Uranium in volcanic rocks from the central Andes

The distribution of U in volcanic rocks from two transects across the Central Andes (latitudes 27°–28° S and 16°–18° S, respectively) differs from that of K. For a given SiO₂, content of the rocks, K systematically increases with the distance from the trench, while the highest U abundances are found in the rocks overlying the thickest segments of the continental crust, which are situated in the middle parts of the transects. It is suggested that this variation of U reflects crustal contamination.     

Geochemistry and origin of volcanic rocks of the Andes (26°–28°S)

Mesozoic to Recent volcanic rocks from a transect of the Central Andes between latitudes 26 ° and 28 ° South in northern Chile and Argentina show chemical and temporal zonation with respect to the Peru-Chile trench. Jurassic to Eocene lavas occur closer to the trench and are comparable to calc-alkaline rocks of island arcs. Eastwards they are followed by Miocene to Quaternary sequences of typical continental margin calc-alkaline rocks which have higher contents of K, Rb, Sr, Ba, Zr, and REE and also higher K/Na and La/Yb ratios. The rocks occurring farthest from the trench have shoshonitic affinities. The distribution of major and trace elements is consistent with a model in which magmas were derived by anatexis of an upper mantle source already enriched in LILE and located above the descending oceanic slab. It is suggested that the chemical variations across the volcanic belt reflect systematic changes in the composition of the magmas due to a decreasing degree of partial melting with increasing depth, and probably also due to the heterogeneity of the source materials.     

Oxygen isotopic compositions of Central Andean plutonic and volcanic rocks,latitudes 26°–29° south

Oxygen isotope data are reported for 27 igneous rocks of Mesozoic to Quaternary age from the Central Andes. 26–29°S. The plutonic rocks, and most of the volcanics, have δ¹⁸O values between 6.2 and 8.3‰.The whole-rock δ¹⁸O values show a weak correlation with initial⁸⁷Sr/⁸⁶Sr data. This O-Sr array differs from documented trends for calc-alkaline plutonic suites from California, Scotland and northern Italy, but overlaps with data for volcanic and plutonic rocks from Ecuador, northern Chile and southern Perú.The oxygen isotope results indicate that the magmas evolved without significant contamination from supracrustal rocks (e.g., rocks that experienced¹⁸O enrichment during surficial weathering). The available O, Sr and Pb isotopic data for these rocks are best explained by magma generation in the upper mantle or lower crust. From the Late Mesozoic on, the⁸⁷Sr/⁸⁶Sr values were modified at depth by isotopic exchange between the magma and a continually thickening crust of plutonic rocks of Late Precambrian to early Mesozoic age.     

Nitrogen distribution in Lower Palaeozoic slates/phyllites of the Meguma Supergroup, Nova Scotia, Canada: implications for Au and Zn-Pb mineralisation and exploration

Major and trace elements and nitrogen were analysed in 59 Cambrian and Ordovician slates/phyllites of various lithostratigraphic levels within the Meguma Supergroup, 14 Ordovician slates/phyllites of The Ovens gold mineralisation, and 16 Ordovician slates/phyllites of the Eastville Pb-Zn-Cu mineralisation.The fixed nitrogen content and the normative N_fix/K₂O ratio of muscovite separates members of the Goldenville (sandstone-greywacke-quartzite dominated) and Halifax Formation (slate-phyllite dominated). Low fixed nitrogen concentration is related to high manganese concentration. Black slates/phyllites of the saddle-reef-type Au-mineralisation in The Ovens area are characterised by high fixed nitrogen and a high normative N_fix/K₂O ratio of muscovite. The nitrogen is of secondary hydrothermal origin. Therefore, it might be possible to use the fixed nitrogen as an exploration tool for black slates/phyllite hosted gold mineralisation in Nova Scotia. Mineralised slates/phyllites of the Eastville stratabound Pb-Zn mineralisation cannot be distinguished from nonmineralised time equivalent lithologies on the basis of the fixed nitrogen distribution or the N_fix/K₂O ratio of muscovite.     

Cooling of the Sverdrup Basin during Tertiary basin inversion: implications for hydrocarbon exploration

