Structurally controlled gold and sulfosalt mineralization: the Altenberg example, Salzburg Province, Austria

Summary ?In the south-eastern Altenbergkar–Silbereck area in the eastern Tauern window (Lungau, Salzburg) structurally controlled precious-metal (Au–Ag) mineralization is hosted in marbles of the Permo(?)-Mesozoic Silbereck Formation and in the underlying Variscan Central gneiss. During the Alpine otogeny both lithologies were affected by ductile deformation (shearing, D1; folding, D2/D3) and subsequent brittle deformation (tension gashes, D4; normal faulting, D5) related to the uplift and exhumation of the Tauern window. Mineralization is controlled by brittle D4 structures. NE–SW trending steeply dipping tension gashes of the “Tauerngoldgang” type occur within the Central gneiss. Three different marble-hosted ore types following fracture systems as well as foliation and bedding planes can be distinguished: 1) metasomatic replacement ores, 2) ores in tension gashes and 3) ores in talc-bearing structures, often containing high-grade gold and silver mineralization (native gold in association with Ag–Pb–Bi–sulfosalts). Four stages of mineralization can be distinguished which occur in all ore types: arsenopyrite–pyrite–pyrrhotite (first stage), Au–(Ag–Pb–Bi–sulfosalts) (second stage), base-metal sulfides and tetrahedrite–tennantite (third stage) and Ag-rich galena (fourth stage). Preliminary fluid inclusion data indicate temperatures of ore formation well above 300 °C (346 °C mean) for the second stage within the Central gneiss and temperatures between 310 and 230 °C for the second and third stages in the marble. Received October 12, 2001; revised version accepted September 5, 2002 Published online March 10, 2003     

Arsenic attenuation in tailings at a former Cu–W–As mine,SW Finland

Nearly half a century after mine closure, release of As from the Ylöjärvi Cu–W–As mine tailings in groundwater and surface water run-off was observed. Investigations by scanning electron microscopy (SEM), electron microprobe analysis (EMPA), synchrotron-based micro-X-ray diffraction (μ-XRD), micro-X-ray absorption near edge structure (μ-XANES) and micro-extended X-ray absorption fine structure (μ-EXAFS) spectroscopy, and a sequential extraction procedure were performed to assess As attenuation mechanisms in the vadose zone of this tailings deposit. Results of SEM, EMPA, and sequential extractions indicated that the precipitation of As bearing Fe(III) (oxy)hydroxides (up to 18.4 wt.% As₂O₅) and Fe(III) arsenates were important secondary controls on As mobility. The μ-XRD, μ-XANES and μ-EXAFS analyses suggested that these phases correspond to poorly crystalline and disordered As-bearing precipitates, including arsenical ferrihydrite, scorodite, kaňkite, and hydrous ferric arsenate (HFA). The pH within 200 cm of the tailings surface averaged 5.7, conditions which favor the precipitation of ferrihydrite. Poorly crystalline Fe(III) arsenates are potentially unstable over time, and their transformation to ferrihydrite, which contributes to As uptake, has potential to increase the As adsorption capacity of the tailings. Arsenic mobility in tailings pore water at the Ylöjärvi mine will depend on continued arsenopyrite oxidation, dissolution or transformation of secondary Fe(III) arsenates, and the As adsorption capacity of Fe(III) (oxy)hydroxides within this tailings deposit.     

Hydrological modelling for assessing spatio-temporal groundwater recharge variations in the water-stressed Amathole Water Supply System,Eastern Cape,South Africa

To increase the resilience of regional water supply systems in South Africa in the face of anticipated climatic changes and a constant increase in water demand, water supply sources require diversification. Many water-stressed metropolitan regions in South Africa depend largely on surface water to cover their water demand. While climatic and river discharge data is widely available in these regions, information on groundwater resources – which could support supply source diversification – is scarce. Groundwater recharge is a key parameter that is used to estimate groundwater amounts that can be sustainably exploited at a sub-watershed level. Therefore, the objective of this study was to develop a reliable hydrological modelling routine that enables the assessment of regional spatio-temporal variations of groundwater recharge to discern the most promising areas for groundwater development. Accordingly, we present a semi-distributed hydrological modelling approach that incorporates water balance routines coupled with baseflow modelling techniques to yield spatio-temporal variations of groundwater recharge on a regional level. The approach is demonstrated for the actively managed catchment areas of the Amathole Water Supply System situated in a semi-arid part of the Eastern Cape of South Africa. In the investigated study area, annual groundwater recharge exhibits a high spatio-temporal heterogeneity and is estimated to vary between ~0.5% and 8% of annual rainfall. Despite some uncertainties induced by limited data availability, calibration and validation of the model were found to be satisfactory and yielded model results similar to (point) data of annual groundwater recharge reported in earlier studies. Our approach is therefore found to derive crucial information for efficiently targeting more detailed groundwater exploration studies and could work as a blueprint for orientating groundwater potential exploration in similar environments.     

