Geophysical evidence of mud diapirism on the Mediterranean Ridge accretionary complex

Mud volcanoes, mud cones, and mud ridges have been identified on the inner portion of the crestal area, and possibly on the inner escarpment, of the Mediterranean Ridge accretionary complex. Four areas containing one or more mud diapirs have been investigated through bathymetric profiling, single channel seismic reflection profiling, heat flow measurements, and coring. A sequence of events is identified in the evolution of the mud diapirs: initially the expulsion on the seafloor of gasrich mud produces a seafloor depression outlined in the seismic record by downward dip of the host sediment reflectors towards the mud conduit; subsequent eruptions of fluid mud may create a flat topped mud volcano with step-like profile; finally, the intrusion of viscous mud produces a mud cone.The origin of the diapirs is deep within the Mediterranean Ridge. Although a minimum depth of about 400 m below the seafloor has been computed from the hydrostatic balance between the diapiric sediments and the host sediments, a maximum depth, suggested by geometric considerations, ranges between 5.3 and 7 km. The presence of thermogenic gas in the diapiric sediments suggests a better constrained origin depth of at least 2.2 km.The heat flow measured within the Olimpi mud diapir field and along a transect orthogonal to the diapiric field is low, ranging between 16 ± 5 and 41 ± 6 mW m^–2. Due to the presence of gas, the thermal conductivity of the diapiric sediments is lower than that of the host hemipelagic oozes (0.6–0.9 and 1.0–1.15 W m^–1 K^–1 respectively).We consider the distribution of mud diapirs to be controlled by the presence of tectonic features such as reverse faults or thrusts (inner escarpment) that develop where the thickness of the Late Miocene evaporites appears to be minimum. An upward migration through time of the position of the décollement within the stratigraphic column from the Upper Oligocene (diapiric sediments) to the Upper Miocene (present position) is identified.     

Gas hydrate and free gas distribution from inversion of seismic data on the South Shetland margin (Antarctica)

Travel-time inversion is applied to seismic data to produce acoustic velocity images of the upper 800 m of the South Shetland margin (Antarctic Peninsula) in three different geological domains: (i) the continental shelf; (ii) the accretionary prism; (iii) the trench. The velocity in the continental shelf sediments is remarkably higher, up to 1000 m/s at 600–700 m below seafloor, than that of the other two geological domains, due to the sediment overcompaction and erosion induced by the wax and waning of a grounded ice sheet. Pre-stack depth migration was applied to the data in order to improve the seismic image and to test the quality of the velocity fields. Where the Bottom Simulating Reflector (BSR) is present, positive and negative velocity anomalies were found with respect to a reference empirical velocity profile. The 2D-velocity section was translated in gas hydrate and free gas distribution by using a theoretical approach. The analysis revealed that the BSR is mainly related to the presence of free gas below it. The free gas is distributed in the area with variable concentration and thickness, while the gas hydrate is quite uniformly distributed across the margin.     

Fluid flow and pore pressure development throughout the evolution of a trough mouth fan,western Barents Sea

Using a combination of geophysical and geotechnical data from Storfjorden Trough Mouth Fan off southern Svalbard, we investigate the hydrogeology of the continental margin and how this is affected by Quaternary glacial advances and retreats over the continental shelf. The geotechnical results show that plumites, deposited during the deglaciation, have high porosities, permeabilities and compressibilities with respect to glacigenic debris flows and tills. These results together with margin stratigraphic models obtained from seismic reflection data were used as input for numerical finite element models to understand focusing of interstitial fluids on glaciated continental margins. The modelled evolution of the Storfjorden TMF shows that tills formed on the shelf following the onset of glacial sedimentation (ca. 1.5 Ma) acted as aquitards and therefore played a significant role in decreasing the vertical fluid flow towards the sea floor and diverting it towards the slope. The model shows that high overpressure ratios (up to λ ca. 0.6) developed below the shelf edge and on the middle slope. A more detailed model for the last 220 kyrs accounting for ice loading during glacial maxima shows that the formation of these aquitards on the shelf focused fluid flow towards the most permeable plumite sediments on the slope. The less permeable glacigenic debris flows that were deposited during glacial maxima on the slope hinder fluid evacuation from plumites allowing high overpressure ratios (up to λ ca. 0.7) to develop in the shallowest plumite layers. These high overpressures likely persist to the Present and are a critical precondition for submarine slope failure.     

