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1.
The Apollo orbital geochemistry, photogeologic, and other remote sensing data sets were used to identify and characterize geochemical anomalies on the eastern limb and farside of the Moon and to investigate the processes responsible for their formation. The anomalies are located in the following regions: (1) Balmer basin, (2) terrain northeast of Mare Smythii, (3) near Langemak crater, (4) Pasteur crater, (5) terrain northwest of Milne basin, (6) northeast of Mendeleev basin, (7) north and northeast of Korolev basin, (8) terrain north of Taruntius crater, and (9) terrain north of Orientale basin. The anomalies are commonly associated with Imbrian- or Nectarian-aged light plains units which exhibit dark-haloed impact craters. The results of recent spectral reflectance studies of dark-haloed impact craters plus consideration of the surface chemistry of the anomalies strongly indicate that those geochemical anomalies associated with light plains deposits which display dark-haloed impact craters result from the presence of basaltic units that are either covered by varying thickness of highland debris or have a surface contaminated with significant amounts of highlands material. The burial or contamination of ancient volcanic surfaces by varying amounts of highland material appears to have been an important (though not the dominant) process in the formation of lunar light plains. Basaltic volcanism on the eastern limb and farside of the Moon was more extensive in both space and time than has been accepted. 相似文献
2.
For several years now, an experimental simulation of Titan's atmosphere has been on going at LISA. A cold plasma is established in a gas mixture representative of the atmosphere of the satellite. In these experiments, more than 70 organic compounds have been identified, including the first identification in this type of experimental simulation of C4N2 already detected in its solid form on Titan, which suggests that the setup correctly mimics the chemistry of Titan's atmosphere.We have carried out the first experimental simulation including O-containing compounds in order to study the influence of the presence of CO on the chemical behavior of Titan's atmosphere. With the help of gas chromatography–mass spectrometry (GC–MS) and infrared spectroscopy (IRS) we can thus determine which minor species still undetected in Titan's atmosphere are likely to be present and understand the complex chemistry of the atmosphere of this satellite. Surprisingly we have identified unpredicted O-containing gaseous compounds, mainly ethylene oxide (also named oxirane, C2H4O). This molecule has been observed in the interstellar medium by observation in the millimeter region (Astrophys. J. 489 (1997) 553; Astron. Astrophys. 337 (1998) 275). On the contrary, the predicted O-compounds (formaldehyde and methanol) have not been identified in this experiment. Furthermore, we have identified NH3 in the gaseous products with an initial mixture of N2 (98%) and CH4 (2%).The paper describes the experimental device used in this work, in particular the IRS and GC–MS techniques. We also comment the results related to the detection of the O-containing compounds and NH3 and their implications on our knowledge of the chemistry of Titan's atmosphere and on the retrieval of the future Titan data expected from Cassini-Huygens. 相似文献
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Marie K. McCabe Zdeněk F. Švestka Russell A. Howard Bernard V. Jackson Neil R. Sheeley Jr. 《Solar physics》1986,103(2):399-408
By using a combination of X-ray (HXIS), H (Haleakala), white-light corona (Solwind), and zodiacal light (Helios) images on 21–22 May, 1980 we demonstrate, and try to explain, the co-existence of a coronal mass ejection with a stationary post-flare coronal arch. The mass ejection was seen, both by Solwind and Helios, in prolongation of the path of a powerful spray, whereas the active region filament did not erupt. A tentative comparison is made with other occurrences of stationary, or quasi-stationary post-flare coronal arches. 相似文献
5.
Daniel Bernard Jamal El Khattabi Emilie Lefevre Hani Serhal Sabine Bastin-Lacherez Isam Shahrour 《Environmental Geology》2008,53(5):1129-1138
In the north of France, high registers of nickel are sometimes recorded within the chalk aquifer. In a confined context, the
presence of pyrite in the covering clays or in the marcasite nodules encrusted in the clay may constitute a natural source
of trace metals. With an objective of sanitary control, the limits of chemical contents regulating the quality of water destined
for human consumption have been lowered by the European Framework Directive in the field of water policy (2000/60/EC). As
a result, nickel limits have been reduced from 50 to 20 μg/l. The analyses, carried out on three water catchment fields in
our area of study, were centred on variable parameters (Eh, O2(d), pH, Conductivity, T°), major elements (SO4, NO3) and metals (Fe, Ni, Mn, Co). The acquired data enabled us to identify from one hand, the conditions which are presented
within the site, special thanks to the evolution of nitrate and iron contents and on the other hand, the natural origin (geological)
of nickel for two of the three sites studied based essentially on the evaluation of the Nickel/Cobalt ratio. Thus, on the
first site, the evolution of nickel content and nitrate content showed the influence of the phenomenon of denitrification
on the re-mobilisation of the nickel. Whereas on the second site, a high variation of total iron content and oxygen dissolved
in solution highlighted a particular phenomenon of oxidation of the pyrite through molecular oxygen. Finally, the correlation
with the sulphates clearly showed behaviour of the nickel, once released, that was entirely dependent on the phenomenon of
adsorption on the iron and manganese hydroxides. 相似文献
6.