The Poseidon Operational Tool for the Prediction of Floating Pollutant Transport

In this work the development and the application of an operational management tool for the Greek Seas is described. This tool consists of a three-dimensional floating pollutant prediction model coupled with a weather, a hydrodynamic and a wave model in order to track the movements and the spreading of the pollutants and indicate those coastal areas which might be affected. The tool is part of the Poseidon system which has been designed to provide real time data and forecasts for marine environmental conditions in the Greek Seas. In this paper, we present four case studies based on realistic scenarios that show the value of the application for long-term strategic planning and short-term decision making in oil spill accidents.     

Uncertainty of ENSO-amplitude projections in CMIP5 and CMIP6 models

There is a long-standing debate on how the El Niño/Southern Oscillation (ENSO) amplitude may change during the twenty-first century in response to global warming. Here we identify the sources of uncertainty in the ENSO amplitude projections in models participating in the Coupled Model Intercomparison Phase 5 (CMIP5) and Phase 6 (CMIP6), and quantify scenario uncertainty, model uncertainty and uncertainty due to internal variability. The model projections exhibit a large spread, ranging from increasing standard deviation of up to 0.6 °C to diminishing standard deviation of up to − 0.4 °C by the end of the twenty-first century. The ensemble-mean ENSO amplitude change is close to zero. Internal variability is the main contributor to the uncertainty during the first three decades; model uncertainty dominates thereafter, while scenario uncertainty is relatively small throughout the twenty-first century. The total uncertainty increases from CMIP5 to CMIP6: while model uncertainty is reduced, scenario uncertainty is considerably increased. The models with “realistic” ENSO dynamics have been analyzed separately and categorized into models with too small, moderate and too large ENSO amplitude in comparison to instrumental observations. The smallest uncertainties are observed in the sub-ensemble exhibiting realistic ENSO dynamics and moderate ENSO amplitude. However, the global warming signal in ENSO-amplitude change is undetectable in all sub-ensembles. The zonal wind-SST feedback is identified as an important factor determining ENSO amplitude change: global warming signal in ENSO amplitude and zonal wind-SST feedback strength are highly correlated across the CMIP5 and CMIP6 models.

     

Retrospective and prospective model simulations of sea level rise impacts on Gulf of Mexico coastal marshes and forests in Waccasassa Bay, Florida

The State of Florida (USA) is especially threatened by sea level rise due to extensive low elevation coastal habitats (approximately 8,000?km²?<?1?m above sea level) where the majority of the human population resides. We used the Sea Level Affecting Marshes Model (SLAMM) simulation to improve understanding of the magnitude and location of these changes for 58,000?ha of the Waccasassa Bay region of Florida??s central Gulf of Mexico coast. To assess how well SLAMM portrays changes in coastal wetland systems resulting from sea level rise, we conducted a hindcast in which we compared model results to 30?years of field plot data. Overall, the model showed the same pattern of coastal forest loss as observed. Prospective runs of SLAMM using 0.64?m, 1?m and 2?m sea level rise scenarios predict substantial changes over this century in the area covered by coastal wetland systems including net losses of coastal forests (69%, 83%, and 99%, respectively) and inland forests (33%, 50%, and 88%), but net gains of tidal flats (17%, 142%, and 3,837%). One implication of these findings at the site level is that undeveloped, unprotected lands inland from the coastal forest should be protected to accommodate upslope migration of this natural community in response to rising seas. At a broader scale, our results suggest that coastal wetland systems will be unevenly affected across the Gulf of Mexico as sea level rises. Species vulnerable to these anticipated changes will experience a net loss or even elimination.     

