Models of the REE distribution in the black shale Bazhenov Formation of the West Siberian marine basin,Russia

Rare-earth elements abundance in black shales of the Upper Jurassic (Tithonian Stage)–Lower Cretaceous (Berriassian Stage) Bazhenov Formation is discussed. This formation is the principal oil source rocks of West Siberia. The deposits within the formation can be subdivided into two main marine groups: (a) moderately hemipelagic deposits (clayey-siliceous, including phosphatic and carbonate rocks) and low-density distal clayey turbidites (argillites), both are considered as normal and (b) silty argillites and clayey-silt rocks, which are channel deposits and considered as anomalous. The hemipelagic rocks of normal sections, which are enriched in the rare-earth elements (REE), accumulated under both slow rates of sedimentation (clayey-siliceous rocks) and faster rates of sedimentation (argillites). The channel deposits of anomalous sections, which are impoverished in the REE, accumulated exclusively under fast rates of sedimentation.Within the hemipelagic group the rate of sedimentation of the argillites was faster than of the clayey-siliceous rocks, but the REE concentration in the former rocks (140.4 ppm) is higher than in the latter group (97.4 ppm). The argillites are more than twice enriched in clayey material than clayey-siliceous rocks. It is likely that the clay fraction was the main carrier of REE in these rocks. In the channel group of rocks, the REE abundance in clayey-silt rocks (21.2 ppm) is lower than in the silty argillite (84.6 ppm), in which the clay content is elevated.With respect to redox potential the Bazhenov Formation rocks can be subdivided further into three groups, based on the degree of pyritization index (DOP): (1) the highly reducing clayey-siliceous rocks of normal sections, with high DOP; (2) the substantially reducing argillites and carbonate rocks of normal sections, with intermediate DOP; (3) the moderately reducing rocks of anomalous sections with low DOP. The rocks with the high DOP (group 1) are characterized by ΣLREE/Σ(M+H)REE ratios between 7.37 and 7.5, whereas the rocks with the lower DOP (group 2 and 3) are characterized by ΣLREE/Σ(M+H)REE ratios between 12.8 and 13.5. Negative Ce anomalies are either small or absent in all deposits, which is typical for reducing conditions.Thus, the Bazhenov Formation exemplifies the complex depositional conditions that influence the REE concentration in black shale. However, it is this very complexity that has contributed to the development of six separate depositional models (REE contents in ppm are given in brackets). (1) Phosphatic clayey-siliceous rocks of normal sections (367.95); (2) argillites of normal sections (130.73); (3) clayey-siliceous rocks of normal sections (85.97); (4) carbonate rocks, largely dolomites of normal sections (23.23); (5) silty argillites of anomalous sections (78.7) and (6) clayey-silt rocks of anomalous sections (19.66).     

宁芜盆地火山-次火山岩的锆石U-Pb年龄、Hf同位素组成及其地质意义

宁芜火山盆地是长江中下游重要的火山盆地之一,在盆地内自下而上依次发育龙王山组、大王山组、姑山组和娘娘山组火山岩和若干个同源次火山岩或小侵入岩体。本文对宁芜盆地火山-次火山岩进行了详细的锆石U-Pb年龄和Hf同位素地球化学研究。研究结果表明,大王山组粗安岩锆石U-Pb年龄为130.3±0.9Ma,姑山组两个粗安岩锆石U-Pb年龄分别为128.2±1.3Ma和128.5±1.8Ma,另外三个侵入岩年龄分别为127.1±1.2Ma、128.3±0.6Ma和128.2±1.0Ma,均为早白垩纪。综合前人成果,认为长江中下游地区火山盆地内火山活动的时限在135～124Ma之间,不存在侏罗纪岩浆活动。宁芜盆地火山岩和侵入岩的锆石176Hf/177Hf值在0.282502～0.282673范围内,εHf(t)变化为-6.9～-0.7,显示岩浆源自于岩石圈富集地幔部分熔融并在上升过程中受地壳物质的混染,为岩石圈伸展环境的产物。     

Melanterite and szomolnokite as weathering products of pyrite from the Bazhenovo Formation

Weathering of pyrite in the core recovered from black shales of the Bazhenovo Formation (Upper Jurassic-Lower Cretaceous) in the West Siberian marine basin promoted the successive formation of melanterite (FeSO₄ · 7H₂O) and szomolnokite (FeSO₄ · H₂O). Szomolnokite was detected in West Siberia for the first time.     

