On the OH initiated oxidation of C2-C5 aliphatic aldehydes in the presence of mineral aerosols

Clay particles are present in large quantities in mineral dust of atmospheric aerosols, and their interaction with organic species may influence atmospheric reactions and the prediction of environmental risks. However, the kinetics and mechanisms of adsorption and reaction of atmospheric volatile organic compounds on aerosol surfaces are not well understood.In this work, quantum chemical methods are used to study the adsorption of C2-C5 aliphatic aldehydes on silicate clusters active sites, and their subsequent reaction with OH radicals. It is shown that adsorption may occur in two different ways, and that the adsorption complex structure determines the subsequent path of its reaction with OH. The initial step in the OH reaction with acetaldehyde occurs according to the same mechanism as in the gas phase, i.e., the aldehydic hydrogen abstraction. Starting from propanal, another abstraction channel becomes increasingly important, involving mainly the abstraction of a β-hydrogen of the aliphatic chain. In the presence of a silica monomer model surface, the reaction rate of aldehydes with OH free-radicals is smaller than in the gas phase. Furthermore silicates are good sinks for trapping these aldehydes. Thus, our results may have implications in the study of tropospheric chemistry and cosmochemistry.     

Thermal evolution of the western Svalbard margin

The northern Norwegian-Greenland Sea opened up as the Knipovich Ridge propagated from the south into the ancient continental Spitsbergen Shear Zone. Heat flow data suggest that magma was first intruded at a latitude of 75° N around 60 m.y.b.p. By 40–50 m.y.b.p. oceanic crust was forming at a latitude of 78° N. At 12 m.y.b.p. the Hovgård Transform Fault was deactivated during a northwards propagation of the Knipovich Ridge. Spreading is now in its nascent stages along the Molloy Ridge within the trough of the Spitsbergen Fracture Zone. Spreading rates are slower in the north than the south. For the Knipovich Ridge at 78° N they range from 1.5–2.3 mm yr^-1 on the eastern flank to 1.9–3.1 mm yr^-1 on the western flank. At a latitude of 75° N spreading rates increase to 4.3–4.9 mm yr^-1.Thermal profiles reveal regions of off-axial high heat flow. They are located at ages of 14 m.y. west and 13 m.y. east of the northern Knipovich Ridge, and at 36 m.y. on the eastern flank of the southern Knipovich Ridge. These may correspond to episodes of increased magmatic activity; which may be related to times of rapid north-wards rise axis propagation.The fact that the Norwegian-Greenland Sea is almost void of magnetic anomalies may be caused by the chaotic extrusion of basalts from a spreading center trapped within the confines of an ancient continental shear zone. The oblique impact of the propagating rift with the ancient shear zone may have created an unstable state of stress in the region. If so, extension took place preferentially to the northwest, while compression occurred to the southeast between the opening, leaking shear zone and the Svalbard margin. This caused faster spreading rates to the northwest than to the southeast.     

Continental margin off Lofoten-Vesterålen northern Norway

The continental margin off the Lofoten-Vesterålen islands between 67° and 70°N becomes progressively narrower northwards. The continental shelf west of the islands and in the Vestfjord is underlain by a relatively thin sedimentary sequence which has been subjected to block faulting, forming local basins and highs. The structural deformation had ceased in the mid-Creataceous. The Tertiary sediments are generally missing, but reappear in the Træn Basin south of about 67.5°N. The continental margin seaward of the shelf edge changes structural style from south to north. In the north, the marginal subsidence is characterized by major faults, whereas minor faults and flexuring dominate south of 69°N. A smooth acoustic basement reflector, which in places is underlain by dipping sub-basement interfaces, is typical for the area between anomaly 23 and the Vøring Plateau Escarpment. In the northern area, the acoustic basement extends almost to the shelf edge. These observations relate to the early Tertiary history of rifting and passive margin formation within a preexisting epicontinental sea between Norway and Greenland. The abrupt change from continental to oceanic basement is defined by the extension of the Vøring Plateau Escarpment south of 69.1°N and by the change in magnetic character off Vesterålen.     