The Stanford Climate Change Behavior Survey (SCCBS): assessing greenhouse gas emissions-related behaviors in individuals and populations

Many individual-level behaviors are associated with greenhouse gas (GHG) emissions. Reliable and valid assessment instruments are needed to (1) identify behaviors and populations to target with emissions-reduction programs and policies, (2) evaluate the effectiveness of such programs, (3) link self-reported and objective measures of GHG emissions to establish the impact of specific behaviors, and (4) estimate frequencies of behaviors and their changes over time to aid policy makers in understanding energy consumption trends. The self-administered Stanford Climate Change Behavior Survey (SCCBS) is shown to be a reliable and valid instrument that can be used for these purposes in college students, and we anticipate that it will also be useful for assessing these behaviors in other adolescent or adult populations in developed countries. Questions included behaviors likely to be within the control of most individuals and did not include behaviors specific to home owners (e.g. appliance purchases). Ten indices were identified: Energy Use, No-, Low-, and High-GHG Transportation, Waste, Food Packaging, High- and Low-GHG Food, Food Purchasing, and GHG Credits use. A Total GHG Behavior score was calculated. Test–retest reliabilities of individual items ranged from .64 to .91. Internal consistency reliabilities for each of the indices ranged from .51 to .89. Most indices were statistically significantly correlated with one another. Correlational validity of the SCCBS was demonstrated with statistically significant associations between behavior scores and perceived importance of environmental sustainability and membership in an environmental organization. The use of the SCCBS to identify potential target sub-populations and behaviors was demonstrated.     

Effects of neighboring vascular plants on the abundance of bryophytes in different vegetation types

Due to the climate change, vegetation of tundra ecosystems is predicted to shift toward shrub and tree dominance, and this change may influence bryophytes. To estimate how changes in growing environment and the dominance of vascular plants influence bryophyte abundance, we compared the relationship of occurrence of bryophytes among other plant types in a five-year experiment of warming (T), fertilization (F) and T + F in two vegetation types, heath and meadow, in a subarctic–alpine ecosystem. We compared individual leaf area among shrub species to confirm that deciduous shrubs might cause severe shading effect. Effects of neighboring functional types on the performance of Hylocomium splendens was also analyzed.Results show that F and T + F treatments significantly influenced bryophyte abundance negatively. Under natural conditions, bryophytes in the heath site were negatively related to the abundance of shrubs and lichens and the relationship between lichens and bryophytes strengthened after the experimental period. After five years of experimental treatments in the meadow, a positive abundance relationship emerged between bryophytes and deciduous shrubs, evergreen shrubs and forbs. This relationship was not found in the heath site. Our study therefore shows that the abundance relationships between bryophytes and plants in two vegetation types within the same area can be different. Deciduous shrubs had larger leaf area than evergreen shrubs but did not show any shading effect on H. splendens.     

Three-dimensional model and late stage warping of the Plattengneis Shear Zone in the Eastern Alps

The Plattengneis shear zone is a 250–600 m thick, flat lying, Cretaceous, eclogite facies, mylonitic shear zone, with north-over-south transport direction, that is exposed over almost 1000 km² in the Koralpe region along the eastern margin of the Alps. Although the shear zone is one of the largest in the Alps, its role in the Eoalpine metamorphic evolution and the subsequent exhumation of the region, remain enigmatic and its large-scale geometry is not well understood. The outcrop pattern suggests that the shear zone is made up of a single sheet that is folded into a series of open syn- and antiforms with wavelengths of about 10 km. Eclogite bodies occur above, within and below the shear zone and there is no metamorphic grade change across the shear zone. In the south, the fold axes strike east–west and plunge shallowly to the east. In the north, the fold axes are oriented in north–south direction and form a dome shaped structure of the shear zone. Total shortening during this late stage warping event was of the order of 5%. Indirect evidence constrains this folding event to have occurred between 80 and 50 Ma and the fold geometry implies that the final exhumation in the Koralpe occurred somewhat later than further north. Interestingly, the shear zone appears to strike out of the topography in the south and dip into the topography in the north, so that north of the shear zone only hanging-wall rocks are exposed and south of it only foot-wall rocks. Possibilities for the geometric relationship of the Plattengneis shear zone with the surrounding south dipping detachments are discussed.