Determination of nutrient salts by automatic methods both in seawater and brackish water: the phosphate blank

The main inconvenience in determining nutrients in seawater by automatic methods is simply solved: the preparation of a suitable blank which corrects the effect of the refractive index change on the recorded signal. Two procedures are proposed, one physical (a simple equation to estimate the effect) and the other chemical (removal of the dissolved phosphorus with ferric hydroxide).     

一维热扩散湖模式在太湖的应用研究

利用在太湖获得的2010年8月11-28日的观测资料研究了一维热扩散湖模式在太湖的适用性,通过对比模拟进一步研究了影响太湖湖表温度模拟的主要因子。该湖模式对太湖最初的模拟结果并不理想,模拟的湖表面温度与观测有较大的系统性偏差,温度的日变化幅度与观测相比也偏小。通过分析该模式对太湖的模拟效果不理想的可能原因,针对太湖的生态环境和污染情况,设计了18个测试参数的敏感性试验,从敏感性试验的结果分析得到,适用于太湖的、依赖于湖泊类型的3个参数应做如下修改:消光系数（η₀）应放大3倍,湖泊表层吸收的太阳辐射系数（β）应取0.8,粗糙长度（z₀）采用公式计算得到。用新得到的适用于太湖的3个参数,模拟得到的结果与最初的模拟结果和观测资料对比,发现采用新的参数后,模拟结果比最初的模拟结果有了很大的改进,模拟的湖表温度基本接近观测,模拟的湖水垂直剖面时间序列图也跟观测吻合得较好,随之的感热、潜热通量的模拟也都与观测接近。最后,对输入湖模式的主要大气参量（太阳辐射、2 m气温及风场）±10%的误差引起的模式模拟的湖表面温度误差进行分析,结果表明该湖模式对大气强迫场的误差敏感度不高;相比之下,模拟结果对风场敏感性最小,对辐射和气温的敏感度相当。     

Influence of the oceanographic conditions during spring 2003 on the transport of the Prestige tanker fuel oil to the Galician coast

Hydrographic data collected during the cruise HIDROPRESTIGE were combined with meteorological and dynamic data provided by remote sensors and drifting/moored buoys, to describe the surface circulation of the Northern Iberian basin in March-April 2003. Sea surface winds transported the floating Prestige oil slicks from the sinking area to the continental slope off the Rías Baixas in 1/2 month: the surface current intensity was 2% of the wind intensity and it was rotated clockwise 5 degrees from the wind direction. Mesoscale cyclonic and anticyclonic structures west of 10 degrees W increased the residence time of oil patches in the Northern Iberian basin, as compared with the expected southwards flow of the Iberian current (IC). On the other hand, the Iberian poleward current (IPC) formed a marked surface front with coastal waters, preventing the entry of fuel oil into the rías. PAHs in the surface layer during the cruise were <0.5 microgL(-1), except in the Galicia bank (approximately 1 microg L(-1); where the Prestige tanker was still leaking) and the vicinity of Cape Fisterra (approximately 1.5 microg L(-1); where the convergence front between the IPC and coastal waters vanished).     

The effect of the "Prestige" oil spill on the plankton of the N-NW Spanish coast

Chlorophyll, primary production, zooplankton biomass and the species composition of phytoplankton and zooplankton were studied in 2003, after the Prestige shipwreck. The information obtained was compared to previous data series available for the area affected by the spill. A large data series on plankton variables for the N-NW Spanish coast existed, and therefore a realistic evaluation of the effects by comparison with the range of natural variability could be carried out. We emphasized the evaluation of impact during the spring bloom, the first important biological event after the spill. Some minor changes were observed occasionally, but they did not show any clear pattern and were more related to the natural variability of the ecosystem than to effect of the spill. Plankton community structure did not undergo any changes. Only a few species were more abundant during spring 2003 than in previous years. No significant changes were detected in the planktonic community during productive periods, such as the spring bloom and the summer blooms related to intrusions of East North Atlantic Central Waters. The lack of evidence of the effects of the spill on planktonic communities is discussed in terms of the characteristics of the fuel, the high dynamics of the water masses, the biological mechanisms through which the fuel from the surface waters is transferred to the sea floor and, particularly, the influence of the natural variability by means of large and meso-scale hydrographic processes in the area under study. At the present time it is not possible to determine any minor effects the spill may have had on the plankton owing to the great variability of the planktonic cycles and the short-term impact of the oil from the Prestige on the pelagic system.     

微晶白云母/聚丙烯酸钠超强吸水性复合材料制备研究

以微晶白云母的超细粉体与丙烯酸为主要原料,采用溶液聚合法制备微晶白云母／聚丙烯酸钠超强吸水性复合材料,优化该复合材料吸自来水性能的配方,即中和度100％,丙烯酰胺用量30％,交联荆用量0．04％,白云母用量60％,引发荆用量0．40％;在此配方下制备的复合材料．吸蒸馏水倍率为420g／g,吸自来水倍率为220g／g,吸生理盐水倍率为55g／g。XRD、SEM分析表明,白云母在复合过程中没有发生结构的变化,在复合材料中均匀分散。同时,该复合材料具有反应便于控制且不粘容器、抗盐性能好、凝胶强度高,特别是白云母可添加60％,丙烯酰胺用量30％,使成本大幅降低。该产品可广泛应用于农林因艺、生态环境治理等领域作保水剂。     

Fingerprinting petroleum hydrocarbons in plankton and surface sediments during the spring and early summer blooms in the Galician coast (NW Spain) after the Prestige oil spill

Plankton samples (20-350 microm and >350 microm) collected at three transects along the Galician coast (NW Spain) were analysed for individual aliphatic and aromatic hydrocarbons by GC-MS. Sample collection was performed in April-July 2003, after the Prestige oil spill (November 2002), to determine whether the hydrocarbons released into the water column as a consequence of the spill were accumulated by the planktonic communities during the subsequent spring and early summer blooms. Surface sediments were also collected to assess the presence of the spilled oil, removed from the water column by downward particle transport. Plankton concentrations of PAHs (Sigma14 parent components) were in the range of 25-898 ng g(-1)dw, the highest values being close to coastal urban areas. However, the individual distributions were highly dominated by alkyl naphthalenes and phenanthrenes, paralleling those in the water dissolved fraction. The detailed study of petrogenic molecular markers (e.g. steranes and triterpanes, and methyl phenanthrenes and dibenzothiophenes) showed the occurrence of background petrogenic pollution but not related with the Prestige oil, with the possible exception of the station off Costa da Morte in May 2003, heavily oiled after the accident. The dominant northerly wind conditions during the spring and early summer 2003, which prevented the arrival of fresh oil spilled from the wreck, together with the heavy nature of the fuel oil, which was barely dispersed in seawater, and the large variability of planktonic cycles, could be the factors hiding the acute accumulation of the spilled hydrocarbons. Then, with the above exception, the concentrations of PAHs found in the collected samples, mostly deriving from chronic pollution, can be considered as the reference values for the region.