Initial interpretation of Titan plasma interaction as observed by the Cassini plasma spectrometer: Comparisons with Voyager 1

The Cassini plasma spectrometer (CAPS) instrument made measurements of Titan's plasma environment when the Cassini Orbiter flew through the moon's plasma wake October 26, 2004 (flyby TA). Initial CAPS ion and electron measurements from this encounter will be compared with measurements made by the Voyager 1 plasma science instrument (PLS). The comparisons will be used to evaluate previous interpretations and predictions of the Titan plasma environment that have been made using PLS measurements. The plasma wake trajectories of flyby TA and Voyager 1 are similar because they occurred when Titan was near Saturn's local noon. These similarities make possible direct, meaningful comparisons between the various plasma wake measurements. They lead to the following: (A) The light and heavy ions, H⁺and N⁺/O⁺, were observed by PLS in Saturn's magnetosphere in the vicinity of Titan while the higher mass resolution of CAPS yielded H⁺ and H₂⁺as the light constituents and O⁺/CH₄⁺ as the heavy ions. (B) Finite gyroradius effects were apparent in PLS and CAPS measurements of ambient O⁺ ions as a result of their absorption by Titan's extended atmosphere. (C) The principal pickup ions inferred from both PLS and CAPS measurements are H⁺, H₂⁺, N⁺, CH₄⁺ and N₂⁺. (D) The inference that heavy pickup ions, observed by PLS, were in narrow beam distributions was empirically established by the CAPS measurements. (E) Slowing down of the ambient plasma due to pickup ion mass loading was observed by both instruments on the anti-Saturn side of Titan. (F) Strong mass loading just outside the ionotail by a heavy ion such as N₂⁺ is apparent in PLS and CAPS measurements. (G) Except for the expected differences due to the differing trajectories, the magnitudes and structures of the electron densities and temperatures observed by both instruments are similar. The high-energy electron bite-out observed by PLS in the magnetotail is consistent with that observed by CAPS.     

The second order characteristic condition for plastic flow

In this paper the second order characteristic (discontinuous bifurcation) condition is derived for the granular flow (fully plastic) equations. This second order bifurcation equation is shown to be formally identical to the first order localization requirement during steady elastoplastic deformation provided the elastic compliance tensor is substituted for the product of the plastic multiplier with the flow Hessian. For isotropic yield and flow functions the invariant form of the characteristic condition is given in detail, as well as an alternative expression in adapted co‐ordinates. The characteristic condition can be regarded as defining a hardening function which is maximized to identify the critical angles. When the method is applied to 3D Coulomb flow, Mohr's 3D fracture plane conditions are obtained uniquely. Copyright © 2003 John Wiley & Sons, Ltd.     

A spectroscopic study of the microorganism model of interstellar grains

The microorganism model of interstellar grains is investigated by spectroscopy from the infrared (IR), visible to the ultraviolet (UV) wave regions.E. coli, yeast and spores ofBacillus subtilis exhibit absorption bands at =3.1 and 9.7 m; they also exhibit several absorptions at 68 m which are in agreement with the observed IS extinction curves.To obtain the extinction curves in the visible and UV regions, dry films of microorganism are prepared on a MgF₂ plate or synthesized quartz plate and their spectra measured. In the wavelength region 190400 nm, conventional spectrophotometers are adopted for the measurement. The extinction curve of the film ofE. coli is similar to the observed IS curve.For the wave-range 100<<400 nm, a vacuum UV spectrometer is adopted to avoid absorptions due to O₂ in the atmosphere. The extinction spectra by this method are in agreement with the result obtained by the conventional method where comparison is possible. The extinction curves ofE. coli and yeast are such that they incrase towards the short wavelength and exhibit a peak at -190 nm, which is different from the well-known IS peak at =220 nm. It remains to be seen whether interstellar low temperatures (1040 K) can shift the peak position in the extinction curve of biochemical materials.     

The effects of metamorphism on O and Fe isotope compositions in the Biwabik Iron Formation, northern Minnesota