Temporal variation of suspended sediment transport in the Koga catchment,North Western Ethiopia and environmental implications

Event sediment transport and yield were studied for 45 events in the upstream part of the 260 km² agricultural Koga catchment that drains to an irrigation reservoir. Discharge and turbidity data were collected over a period of more than a year, accompanied by grab sampling. Turbidity was very well correlated with the sediment concentrations from the samples (r = 0.99), which allowed us to estimate the temporal patterns of sediment concentrations within events. The hysteresis patterns between discharge and sediment concentrations were analysed to provide insight into the different sediment sources. Anticlockwise patterns are the dominant hysteresis patterns in the area, suggesting smaller contributions of suspended sediment from the river channels than from the hillslopes and agricultural areas. Complicated types of hysteresis patterns were mostly observed for long events with multiple peaks. For a given discharge, sediment yields in August and September, when the catchment was almost completely covered with vegetation, were much smaller than during the rest of the rainy season. The hysteresis patterns and timing suggest that the sediment availability from the agricultural areas and hillslopes affects sediment yields more strongly than does peak discharge. Two distinct types of sediment rating curves were observed for the season when the agricultural land was covered with vegetation and when it was not, indicating the dominating contribution of land use/cover to sediment yields in the catchment. The rate of suspended sediment transport in the area was estimated as 25.6 t year^?1 ha^?1. Copyright © 2013 John Wiley & Sons, Ltd.     

西藏南部晚始新世打拉埃达克质花岗岩及其构造动力学意义

打拉二云母花岗岩岩体位于雅拉香波穹隆的东南,侵入到中生代以前的变质岩系(眼球状花岗质片麻岩和石榴黑云母片麻岩)和特提斯沉积岩(页岩和砂岩)中,主要由石英、斜长石、钾长石、黑云母和白云母组成,形成于～44.3Ma。打拉二云母花岗岩地球化学特征表明:打拉花岗岩具有高Al_2O_3(16.0%～17.0%)、Na_2O/K_2O(1.2)以及A/CNK比值(1.05),表明打拉花岗岩为富钠过铝质花岗岩;轻稀土(LREE)富集,重稀土(HREE)相对亏损,HREE中的Ho到Lu元素有变平的特征((Ho/Lu)_N=1.11～1.46);具有微弱或无Eu异常,Eu/Eu~*=0.87～0.95;较高的初始Sr同位素比值(~(87)Sr/~(86)Sr(i)=0.71754～0.71785)和较低的初始Nd比值(ε_(Nd)(i)=-9.15～-12.4)。打拉花岗岩具有高Sr含量(为355×10~(-6)～416×10~(-6))和Sr/Y的比值(59.1～71.5)、高La/Yb比值、低Y及HREE亏损的特征,与埃达克质花岗岩类似。上述特征表明打拉花岗岩是在较高压力条件下,以角闪岩为主的深部岩石部分熔融的结果。     

The geoid in southeastern Brazil and adjacent regions: new constraints on density distribution and thermal state of the lithosphere