Bannock Basin,Sirte Abyssal Plain and Conrad Spur: structural relationships between Mediterranean Ridge and its western foreland and implications on the character of the accretionary complex (eastern Mediterranean)

In previous publications, the relationship between the Sirte Abyssal Plain as foreland and the Mediterranean Ridge as accretionary complex was considered to be simple: the foreland is undeformed, the accretionary complex consumes the foreland, the Messinian evaporites control the internal structure of the growing complex. The compilation of our own and published data results in a more complex tectonic pattern and a new geodynamic interpretation. The Sirte Abyssal Plain is imprinted by extensional tectonics which originated independently from and prior to the approaching process of accretion. The structural setting of the pre-Messinian and Messinian Sirte Abyssal Plain is responsible for the highly variable thickness of Messinian evaporites. The foreland setting in the Sirte Abyssal Plain also controls the internal structure of the Mediterranean Ridge, at least between the deformation front and Bannock Basin, following sediment deformation within the accretionary wedge with a dominating inherited SW-NE orientation. The taper angle of the post-Messinian Mediterranean Ridge is unusually small compared with other accretionary wedges. In the studied area, within a distance of about 45 km from the deformation front, there is no appreciable dip in the décollement. Therefore, the slope of the outer 45 km of the Mediterranean Ridge is considered to be caused only by gravitational spreading of Messinian evaporites deposited on the slope of pre-Messinian accretionary wedge. As a consequence, the Mediterranean Ridge underlying such slope is interpreted to belong to the foreland. The allochthonous evaporites overlie autochthonous evaporites of the Sirte Abyssal Plain. The NE-dipping décollement (and thus of the true tectonically driven deformation front) is expected to initiate at about the present position of Bannock Basin. The Sirte Abyssal Plain, the adjacent Cyrene Seamount and neighbouring seafloor relief on the African continental margin are considered to be the product of tectonic segmentation of the continental crust.     

Late Miocene sedimentary architecture of the Ebro Continental Margin (Western Mediterranean): implications to the Messinian Salinity Crisis

The Messinian Salinity Crisis (MSC) resulted from a significant multi-phase drop and subsequent reflooding of the Mediterranean Sea from 5.96 to 5.33 Ma. Well-developed drainage networks, characterized by step-like profiles and abrasion platforms, are associated to this event. The Ebro Continental Margin (Western Mediterranean) presents an additional complexity since the capture of the drainage of the adjacent subaerial Ebro Basin took place sometime prior to the Messinian stage. Using 3D seismic reflection data, this work provides new insights into the origin of the step-like profile of the Messinian erosional surface (MES) and timing of the capture of the subaerial Ebro Basin. The results obtained indicate a sedimentary-active continental slope and delta progradation during Middle-Late Miocene, in a normal regressive context associated to a pre-Messinian proto-Ebro River. The mature development attained by the Messinian Ebro River network during the MSC corroborates that the capture of the Ebro Basin occurred prior to the MSC. The configuration of the clinoforms below the MES suggests that deltaic sediments of the Messinian Paleo-Ebro River deposited during the Tortonian and initial Messinian sea-level drawdown. The MES formed at the top of the Tortonian Highstand, where a fluvial network was deeply carved, and in the topset region of the Messinian Falling Stage Systems Tract, where minor erosion occurred. Fluvial deposits are outstandingly preserved on the main valleys of the MES. Therefore, the step-like profile of the MES was not created during Zanclean inundation, but during the latest stages of the main Messinian sea-level fall and lowstand.     