Core formation and the oxidation state of the Earth: Additional constraints from Nb, V and Cr partitioning 总被引:1,自引:0,他引:1
We have combined metal-silicate partitioning data from the literature with new experimental results at 1.5-8 GPa and 1480-2000 °C to parameterize the effects of pressure, temperature and composition on the partitioning of V, Cr and Nb between liquid Fe metal (with low S and C content) and silicate melt.Using information from the steelmaking literature to correct for interactions in the metal phase, we find that, for peridotitic silicate melts, metal-silicate partition coefficients are given by:
7.
Zsuzsanna Balogh-Brunstad C. Kent Keller Forrest Stevens Bernard T. Bormann 《Geochimica et cosmochimica acta》2008,72(11):2601-2618
Ectomycorrhiza-forming fungi (EMF) alter the nutrient-acquisition capabilities of vascular plants, and may play an important role in mineral weathering and the partitioning of products of weathering in soils under nutrient-limited conditions. In this study, we isolated the weathering function of Suillus tomentosus in liquid-cultures with biotite micas incubated at room temperature. We hypothesized that the fungus would accelerate weathering by hyphal attachment to biotite surfaces and transmission of nutrient cations via direct exchange into the fungal biomass. We combined a mass-balance approach with scanning electron microscopy (SEM) and atomic force microscopy (AFM) to estimate weathering rates and study dissolution features on biotite surfaces. Weathering of biotite flakes was about 2-3 orders of magnitude faster in shaken liquid-cultures with fungus compared to shaken controls without fungus, but with added inorganic acids. Adding fungus in nonshaken cultures caused a higher dissolution rate than in inorganic pH controls without fungus, but it was not significantly faster than organic pH controls without fungus. The K+, Mg2+ and Fe2+ from biotite were preferentially partitioned into fungal biomass in the shaken cultures, while in the nonshaken cultures, K+ and Mg2+ was lost from biomass and Fe2+ bioaccumulated much less. Fungal hyphae attached to biotite surfaces, but no significant surface changes were detected by SEM. When cultures were shaken, the AFM images of basal planes appeared to be rougher and had abundant dissolution channels, but such channel development was minor in nonshaken conditions. Even under shaken conditions the channels only accounted for only 1/100 of the total dissolution rate of 2.7 × 10−10 mol of biotite m−2 s−1. The results suggest that fungal weathering predominantly occurred not by attachment and direct transfer of nutrients via hyphae, but because of the acidification of the bulk liquid by organic acids, fungal respiration (CO2), and complexation of cations which accelerated dissolution of biotite. Results further suggest that both carbohydrate source (abundant here) and a host with which nutrients are exchanged (missing here) may be required for EMF to exert an important weathering effect in soils. Unsaturated conditions and physical dispersal of nutrient-rich minerals in soils may also confer a benefit for hyphal growth and attachment, and promote the attachment-mediated weathering which has been observed elsewhere on soil mineral surfaces. 相似文献
8.
This paper discusses the provision of water and sanitation services and the related urban impacts in Buenos Aires circa 2005. The first part of the paper focuses on the metropolitan region (BAMR) which is larger than the area served by the Aguas Argentinas S.A. (AASA) concession (i.e. the capital and its conurbano). It highlights a form of institutional fragmentation that is reflected in the diverse management practices of the numerous service providers and results in differentiated levels of and access to services. The paper discusses the technical, economic and regulatory factors that have historically resulted in this institutional fragmentation. The second part of the article focuses on AASA’s water concession agreement. It demonstrates that, although the agreement had an in-built splintering logic, its implementation led to a more “integrated approach” based on the “reality on the ground”. On the whole, the conclusion regarding the application of the splintering urbanism concept to Buenos Aires is a mixed one and depends on the scale of observation. Although at regional level (BAMR), a form of “institutional fragmentation” would appear to be obvious, it is the result of a long and complex historical process and, while recent neo-liberal reforms in service provisions have “cemented” this fragmentation, they did not actually cause it. If we take the AASA service area in isolation, the trend in the decade following the contracting out of the service has been one of improved service provision and access—although this was not achieved through increased integration of the supply system. Finally, in the case of the Buenos Aires metropolitan region, the splintering urbanism thesis defended by Marvin and Graham needs to be nuanced in several significant ways. 相似文献
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