The Biwabik Iron Formation of Minnesota (1.9 Ga) underwent contact metamorphism by intrusion of the Duluth Complex (1.1 Ga). Apparent quartz–magnetite oxygen isotope temperatures decrease from ∼700°C at the contact to ∼375°C at 2.6 km distance (normal to the contact in 3D). Metamorphic pigeonite at the contact, however, indicates that peak temperatures were greater than 825°C. The apparent O isotope temperatures, therefore, reflect cooling, and not peak metamorphic conditions. Magnetite was reset in δ¹⁸O as a function of grain size, indicating that isotopic exchange was controlled by diffusion of oxygen in magnetite for samples from above the grunerite isograd. Apparent quartz–magnetite O isotope temperatures are similar to calculated closure temperatures for oxygen diffusion in magnetite at a cooling rate of ∼5.6°C/kyr, which suggests that the Biwabik Iron Formation cooled from ∼825 to 400°C in ∼75 kyr at the contact with the Duluth Complex. Isotopic exchange during metamorphism also occurred for Fe, where magnetite–Fe silicate fractionations decrease with increasing metamorphic grade. Correlations between quartz–magnetite O isotope fractionations and magnetite–iron silicate Fe isotope fractionations suggest that both reflect cooling, where the closure temperature for Fe was higher than for O. The net effect of metamorphism on δ¹⁸O–δ⁵⁶Fe variations in magnetite is a strong increase in δ¹⁸O_Mt and a mild decrease in δ⁵⁶Fe with increasing metamorphic grade, relative to the isotopic compositions that are expected at the low temperatures of initial magnetite formation. If metamorphism of Iron Formations occurs in a closed system, bulk O and Fe isotope compositions may be preserved, although re-equilibration among the minerals may occur for both O and Fe isotopes. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Kinetics of Cd sorption, desorption and fixation by calcite: A long-term radiotracer study

Time-dependent sorption and desorption of Cd on calcite was studied over 210 days utilizing ¹⁰⁹Cd as a tracer to distinguish between ‘labile’ and ‘non-labile’ forms of sorbed Cd. Stabilizing the calcite suspensions for 12 months under atmospheric P_CO2 and controlled temperature was necessary to reliably follow Cd dynamics following initial sorption. Results revealed time-dependant Cd sorption and marked desorption hysteresis by calcite under environmentally relevant conditions. Data obtained were fitted to a first-order kinetic model and a concentric shell diffusion model. Both models described the progressive transfer of Cd²⁺ to a less reactive form within calcite and subsequent desorption of Cd subject to different initial contact times. The kinetic model provided a better fit to the combined sorption and desorption data (R² = 0.992). It differentiates between two ‘pools’ of sorbed Cd²⁺ on calcite, ‘labile’ and ‘non-labile’, in which labile sorbed Cd is in immediate equilibrium with the free Cd²⁺ ion activity in solution whereas non-labile Cd is kinetically restricted. For the diffusion model (R² = 0.959), the rate constants describing Cd dynamics in calcite produced a half-life for Cd desorption of ∼175 d, for release to a ‘zero-sink’ solution. Results from this study allow comment on the likely mechanisms occurring at the calcite surface following long-term Cd sorption.     

The Fe-C system at 5 GPa and implications for Earth’s core

Earth’s core may contain C, and it has been suggested that C in the core could stabilize the formation of a solid inner core composed of Fe₃C. We experimentally examined the Fe-C system at a pressure of 5 GPa and determined the Fe-C phase diagram at this pressure. In addition, we measured solid metal/liquid metal partition coefficients for 17 trace elements and examined the partitioning behavior between Fe₃C and liquid metal for 14 trace elements. Solid metal/liquid metal partition coefficients are similar to those found in one atmosphere studies, indicating that the effect of pressure to 5 GPa is negligible. All measured Fe₃C/liquid metal partition coefficients investigated are less than one, such that all trace elements prefer the C-rich liquid to Fe₃C. Fe₃C/liquid metal partition coefficients tend to decrease with decreasing atomic radii within a given period. Of particular interest, our 5 GPa Fe-C phase diagram does not show any evidence that the Fe-Fe₃C eutectic composition shifts to lower C contents with increasing pressure, which is central to the previous reasoning that the inner core may be composed of Fe₃C.     

On the recovery of surface wave by pressure transfer function

Except the commonly selected pressure transfer function derived from the linear wave theory, a previous study on the pressure transfer function for recovering surface wave from underwater pressure transducer suggested that the pressure transfer function is a function of frequency parameter only. With careful analysis, this study showed that the pressure transfer function should include a transducer submergence parameter as that given by the linear theory. It was found that the previously suggested empirical formula should be restricted to measurements with the pressure transducer close to the surface; otherwise overestimation of wave height would result. Field measurements were carried out with an acoustic wave gauge and a synchronized pressure transducer located at various depths with submergence parameter close to 1 (near the sea floor). It was shown that the previous one-parameter empirical formula might overestimate the significant wave height by more than 30%. This study found that with deep-water wave bursts excluded, the transfer function based on the linear wave theory provided a fairly good estimation on the significant wave heights, with an average deviation of 3.6%.