Tracing seafloor methane emissions with benthic foraminifera: Results from the Ana submarine landslide (Eivissa Channel,Western Mediterranean Sea)

The hypothesis that benthic foraminifera are useful proxies of local methane emissions from the seafloor has been verified on sediment core KS16 from the headwall of the Ana submarine landslide in the Eivissa Channel, Western Mediterranean Sea. The core MS312 from a nearby location with no known methane emissions is utilised as control. The core was analysed for biostratigraphy, benthic foraminiferal assemblages, Hyalinea balthica and Uvigerina peregrina carbon and oxygen stable isotope composition, and sedimentary structures. The upper part of the core records post-landslide deglacial and Holocene normal marine hemipelagic sediments with highly abundant benthic foraminifera species that are typical of outer neritic to upper bathyal environment. In this interval, the δ¹³C composition of benthic foraminifera indicates normal marine environment analogous to those found in the control core. Below the sedimentary hiatus caused by the emplacement of the slide, the foraminiferal assemblages are characterised by lower density and higher Shannon Index. Markedly negative δ¹³C shifts in benthic foraminifera are attributed to the release of methane through the seabed. The mean values of the ¹³C anomaly in U. peregrina are ? 0.951 ± 0.208 in the pre-landslide sediments, and ? 0.269 ± 0.152 in post-slide reworked sediments deposited immediately above the hiatus. The δ¹³C anomaly in Hyalinea balthica is ? 2.497 ± 0.080 and ? 2.153 ± 0.087, respectively. To discard the diagenetic effects on the δ¹³C anomaly, which could have been induced by Ca–Mg replacement and authigenic carbonate overgrowth on foraminifera tests, a benthic foraminifera subsample has been treated following an oxidative and reductive cleaning protocol. The cleaning has resulted, only in some cases, in a slight reduction of the anomaly by 0.95% for δ¹³C and < 0.80% for δ¹⁸O. Therefore, the first conclusion is that the diagenetic alteration is minor and it does not alter significantly the overall carbon isotopic anomaly in the core. Consequently, the pre-landslide sediments have been subject to pervasive methane emissions during a time interval of several thousand years. Methane emissions continued during and immediately after the occurrence of Ana Slide at about 61.5 ka. Subsequently, methane emissions decreased and definitely ceased during the last deglaciation and the Holocene.     

Effects of biogenic silica on sediment compaction and slope stability on the Pacific margin of the Antarctic Peninsula

Analysis of physical properties measured on cores and on discrete samples collected by the Ocean Drilling Programme (ODP) Leg 178 on the Pacific margin of the Antarctic Peninsula reveals anomalous down‐hole curves of porosity, density, water content, and P‐wave velocity. These indicate an overall trend of increasing porosity with depth and suggest that the drifts are mostly undercompacted. In one of the two boreholes analysed, a sharp decrease in porosity, matching increasing bulk sediment density and increasing compressional velocity occurs towards the base of the hole, which corresponds to a bottom‐simulating reflector in the seismic section. Analysis of seismic reflection, down‐hole logging, geotechnical and mineralogical data from two drilling sites indicates that the observed anomalous consolidation trends are a consequence of the presence of biogenic silica (diatom and radiolarian skeletons) even with a small to moderate amount. Above the bottom‐simulating reflector, intergranular contacts among whole or broken siliceous microfossils prevent normal sediment consolidation. Diagenetic alteration of biogenic opal‐A to opal‐CT causes a dramatic reduction of intra‐ and interskeletal porosity allowing sediments to consolidate at depth. This results in overpressuring and a decrease in the effective stress. Excess fluids are expelled towards the sediment surface through near vertical, small throw normal faults extending from the diagenetic front to the seafloor and affecting the stability of the submarine slope in the form of gravitational creep along a weakened surface. This work shows how physical properties of shallow fine‐grained marine sediments can be analysed as basin‐wide indicators of biogenic silica abundance. The diagenetic alteration of siliceous microfossils is a possible cause of slope instability along world continental margins where bottom‐simulating reflectors related to silica diagenesis are present at a regional scale.     

