamp. This shallow environment is known to harbour thiotrophic symbioses and is also abundantly supplied with sunken wood. A significant sulfide enrichment at the wood surface was revealed. A 72 h sequence of measurements emphasized the wide fluctuation of sulfide levels (0.1–>100 μM) over time with both a tidal influence and rapid fluctuations. Protozoans observed on the wood surface were similar to Zoothamnium niveum and to vorticellids. Our SEM observations revealed their association with ectosymbiotic bacteria, which are likely to be sulfide-oxidizers. These results support the idea that sunken wood surfaces constitute an environment suitable for sulfide-oxidizing symbioses.     

Ontogenic variation and effect of collection procedure on leaf biomechanical properties of Mediterranean seagrass Posidonia oceanica (L.) Delile

Leaf mechanical traits are important to understand how aquatic plants fracture and deform when subjected to abiotic (currents or waves) or biotic (herbivory attack) mechanical forces. The likely occurrence of variation during leaf ontogeny in these traits may thus have implications for hydrodynamic performance and vulnerability to herbivory damage, and may be associated with changes in morphologic and chemical traits. Seagrasses, marine flowering plants, consist of shoot bundles holding several leaves with different developmental stages, in which outer older leaves protect inner younger leaves. In this study we examined the long‐lived seagrass Posidonia oceanica to determine ontogenic variation in mechanical traits across leaf position within a shoot, representing different developmental stages. Moreover, we investigated whether or not the collection procedure (classical uprooted shoot versus non‐destructive shoot method: cutting the shoot without a portion of rhizome) and time span after collection influence mechanical measurements. Neither collection procedure nor time elapsed within 48 h of collection affected measurements of leaf biomechanical traits when seagrass shoots were kept moist in dark cool conditions. Ontogenic variation in mechanical traits in P. oceanica leaves over intermediate and adult developmental stages was observed: leaves weakened and lost stiffness with aging, while mid‐aged leaves (the longest and thickest ones) were able to withstand higher breaking forces. In addition, younger leaves had higher nitrogen content and lower fiber content than older leaves. The observed patterns may explain fine‐scale within‐shoot ecological processes of leaves at different developmental stages, such as leaf shedding and herbivory consumption in P. oceanica.