The prospect of high‐precision Pb isotopic dating of meteorites

Abstract— The radiogenic ²⁰⁷Pb/²⁰⁶Pb ratio is the only extant nuclide chronometer with sufficient time resolution for studies of the solar nebula accretion and early asteroidal differentiation and metamorphism. Pb isotopic dates can be used to link the dates obtained from extinct nuclide chronometers to the absolute time scale. The factors that control precision and accuracy of Pb isotopic dates of meteorites: instrumental mass fractionation in isotopic analysis, mass spectrometer sensitivity, removal of common Pb, multi‐stage evolution of U‐Pb systems, disturbances caused by diffusion, alteration, and shock metamorphism, and uncertainties in decay constants and the natural ratio of the U isotopes are reviewed. The precision of Pb isotopic dates of meteorites attained with currently available techniques and methodology is ±0.5–1.0 Myr in favorable cases. The accuracy of time interval measurements is approximately the same. The most serious limitation on precision and accuracy of Pb isotopic dates is placed by the presence of common Pb of uncertain and/or variable isotopic composition. Improvement in precision and accuracy of Pb isotopic dates would be possible through combined advancement of techniques of isotopic analysis (most importantly, better control over instrumental mass fractionation) and more effective techniques for the removal of common Pb, together with a better understanding of the effects of thermal metamorphism, shock metamorphism, and aqueous alteration on the U‐Pb system in meteorites.     

Unique Marine Olenekian-Anisian Boundary Section from South Primorye, Russian Far East

INTRODUCTION LateOlenekianandAnisianmarinedepositsin SouthPrimoryewerefirststudiedbyD.L.Ivanov,thechiefofageologicalteammakingreconnaissance workfortheconstructionofthetrans Siberianrail road.HecollectedEarlyandMiddleTriassicam monoidsonRussianIsland.Arep…     

Some results obtained on the study of the chemical composition of Eurasian oils depending on the depth and age of the reservoir rock

The sulfur, paraffin, resin and asphaltene contents of some 6570 Cenozoic, Mesozoic and Paleozoic Eurasian oils were analysed statistically in terms of reservoir age and depth. The database includes all principal oil-bearing basins from 60 Eurasian countries. The results of the studies of the relationships between the distribution of oils with different sulfur, paraffin, resin and asphaltene contents and the reservoir age and depth are presented. Predictive trends are established allowing polynomial predictions of average properties.     

Surface structure effects on direct reduction of iron oxides by Shewanella oneidensis

The atomic and electronic structure of mineral surfaces affects many environmentally important processes such as adsorption phenomena. They are however rarely considered relevant to dissimilatory bacterial reduction of iron and manganese minerals. In this regard, surface area and thermodynamics are more commonly considered. Here we take a first step towards understanding the nature of the influence of mineral surface structure upon the rate of electron transfer from Shewanella oneidensis strain MR-1 outer membrane proteins to the mineral surface and the subsequent effect upon cell “activity.” Cell accumulation has been used as a proxy for cell activity at three iron oxide single crystal faces; hematite (001), magnetite (111) and magnetite (100). Clear differences in cell accumulation at, and release from the surfaces are observed, with significantly more cells accumulating at hematite (001) compared to either magnetite face whilst relatively more cells are released into the overlying aqueous phase from the two magnetite faces than hematite. Modeling of the electron transfer process to the different mineral surfaces from a decaheme (protoporphyrin rings containing a central hexacoordinate iron atom), outer membrane-bound cytochrome of S. oneidensis has been accomplished by employing both Marcus and ab initio density functional theories. The resultant model of electron transfer to the three oxide faces predicts that over the entire range of expected electron transfer distances the highest electron transfer rates occur at the hematite (001) surface, mirroring the observed cell accumulation data. Electron transfer rates to either of the two magnetite surfaces are slower, with magnetite (111) slower than hematite (001) by approximately two orders of magnitude. A lack of knowledge regarding the structural details of the heme-mineral interface, especially in regards to atomic distances and relative orientations of hemes and surface iron atoms and the conformation of the protein envelope, precludes a more thorough analysis. However, the results of the modeling concur with the empirical observation that mineral surface structure has a clear influence on mineral surface-associated cell activity. Thus surface structure effects must be accounted for in future studies of cell-mineral interactions.     

