Inorganic nitrogen in coral reef sediments

Representative profiles of inorganic nitrogenous species dissolved in interstitial waters of coral reef sands are presented. Ammonium is the dominant nitrogenous species in these pore waters with concentrations of up to 40 μm. Nitrate is present but in lower concentrations. Nitrite is found only occasionally in trace amounts. Computations of diffusive fluxes and inferences concerning microbial activity are derived from the profile structures. Computed flux rates of nitrogenous species from the sediment to the water column range between 0.75 and 1.37 μM m⁻¹ h⁻¹. These inputs may represent a significant source of recycled nitrogen to the primary producers of the coral reef ecosystem.     

Evaluating foreland basin partitioning in the northern Andes using Cenozoic fill of the Floresta basin,Eastern Cordillera,Colombia

This paper addresses foreland basin fragmentation through integrated detrital zircon U–Pb geochronology, sandstone petrography, facies analysis and palaeocurrent measurements from a Mesozoic–Cenozoic clastic succession preserved in the northern Andean retroarc fold‐thrust belt. Situated along the axis of the Eastern Cordillera of Colombia, the Floresta basin first received sediment from the eastern craton (Guyana shield) in the Cretaceous–early Palaeocene and then from the western magmatic arc (Central Cordillera) starting in the mid‐Palaeocene. The upper‐crustal magmatic arc was replaced by a metamorphic basement source in the middle Eocene. This, in turn, was replaced by an upper‐crustal fold‐thrust belt source in the late Eocene which persisted until Oligocene truncation of the Cenozoic section by the eastward advancing thrust front. Sedimentary facies analysis indicates minimal changes in depositional environments from shallow marine to low‐gradient fluvial and estuarine deposits. These same environments are recorded in coeval strata across the Eastern Cordillera. Throughout the Palaeogene, palaeocurrent and sediment provenance data point to a uniform western or southwestern sediment source. These data show that the Floresta basin existed as part of a laterally extensive, unbroken foreland basin connected with the proximal western (Magdalena Valley) basin from mid‐Paleocene to late Eocene time when it was isolated by uplift of the western flank of the Eastern Cordillera. The Floresta basin was also connected with the distal eastern (Llanos) basin from the Cretaceous until its late Oligocene truncation by the advancing thrust front.     

Nitrate depuration of secondary sewage effluents in mangrove sediments

The sewage treatment plant (STP) at La Parguera, on the southwest coast of Puerto Rico, discharges an average of 228,000 dm³ of secondary sewage effluents per day into percolation ponds located at the landward margin of the coastal mangrove fringe. Effluents flowing from the STP percolation ponds to the adjacent mangrove fringe typically exhibited nitrate levels between 0.2 mM and 1.0 mM. Experimental determination of actual and potential denitrification using acetylene block and substrate disappearance techniques indicate that mangrove sediment microbial communities are capable of depurating 10 to 15 times the nitrate added in the STP effluent. Plots of porewater salinities vs nitrate concentrations show exponential decay of nitrate concentration. Our observations confirm the potential of mangrove sediment-microbial communities for nitrate depuration of secondary sewage effluents.     

Pelagic petroleum pollution off the south-west coast of Puerto Rico

Petroleum pollution in the form of floating tar balls and dissolved or dispersed hydrocarbons has been monitored off the south-west coast of Puerto Rico on a weekly basis since November 1980. Tar ball abundance estimates agree well with previously published data for the area. Dissolved/dispersed hydrocarbon concentrations are close to, but below, those found in the Mediterranean Sea and considerably lower than those for more polluted areas. Tar ball abundance is closely related to the intensity of southerly winds. Dissolved/dispersed hydrocarbon concentrations are highest during the fall and coincident with the highest surface water temperatures.     

Methane flux from mangrove sediments along the Southwestern coast of Puerto Rico

Although the sediments of coastal marine mangrove forests have been considered a minor source of atmospheric methane, these estimates have been based on sparse data from similar areas. We have gathered evidence that shows that external nutrient and freshwater loading in mangrove sediments may have a significant effect on methane flux. Experiments were performed to examine methane fluxes from anaerobic sediments in a mangrove forest subjected to secondary sewage effluents on the southwestern coast of Puerto Rico. Emission rates were measured in situ using a static chamber technique, and subsequent laboratory analysis of samples was by gas chromatography using a flame ionization detector. Results indicate that methane flux rates were lowest at the landward fringe nearest to the effluent discharge, higher in the seaward fringe occupied by red mangroves, and highest in the transition zone between black and red mangrove communities, with average values of 4 mg CH₄ m^?2 d^?1, 42 mg CH₄ m^?2 d^?1, and 82 mg CH₄ m^?2 d^?1, respectively. Overall mean values show these sediments may emit as much as 40 times more methane than unimpacted pristine areas. Pneumatophores ofAviciennia germinans have been found to serve as conduits to the atmosphere for this gas. Fluctuating water level overlying the mangrove sediment is an important environmental factor controlling seasonal and interannual CH₄ flux variations. Environmental controls such as freshwater inputs and increased nutrient loading influence in situ methane emissions from these environments.     

Seismic strain rates and distributed continental deformation in the northern Andes and three-dimensional seismotectonics of northwestern South America

Remote sensing and field studies of several extensional basins along the northern margin of the Gulf of Aden in Yemen show that Oligocene–Miocene syn-rift extension trends N20°E on average, in agreement with the E–W to N120°E strike of main rift-related normal faults, but oblique to the main trend of the Gulf (N70°E). These faults show a systematic reactivation under a 160°E extensional stress that we interpret also as syn-rift. The occurrence of these two successive phases of extension over more than 1000 km along the continental margin suggests a common origin linked to the rifting process. After discussing other possible mechanisms such as a change in plate motion, far-field effects of Arabia–Eurasia collision, and stress rotations in transfer zones, we present a working hypothesis that relates the 160°E extension to the westward propagation since about 20 Ma of the N70°E-trending, obliquely spreading, Gulf of Aden oceanic rift. The late 160°E extension, perpendicular to the direction of rift propagation, could result from crack-induced extension associated with the strain localization that characterises the rift-to-drift transition.     

Increase of nitrous oxide flux to the atmosphere upon nitrogen addition to red mangroves sediments

Response of nitrous oxide N20 sediment/air flux to nitrogen addition was assessed in mangrove (Rhizophora mangle) sediments. Fluxes were enhanced with both ammonium and nitrate loading. Greatest fluxes (52 micromol m(-2) h(-1)) were obtained with ammonium addition and saturation was achieved with additions of 0.9 mol m(-2). Maximum flux following ammonium addition was 2785 times greater than control plots and 4.5 times greater during low tide than with equivalent ammonium addition at high tide. Nitrate enrichment resulted in exponential growth, with maximal mean flux of 36.7 micromolm(-2) h(-1) at 1.9 molm(-2); saturation was not achieved. Differential response to ammonium and nitrate, and to tide and elevation, indicate that microbial nitrification is responsible for most of the observed gas flux. Mangrove sediments constitute an important source of global atmospheric N20 and increases in nitrogen loading will lead to significant increases in the flux of this atmospherically active gas.