Thermal implications for the evolution of the spitsbergen transform fault

Heat flow taken between Svalbard and Greenland reveal three thermal provinces:

1. (1) the Molloy Ridge within the Spitsbergen Transform,

2. (2) the Yermak Plateau

3. (3) the northeastern margin of Svalbard (Nordaustlandet).

The Molloy Ridge is a short spreading segment and the average heat flow is much above the Sclater et al. (1971), cooling curve but agrees with values from the Norwegian-Greenland Sea. An additional zone of intrusion identified by heat flow lies to the northwest of the Molloy Ridge. It straddles both the visible fracture zone and part of the Yermak Plateau. A thermal boundary lies between the warm western segment of the Yermak Plateau and the shelf off Nordaustlandet. If the thermal subsidence of the western Yermak Plateau can be traced to the latest heating episode then it is likely that the crust is similar to oceanic in composition and not older than 13 m.y. (approximately 20 m.y. younger than the northeastern segment of the plateau). Plate rotation shows that there was no room for the western segment of the plateau prior to anomaly 7. We postulate that the original transform is associated with the Hornsund Fault zone. In response to deviatoric stress across the oblique ridge-transform system, the Nansen Ridge propagated southwestward aborting the old transform trace, and shifted to its present position.It is suggested that this propagation and migration of the ridge-transform system across a zone of extensional deviatoric stress allowed the massive intrusion of basalt forming the Western Yermak Plateau. The propagation phenomenon coincides with large-scale Tertiary volcanic activity on Svalbard.Readjustment and migration of the oblique transform is still taking place. As the transform-ridge system is liberated from continental constraints, the migration rate will diminish as orthogonality is approached.     

Direct human influence of irrigation on atmospheric water vapour and climate

Human activity increases the atmospheric water vapour content in an indirect way through climate feedbacks. We conclude here that human activity also has a direct influence on the water vapour concentration through irrigation. In idealised simulations we estimate a global mean radiative forcing in the range of 0.03 to +0.1 Wm^–2 due to the increase in water vapour from irrigation. However, because the water cycle is embodied in the climate system, irrigation has a more complex influence on climate. We also simulate a change in the temperature vertical profile and a large surface cooling of up to 0.8 K over irrigated land areas. This is of opposite sign than expected from the radiative forcing alone, and this questions the applicability of the radiative forcing concept for such a climatic perturbation. Further, this study shows stronger links than previously recognised between climate change and freshwater scarcity which are environmental issues of paramount importance for the twenty first century.     

The margin between Senja and Spitsbergen fracture zones: Implications from plate tectonics

Analysis of multichannel seismic data from the continental margin off Svalbard between the Senja and Spitsbergen fracture zones suggests that the transition between continental and oceanic crust is located at or close to the Hornsund Fault Zone. In the Late Paleocene/Early Eoeene (57 m.y.) the region between Svalbard and Northeast-Greenland was subjected to regional shear movements associated with a transform system between the young Lofoten-Greenland Basin and the Arctic Ocean. Approximately 50 m.y. ago the spreading axis migrated to the northeast creating a deep basin north of the Greenland-Senja Fracture Zone forming the passive margin between Bear Island and 76.5°N. North of 76.5°N the regional transform was maintained. At the time of the main reorganization of relative plate motion (36 m.y.) the northern margin evolved. A continental fragment was possibly cut off from the Svalbard margin forming a small microcontinent. The microcontinent appears as the submarine ridge which has been associated with the Hovgaard Fracture Zone. It is suggested that the sediments west of the Hornsund Fault Zone are not older than Eocene in the south and mid-Oligocene in the north. The position of the spreading axis has greatly influenced the margin sedimentation.     