Least-squares collocation technique was used to process regional gravity data of the SE South American lithospheric plate in order to map intermediate (10–2000 km) wavelength geoid anomalies. The area between 35–10° S and 60–25° W includes the Paraná CFB Province, the Southern São Francisco Craton and its marginal fold/thrust belts, the Brazilian continental margin and oceanic basins. The main features in the geoid anomaly map are: (a) Paraná CFB Province is characterized by a 1000 km long and 500 km wide, NE-trending, 9 m-amplitude negative anomaly which correlates with the distribution of sediments and basalts within the Paraná basin. (b) A circular (600–800 km in diameter) positive, 8 m-amplitude geoid anomaly is located in the southern S. Francisco craton and extends into the northeastern border of the Paraná CFB Province. This anomaly partially correlates with Alto Paranaíba Igneous Province (APIP), where alkalic volcanism and tholeiitic dikes of ages younger than 80 Ma are found and where a low-velocity zone in the mantle has been mapped using seismic tomography. This positive geoid anomaly extends towards the continental margin at latitude 21° S and joins a linear sequence of short wavelength positive geoid anomalies associated with Vitoria–Trindade seamounts. (c) A NE-trending, 1000 km long and 800 km wide, 4 m-amplitude, positive geoid anomaly, which is located along the southeastern coast of Brazil, from latitude 24 to 35° S. The northern part of this anomaly correlates with the Ponta Grossa Arch and Florianopolis dyke swarm provinces. The age of this intrusive volcanism is 130–120 Ma. (d) A circular positive anomaly with 9 m of amplitude, located over the Rio Grande and Uruguay shields and offshore Pelotas basin. Few alkaline intrusives with ages between 65 and 80 Ma are found in the region and apatite fission track ages in basement rocks indicates cooling at around 30 Ma. A semi-quantitative analysis of the observed geoid anomalies using isostatic considerations suggests that the mechanism which generated Paraná CFB Province did not change, in a significant manner, the lithospheric thermal structure, since the same geoid pattern observed within this province continues northward over the Neoproterozoic fold/thrust belts systems separating the São Francisco and Amazon cratons. Therefore, this observation favours Anderson’s idea of rapid basaltic outpouring through a pull-apart mechanism along a major suture zone. A thermal component may still be present in the Southern São Francisco Craton and in the Rio Grande Shield and contiguous continental margins, sites of Tertiary thermal and magmatic reactivations.     

Radiating anisotropic two-fluid model universes involving rotation in general relativity

Radiating anisotropic two-fluid model universes coupled with a scalar field when a slow rotation is introduced in them are studied here, where the anisotropic pressure is generated by the presence of two non-interacting perfect fluids which are in relative motion with respect to each other. Special discussion is made of the physically interesting class of models in which one fluid is a comoving radiative perfect fluid which is taken to model the cosmic microwave background and the second a non-comoving perfect fluid which will model the observed material content of the Universe. Here we take up four analytic solutions. The effects of rotation on these models are studied and the reactions of the scalar and the radiation fields with respect to the rotational motion are discussed. Analysis on the rotational perturbations are also made, in the course of which the amount of anisotropy induced in the pressure distribution by a small deviation from the Friedmann metric is also investigated. It is shown that such anisotropies could grow faster than the expansion of the Universe. The rotating models we obtain here are found to be theoretically satisfactory and they may be taken as physically acceptable models.     

Standardization of a NaI(Tl) scintillation detector and its use on environments for Geology teaching in a Brazilian university

This paper describes analytical protocols adopted for calibrating a portable gamma rays spectrometer using a 2? × 2? NaI(Tl) scintillation detector for performing exploration and environmental surveys. The steps involved the determination of counting times with good accuracy, calibration in energy and concentration, and data conversion to effective dose (Ed) for monitoring the radioactivity levels in the air, for indoor and outdoor environments. The χ² test was applied to the counting rate data acquired for ten different readings, allowing determine the greater accuracy among them. Some standards yielded values above of the detection limit for calibrating the K, eU, and eTh windows, whereas empirical equations provided satisfactory results. The count rates in these windows were obtained in selected environments related to Geology teaching activities in a Brazilian university. Then, they were converted to Ed, showing the applicability of the adopted procedures for environmental surveys. The radiological monitoring showed two sites exhibiting Ed values above the WHO guideline reference value of 1 mSv/year. The first was in a minerals and rocks museum and the second in a deposit (litoteca) dedicated to the rocks storage. Thus, the members of the public are only occasionally exposed to the natural gamma radiation there. Additionally, the Ed values are much lower than the recommended limit of 20 mSv/year for occupationally exposed individuals.