ABSTRACT The regional thermal history of the north‐eastern Sverdrup Basin, Canadian Arctic Archipelago, has been assessed using apatite fission‐track thermochronology and vitrinite reflectance data. Fission‐track data for 27 samples from six wells through the Mesozoic section on Axel Heiberg and Ellesmere Islands reveal significant Palaeocene cooling associated with basin inversion during the Eurekan Orogeny. Fission‐track data for 29 outcrop samples, ranging in stratigraphic age from Cambrian to Tertiary, also reveal significant Palaeocene cooling. Vitrinite reflectance data from carbonaceous shales and coal seams in well and outcrop samples are consistent with these conclusions. The degree of Palaeocene cooling observed is greatest for well and outcrop samples in the cores of anticlines or the hanging walls of thrust faults, such as the Fosheim anticline, and faults, such as the Lake Hazen fault system, and the East Cape and Vesle Fiord thrust faults. Palaeocene cooling is largely attributed to the denudation of structures during the Eurekan Orogeny. At one locality on north‐western Ellesmere Island, which is on the northern flank of the Sverdrup Basin, the underlying Franklinian basement rocks yield Early Cretaceous fission track ages with relatively long mean track lengths. This indicates that this part of the basin was uplifted at this time and that subsequent sedimentation and subsidence in the Cretaceous and early Tertiary were modest. This locality thus appears to be on the rift shoulder, which developed along the flank of the Amerasia Basin in the Lower Cretaceous. At a locality on western Axel Heiberg Island, which is downflank from the rift shoulder, the Upper Jurassic Awingak sandstone has a Late Cretaceous fission track age. This is best explained by heating above the total annealing temperature for fission‐tracks in apatite by extensive Lower Cretaceous intrusions and subsequent heat dissipation and cooling in the Late Cretaceous followed by further substantial cooling due to Tertiary denudation. These results indicate that maximum burial temperatures occurred in the presently exposed Mesozoic section prior to basin inversion during the Eurekan Orogeny. It can therefore be inferred that peak hydrocarbon generation and primary migration predated the formation of structural traps during the Tertiary at shallow depths within the northern Sverdrup Basin.     

Field characteristics of laterally emplaced dikes: Anatomy of an exhumed Miocene dike swarm in Reydarfjördur, eastern Iceland

Many dikes of the Tertiary Breiddalur dike swarm in Reydarfjördur have a great lateral extent but are vertically (upward and/or downward) discontinuous. Field relationships indicate that they are not the feeders of the lava pile they intrude. Their characteristics can be best interpreted as them constituting the fossil expression of lateral magma emplacement analogous to that occurring in the actively spreading Krafla volcanic center of the neovolcanic zone. Average dike thickness increases clearly with depth and the thickness versus depth relationship is different from that described for other Tertiary dike swarms in eastern Iceland. It is suggested that dikes represent the extent of finite spreading which at higher levels in the crust is expressed by fissures and other extensional structures.     

Spatial coincidence and similar geochemistry of Late Triassic and Eocene–Oligocene magmatism in the Andes of northern Chile: evidence from the MMH porphyry type Cu–Mo deposit,Chuquicamata District

International Journal of Earth Sciences - The MMH porphyry type copper–molybdenum deposit in northern Chile is the newest mine in the Chuquicamata District, one of largest copper...     

Initial 87Sr/86Sr ratios of plutonic and volcanic rocks of the Central Andes between latitudes 26° and 29° south

Initial⁸⁷Sr/⁸⁶Sr ratios have been determined for 34 plutonic and volcanic rocks covering the entire age span of magmatic events associated with the Andean orogeny between latitudes 26° and 29° south. The igneous rocks, the majority dated by K/Ar mineral techniques, range in age from Lower Jurassic (190 m.y.) to Quaternary (0.89 m.y.). In addition, initial ratios were determined for three granitoid plutons and one metasediment from the pre-Mesozoic basement which underlies the entire Andean orogen in this transect at shallow depth. The compositions vary from basalt to rhyolite, and from quartz diorite to granodiorite or trondjemite, for the extrusives and intrusives, respectively.Mid-Cretaceous to Quaternary rocks exhibit a systematic west to east increase in mean strontium isotope ratio from 0.7022 to 0.7077, whereas the initial ratios of Jurassic plutons vary from 0.7043 to 0.7059, and do not correlate with age.The existence of unusually low initial ratios (e.g. 0.7022, 0.7023) for several Mesozoic plutonic rocks strongly implies a sub-crustal source for at least some of the Andean magmas. The time-dependent post-Jurassic increase in initial ratio is considered to reflect a systematic change in the composition of partial melts generated in response to the progressive subduction of a lithospheric slab. It is suggested that a systematic change in the locus of melting takes place from along or close to the upper surface of the subduction slab into hanging-wall mantle peridotite as subduction continues.     

Pliocene lahar deposits in the Coastal Cordillera of central Chile: Implications for uplift, avalanche deposits, and porphyry copper systems in the Main Andean Cordillera

Lahar deposits occur within a shallow marine sedimentary succession of the Pliocene La Cueva Formation in the Coastal Cordillera of central Chile (33°40′–34°15′S). Provenance studies of the abundant volcanic material in the lahar deposits suggest that they derive from denudation by mass wasting of Oligocene–Miocene volcanic rocks on the western slopes of the Main Andean Cordillera at the same latitude. Pliocene rock debris deposits preserved in the region of El Teniente (34°S) and scattered along the westernmost part of the Andes of central Chile indicate catastrophic erosive events related to the rapid uplift of the cordilleran block. This rock debris was deposited by avalanches and transformed further downslope into lahars by dilution with stream water. Lahars were channeled along the ancient drainage system that reached a shallow Pliocene sea at the site of the present Coastal Cordillera. The exceedingly rapid exhumation of active porphyry systems during the Early Pliocene in this part of the Andes may have played a role in affecting hydrothermal processes, brecciation, and diatreme formation at the porphyry systems of El Teniente and Río Blanco–Los Bronces.