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Detlef Wolf 《Geophysical Journal International》1985,80(1):275-279
Summary. Boussinesq's problem is solved for a uniform and incompressible Maxwell half-space subject to an external gravity field. The solution is based on momentum equations which account for stress advection in the hydrostatically pre-stressed continuum during its deformation. The analysis shows that disregarding the pre-stress term renders the theoretical stress distribution incorrect and the deformation singular in the inviscid limit of the Maxwell continuum. Our solution is contrasted with a recently published alternative solution of the same problem, where regularity in the inviscid limit was forced by modified boundary conditions. 相似文献
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Accurate U-Pb Age and Trace Element Determinations of Zircon by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry 总被引:190,自引:0,他引:190
Honglin Yuan Shan Gao Xiaoming Liu Huiming Li Detlef Günther Fuyuan Wu 《Geostandards and Geoanalytical Research》2004,28(3):353-370
Various zircons of Proterozoic to Oligocene ages (1060-31 Ma) were analysed by laser ablation-inductively coupled plasma-mass spectrometry. Calibration was performed using Harvard reference zircon 91500 or Australian National University reference zircon TEMORA 1 as external calibrant. The results agree with those obtained by SIMS within 2s error. Twenty-four trace and rare earth elements (P, Ti, Cr, Y, Nb, fourteen REE, Hf, Ta, Pb, Th and U) were analysed on four fragments of zircon 91500. NIST SRM 610 was used as the reference material and 29 Si was used as internal calibrant. Based on determinations of four fragments, this zircon shows significant intra-and inter-fragment variations in the range from 10% to 85% on a scale of 120 μm, with the variation of REE concentrations up to 38.7%, although the chondrite-normalised REE distributions are very similar. In contrast, the determined age values for zircon 91500 agree with TIMS data and are homogeneous within 8.7 Ma (2 s ). A two-stage ablation strategy was developed for optimising U-Pb age determinations with satisfactory trace element and REE results. The first cycle of ablation was used to collect data for age determination only, which was followed by continuous ablation on the same spot to determine REE and trace element concentrations. Based on this procedure, it was possible to measure zircon ages as low as 30.37 0.39 Ma (MSWD = 1.4; 2 s ). Other examples for older zircons are also given. 相似文献
4.
Marcel Guillong Kathrin Hametner Eric Reusser Stephen A. Wilson Detlef Günther 《Geostandards and Geoanalytical Research》2005,29(3):315-331
New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP. 相似文献
5.
Partitioning of trace elements between rutile and silicate melts: Implications for subduction zones 总被引:9,自引:0,他引:9
Mineral/melt trace element partition coefficients were determined for rutile (TiO2) for a large number of trace elements (Zr, Hf, Nb, Ta, V, Co, Cu, Zn, Sr, REE, Cr, Sb, W, U, Th). Whilst the high field strength elements (Zr, Hf, Nb, Ta) are compatible in rutile, other studied trace elements are incompatible (Sr, Th, REE). In all experiments we found DTa > DNb, DHf > DZr and DU > DTh. Partition coefficients for some polyvalent elements (Sb, W, and Co) were sensitive to oxygen fugacity. Melt composition exerts a strong influence on HFSE partition coefficients. With increasing polymerization of the melt, rutile/melt partition coefficients for the high field strength elements Zr, Hf, Nb and Ta increase about an order of magnitude. However, DNb/DTa and DHf/DZr are not significantly affected by melt composition. Because DU ? DTh, partial melting of rutile-bearing eclogite in subducted lithosphere may cause excesses of 230Th over 238U in some island arc lavas, whereas dehydration of subducted lithosphere may cause excesses of 238U over 230Th. From our partitioning results we infer partition coefficients for protactinium (Pa) which we predict to be much lower than previously anticipated. Contrary to previous studies, our data imply that rutile should not significantly influence observed 231Pa-235U disequilibria in certain volcanic rocks. 相似文献
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Palaeocurrent data from parts of the Upper Buntsandstein (Lower Triassic) of both the western (Eifel: Kyllburg-Schichten) and eastern (Bavaria: Plattensandstein) margin of the German Triassic Basin (Middle Europe) have been interpreted by circular directional statistics, eigenvalue and eigenvector analysis, autocorrelation analysis and vector trend analysis. Examination of current roses, histograms of normalized vector magnitudes and plots, of circular skewness of the distribution vs. circular kurtosis, together with the palaeocurrent plots indicate bimodal palaeocurrent distributions with bipolar orientations within long, short and very short sedimentary sequences. Subset I of the directional data is interpreted to represent larger, more continuous flows in a high-energy regime of probably perennial type, whereas subset II may represent smaller, partially episodic flows of probably ephemeral type with larger variability in direction and flow regime; transport and sedimentation rates being significantly smaller than during deposition of subset I. A part of the bimodal palaeocurrent distributions within short sedimentary sequences fits rather well into the general transport pattern. Other bipolarities are primarily interpreted as effects of superimposition of channels of different orientations as well as of main channels and crevasse-splay channels, and condensation of deposition from discontinuous or episodic flows. The main mechanism creating the vertical succession of various directions is stacking of different substratum members to multistorey complexes by primary-depositional restriction of formation and/or secondary-erosional removal of topstratum sediments. The occasional occurrence of herring-bone cross-stratification representing bipolarities within very short depositional sequences, testifies to probably episodic and random changes in water surface slopes allowing currents to reverse locally. Examination of long sedimentary sequences by autocorrelation analysis reveals changes of transport directions with time in a sinusoidal manner, indicating a conformable environmental development of the alluvial watercourses which reflects a time-cyclic trend of sedimentation by spatially continuous and time-concordant shifting of the channel system. The results of the statistical analysis enable an enhanced palaeoenvironmental reconstruction of the alluvial network which fits best to a transitional meandering-thalweg-braided channel pattern. Comparison of the statistical results, especially in the light of vector trend surface analysis, clearly reflects the different palaeogeographic positions of both investigated areas, but rules out only minor influences of regionally different palaeoslopes on the alluvial depositional environment, with the basic principles of fluvial style at the western margin (Eifel) generally matching those at the eastern margin (Bavaria) of the German Basin. 相似文献
10.
We review the historical, geological, tide-gauge, GPS and gravimetric evidence advanced in favour of, or against, continuing
land uplift around Hudson Bay, Canada. We also reanalyse the tide-gauge and GPS data for Churchill using longer time series
than those available to previous investigators. The dependence of the mean rate of relative sea-level change obtained from
the tide-gauge record on the length and mid-epoch of the observation interval considered is investigated by means of a newly
developed linear-trend analysis diagram. For studying the shorter-period variability of the tide-gauge record, the wavelet
transform is used. The mean rate of land uplift obtained from GPS is based on a new analysis using IGS solutions of GFZ. To
include the post-glacial land uplift, sea-level indicators from the Churchill region representing the relative sea-level history
during the past 8000 years are also used. Finally, the values of the four observables are jointly inverted in terms of mantle
viscosity. The optimum values are ~3.2 × 1020 Pa s and ~1.6 × 1022 Pa s for the upper- and lower-mantle viscosities, respectively. 相似文献