U–Pb TIMS age constraints on the evolution of the Neoproterozoic Meatiq Gneiss Dome,Eastern Desert,Egypt

Ages are used to constrain the temporal evolution of the Meatiq Gneiss Dome, Eastern Desert, Egypt, by dating (ID-TIMS) pre-, syn-, and post-tectonic igneous rocks in and around the dome. The Um Ba’anib Orthogneiss, comprising the deepest exposed structural levels of the dome, has a crystallization age of 630.8 ± 2 Ma. The overlying mylonites are interpreted to be a thrust sheet/complex (Abu Fannani Thrust Sheet) of highly mylonitized metasediments (?), migmatitic amphibolites, and orthogneisses with large and small tectonic lenses of less-deformed intrusives. Two syn-tectonic diorite lenses in this complex have crystallization ages of 609.0 ± 1.0 and 605.8 ± 0.9 Ma, respectively. The syn-tectonic Abu Ziran diorite, cutting across the tectonic contact between mylonite gneisses of the Abu Fannani Thrust Sheet and a structurally overlying thrust sheet of eugeoclinal rocks (“Pan-African nappe”), has a magmatic emplacement age of 606.4 ± 1.0 Ma. Zircons from a gabbro (Fawakhir ophiolite) within the eugeoclinal thrust sheet yielded a crystallization age of 736.5 ± 1.2 Ma. The post-tectonic Fawakhir monzodiorite intrudes the ophiolitic rocks and has an emplacement age of 597.8 ± 2.9 Ma. Two other post-tectonic granites, the Arieki granite that intrudes the foliated Um Ba’anib Orthogneiss, and the Um Had granite that cuts the deformed Hammamat sediments, have emplacement ages of 590 ± 3.1 and 596.3 ± 1.7 Ma, respectively. We consider formation of the Meatiq Gneiss Dome to be a young structural feature (<631 Ma), and our preferred tectonic interpretation is that it formed as a result of NE–SW shortening contemporaneous with folding of the nearby Hammamat sediments around 605–600 Ma, during oblique collision of East and West Gondwana.     

Abatement of Greenhouse Gases: Does Location Matter?

Today's climate policy is based on the assumption that the location of emissions reductions has no impact on the overall climate effect. However, this may not be the case since reductions of greenhouse gases generally will lead to changes in emissions of short-lived gases and aerosols. Abatement measures may be primarily targeted at reducing CO₂, but may also simultaneously reduce emissions of NO_x, CO, CH₄ and SO₂ and aerosols. Emissions of these species may cause significant additional radiative forcing. We have used a global 3-D chemical transport model and a radiative transfer model to study the impact on climate in terms of radiative forcing for a realistic change in location of the emissions from large-scale sources. Based on an assumed 10% reduction in CO₂ emissions, reductions in the emissions of other species have been estimated. Climate impact for the SRES A1B scenario is compared to two reduction cases, with the main focus on a case with emission reductions between 2010 and 2030, but also a case with sustained emission reductions. The emission reductions are applied to four different regions (Europe, China, South Asia, and South America). In terms of integrated radiative forcing (over 100 yr), the total effect (including only the direct effect of aerosols) is always smaller than for CO₂ alone. Large variations between the regions are found (53–86% of the CO₂ effect). Inclusion of the indirect effects of sulphate aerosols reduces the net effect of measures towards zero. The global temperature responses, calculated with a simple energy balance model, show an initial additional warming of different magnitude between the regions followed by a more uniform reduction in the warming later. A major part of the regional differences can be attributed to differences related to aerosols, while ozone and changes in methane lifetime make relatively small contributions. Emission reductions in a different sector (e.g. transportation instead of large-scale sources) might change this conclusion since the NO_x to SO₂ ratio in the emissions is significantly higher for transportation than for large-scale sources. The total climate effect of abatement measures thus depends on (i) which gases and aerosols are affected by the measure, (ii) the lifetime of the measure implemented, (iii) time horizon over which the effects are considered, and (iv) the chemical, physical and meteorological conditions in the region. There are important policy implications of the results. Equal effects of a measure cannot be assumed if the measure is implemented in a different region and if several gases are affected. Thus, the design of emission reduction measures should be considered thoroughly before implementation.