The occurrence and significance of Pleistocene and Upper Pliocene sapropels in the Tyrrhenian Sea

Numerous sapropels and sapropelic strata from Upper Pliocene and Pleistocene hemipelagic sediments of the Tyrrhenian Sea show that intermittent anoxia, possibly related to strongly increased biological productivity, was not restricted to the eastern Mediterranean basins and may be a basin-wide result of Late Pliocene-Pleistocene climatic variability. Even though the sapropel assemblage of the Tyrrhenian Sea clearly originates from multiple processes such as deposition under anoxic conditions or during spikes in surface water productivity and lateral transport of organic-rich suspensates, many “pelagic sapropels” have been recognized. Stratigraphic ages calculated for the organic-rich strata recovered during ODP Leg 107 indicate that the frequency of sapropel formation increased from the lowermost Pleistocene to the base of the Jaramillo magnetic event, coinciding with a period when stable isotope records of planktonic foraminifera indicate the onset of climatic cooling in the Mediterranean. A second, very pronounced peak in sapropel formation occurred in the Middle to Late Pleistocene (0.73-0.26 Ma). Formainifers studied in three high-resolution sample sets suggest that changes in surface-water temperature may have been responsible for establishing anoxic conditions, while salinity differences were not noted in the faunal assemblage. However, comparison of sapropel occurrence at Site 653 with the oxygen isotopic record of planktonic foraminifers established by Thunell et al. (Proc. ODP, Sci. Results 107, 1990) indicates that sapropel occurrences coincide with negative δ¹⁸O excursions in planktonic foraminifers in thirteen of eighteen sapropels recognized in Hole 653A. A variant of the meltwater hypothesis accepted for sapropel formation in the Late Pleistocene eastern Mediterranean may thus be the cause of several “anoxic events” in the Tyrrhenian as well. Model calculations indicate that the amount of oxygen advection from Western Mediterranean Deep Water exerts the dominant control on the oxygen content in deep water of the Tyrrhenian Sea. Inhibition of deep-water formation in the northern Adriatic and the Balearic Basin by increased meltwater discharge and changing storm patterns during climatic amelioration may thus be responsible for sapropel formation in the Tyrrhenian Sea.     

Late Pliocene Mega Debris Flow Deposit and Related Fluid Escapes Identified on the Antarctic Peninsula Continental Margin by Seismic Reflection Data Analysis

We have obtained improved images of a debris flow deposit through the reprocessing of multichannel seismic reflection data between Drifts 6 and 7 of the continental rise of the Pacific margin of the Antarctic Peninsula. The reprocessing, primarily aimed at the reduction of noise, relative to amplitude preservation, deconvolution, also included accurate velocity analyses. The deposit is dated as upper Pliocene (nearly 3.0 Ma) via correlation to Sites 1095 and 1096 of the Ocean Drilling Program (ODP) Leg 178. The estimated volume is about 1800 km³ and the inferred provenance from the continental slope implies a run out distance exceeding 250 km. The dramatic mass-wasting event that produced this deposit, unique in the sedimentary history of this margin, is related to widespread late Pliocene margin erosion. This was associated with a catastrophic continental margin collapse, following the Antarctic ice sheet expansion in response to global cooling. The seismic data analysis also allowed us to identify diffractions and amplitude anomalies interpreted as expressions of sedimentary mounds at the seafloor overlying narrow high-velocity zones that we interpret as conduits of fluid expulsion hosting either methane hydrates or authigenic carbonates. Fluid expulsion was triggered by loading of underlying sediments by the debris flow deposits and may have continued until today by input of fluids from sediment compaction following the deep diagenesis of biogenic silica.