Determination of the concentration of potassium chloride solution having the same electrical conductivity, at 15°C and infinite frequency, as standard seawater of salinity 35.0000 ‰ (Chlorinity 19.37394 ‰)

The absolute electrical conductivity at15degC of several lots of standard seawater has been measured with great precision as a function of chlorinity. Potassium chloride (KCI) solutions of known concentration and having almost the same conductivity were also measured and the concentration giving the same conductivity at15degC as35.0000permilstandard seawater (Chl =19.37394permil) was found to be 32.4352 g/kg.     

Non-steady state diagenetic record in eastern equatorial Atlantic sediments

The radiocarbon age profile of a sediment core from the eastern equatorial Atlantic shows a marked decrease in both clay and carbonate accumulation rates at the end of the last glacial period, with overall rates of 3.2 and 8.1 cm/kyr for the Holocene and late glacial respectively. The transition from glacial to postglacial conditions recorded in the sediments at 39 cm is above the visual Fe(II)/Fe(III) redox boundary at 48 cm which has been used in the past to identify the glacial section, and even further above the increase in preserved organic carbon content at 55 cm. It is concluded from the present organic carbon profile, and recent observations in this area and elsewhere, that organic diagenesis in these sediments is not steady state. Instead it is suggested that the uppermost glacial sediments lost carbon through oxic remineralisation at the change to postglacial conditions, and that this process is now continued with nitrate as the electron acceptor. These observations suggest that the double MnO_x solid phase peak which occurs in these and similar sediments is a direct consequence of an adjustment of the oxic layer depth following the decrease in carbon flux at the onset of the Holocene.     

Implications of rate-limited mass transfer for aquifer storage and recovery

Pressure to decrease reliance on surface water storage has led to increased interest in aquifer storage and recovery (ASR) systems. Recovery efficiency, which is the ratio of the volume of recovered water that meets a predefined standard to total volume of injected fluid, is a common criterion of ASR viability. Recovery efficiency can be degraded by a number of physical and geochemical processes, including rate-limited mass transfer (RLMT), which describes the exchange of solutes between mobile and immobile pore fluids. RLMT may control transport behavior that cannot be explained by advection and dispersion. We present data from a pilot-scale ASR study in Charleston, South Carolina, and develop a three-dimensional finite-difference model to evaluate the impact of RLMT processes on ASR efficiency. The modeling shows that RLMT can explain a rebound in salinity during fresh water storage in a brackish aquifer. Multicycle model results show low efficiencies over one to three ASR cycles due to RLMT degrading water quality during storage; efficiencies can evolve and improve markedly, however, over multiple cycles, even exceeding efficiencies generated by advection-dispersion only models. For an idealized ASR model where RLMT is active, our simulations show a discrete range of diffusive length scales over which the viability of ASR schemes in brackish aquifers would be hindered.     

Effect of chlorine on unsaturated lipids

In this note evidence is presented which suggests that an initial effect of chlorine treatment on fouling organisms could involve a deleterious halogenation of membrane lipid components.