Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

黑子磁流体静力学的一个模型

本文对Ｏｓｈｅｒｏｖｉｃｈ的黑子返回磁通量模型作了适当的修改，使用黑子中心作为边界条件，用五种观测结果，导出了理论模型所需的五个主要参量，用半经验方法求得了黑子静力学模型的磁场、压力和温度等物理量．将此模型应用于一个中等大小的圆形对称黑子，可得到一个特解，结果发现我们的模型既能满足黑子的磁性质，同时又能满足合理的热力学量分布．     

Evolution of Electric Currents Associated with Two M-Class Flares

Using one-minute cadence vector magnetograms from Big Bear Solar Observatory (BBSO), we analyze the temporal behavior of derived longitudinal electric currents associated with two flares on July 26, 2002. One of the events is an M1.0 flare which occurred in active region NOAA 10044, while the other is an M8.7 flare in the adjacent region 10039. Rapid changes of magnetic fields in the form of flux emergence are found to be associated with both of these events. However, the temporal behavior of electric currents are very different. For the M1.0 flare, the longitudinal electric current density drops rapidly near the flaring neutral line; while for the M8.7 flare, the current density rapidly increases, confirming the picture of the current-carrying flux emergence. We offer a possible explanation for such a difference: magnetic reconnection at different heights for the two events, near the photosphere for the M1.0 flare, and higher up for the M8.7 flare.     

OSIRIS: AO-assisted integral-field spectroscopy at the Keck Observatory

OSIRIS (OH-Suppressing Infra-Red Integral-field Spectrograph) is a new facility instrument for the Keck Observatory. After seeing first light in February 2005, OSIRIS is currently undergoing commissioning. OSIRIS provides the capability of performing three-dimensional spectroscopy in the near-infrared z, J, H, and K bands at the resolution limit of the Keck II telescope, which is equipped with adaptive optics and a laser guide star. The science case for OSIRIS is summarized, and the instrument and associated data reduction software are described.     

多条太阳光球FeI线在磁场中形成及形成深度的综合分析(Ⅰ)

针对多通道滤光器太阳磁场望远镜的磁场观测定标及掌握(所采用的)谱线特征之需要,取VAL宁静太阳大气模型计算了7条Fel光球线的Stokes轮廓、形成深度、贡献函数分布,从而较为系统地对多条反常及正常Zeeman线的特征及性质作出了分析与总结,解释了在磁光效应影响下Stokes Q,U参量的形成深度曲线在近线心区域处出现陡峭峰值的原因。     

CARBON DYNAMICS OF WETLAND IN THE SANJIANG PLAIN

1INTRODUCTIONWetlandsplayanimportant roleintheprocessofcar-bonstorage.Thetotalcarbonstoredindifferentkindsofwetlandsisabout15%-35%ofthetotalcarboninthegloballandsoils(POSTetal.,1982;GORHAM,1991).Inaddition,wetlandsaresignificantnaturalsources fortheatmospheric CH4 (MOORE,1994).It isestimatedthatabout110×1012gCH4 originates fromanaerobicdecompositioninthenaturalwetlands,CH4 emission fromthenaturalwetlandsis15%-30%oftheglobalCH4 emission andtheCH4 emission from thepeat land at hi…     

SORPTION AND DESORPTION CHARACTERISTICS OF CADMIUM BY FOUR DIFFERENT SOILS IN NORTHEAST CHINA

1IN TR O D U C TIO NA s a persistentand toxic pollutant, cadm ium (C d) canresultin m any adverse health effects in a variety oftis-suesand organssuch asthe lung,kidney,urinary,blad-der,pancreas,breast and prostate (SA TA R U G etal.,2003).C adm ium in so…     

FITS、BMP和SCR图象格式及相互转换

本文详细介绍图象的ＦＩＴＳ格式、ＢＭＰ格式和ＳＣＲ格式。ＦＩＴＳ格式已经是天文界的通用格式，几乎所有的天文软件包都支持这一格式，而ＢＭＰ格式在ＰＣ计算机上有广泛的运用，有大量ＰＣ软件支持ＢＭＰ图象的显示，处理和打印。云南天文台的ＳＣＲ格式是ＰＣ机采集ＣＣＤ图象所使用的格式。实现这三种格式的相互转换，就可以自由的将ＣＣＤ图象在ＰＣ机和工作站上进行各种处理。转换的包括图象头和图象数据的转换，其关键在于交换数据的高低字节。     

卫星电视授时系统及精度估计

我国已建成短波、长波授时台，进行毫秒级、微秒级的时间服务．随着现代科技和经济的发展，上述方法已不能满足国家及国际交流的需要．本文提出卫星电视授时系统，同步卫星定位精度小于１１０ｍ，卫星授时精度为亚微秒。两原子钟利用卫星进行时刻同步，其精度与两原子钟的距离有关，相距３千多公里的两钟同步精度小于３５ｎｓ，相距数百公里的两原子钟同步精度小于２０ｎｓ