Models of the REE distribution in the black shale Bazhenov Formation of the West Siberian marine basin,Russia

Rare-earth elements abundance in black shales of the Upper Jurassic (Tithonian Stage)–Lower Cretaceous (Berriassian Stage) Bazhenov Formation is discussed. This formation is the principal oil source rocks of West Siberia. The deposits within the formation can be subdivided into two main marine groups: (a) moderately hemipelagic deposits (clayey-siliceous, including phosphatic and carbonate rocks) and low-density distal clayey turbidites (argillites), both are considered as normal and (b) silty argillites and clayey-silt rocks, which are channel deposits and considered as anomalous. The hemipelagic rocks of normal sections, which are enriched in the rare-earth elements (REE), accumulated under both slow rates of sedimentation (clayey-siliceous rocks) and faster rates of sedimentation (argillites). The channel deposits of anomalous sections, which are impoverished in the REE, accumulated exclusively under fast rates of sedimentation.Within the hemipelagic group the rate of sedimentation of the argillites was faster than of the clayey-siliceous rocks, but the REE concentration in the former rocks (140.4 ppm) is higher than in the latter group (97.4 ppm). The argillites are more than twice enriched in clayey material than clayey-siliceous rocks. It is likely that the clay fraction was the main carrier of REE in these rocks. In the channel group of rocks, the REE abundance in clayey-silt rocks (21.2 ppm) is lower than in the silty argillite (84.6 ppm), in which the clay content is elevated.With respect to redox potential the Bazhenov Formation rocks can be subdivided further into three groups, based on the degree of pyritization index (DOP): (1) the highly reducing clayey-siliceous rocks of normal sections, with high DOP; (2) the substantially reducing argillites and carbonate rocks of normal sections, with intermediate DOP; (3) the moderately reducing rocks of anomalous sections with low DOP. The rocks with the high DOP (group 1) are characterized by ΣLREE/Σ(M+H)REE ratios between 7.37 and 7.5, whereas the rocks with the lower DOP (group 2 and 3) are characterized by ΣLREE/Σ(M+H)REE ratios between 12.8 and 13.5. Negative Ce anomalies are either small or absent in all deposits, which is typical for reducing conditions.Thus, the Bazhenov Formation exemplifies the complex depositional conditions that influence the REE concentration in black shale. However, it is this very complexity that has contributed to the development of six separate depositional models (REE contents in ppm are given in brackets). (1) Phosphatic clayey-siliceous rocks of normal sections (367.95); (2) argillites of normal sections (130.73); (3) clayey-siliceous rocks of normal sections (85.97); (4) carbonate rocks, largely dolomites of normal sections (23.23); (5) silty argillites of anomalous sections (78.7) and (6) clayey-silt rocks of anomalous sections (19.66).     

Influence of anthropogenic pressure and seasonal upwelling on coral reefs in Nha Trang Bay (Central Vietnam)

The growing coastal development, dredging and dumping activities, overfishing and expansion of marine cage culture in Nha Trang Bay (NTB) of Central Vietnam since the beginning of the 2000s have resulted in a dramatic decrease of live coral cover. Surveys conducted in April–May 2013 and the same period in 2014 revealed that with an increase in distance from the outer part of the bay towards the mainland, the rivers’ influxes and dredged areas, coral cover decreased from 75% to 0.6% and species richness from 63 to 5, while the abundance of macroalgae increased from 0% to 56%. These changes correlate with differences in the concentration of suspended sediments on the same gradient. The abundance of the crown‐of‐thorns starfish Acanthaster planci and of the echinoid Diadema setosum significantly increased between the first estimation in 1998 and the survey in 2014, from 0 to 1.7 individuals (ind.) per 100 m^?2 and from 50.8 to 94.5 ind. per 100 m^?2, respectively, contributing to coral loss and intensive bioerosion of the reef framework in the bay. The large sizes of adult colonies of tabulate Acropora on the remote stations with negligible sedimentation and eutrophication loads were inconsistent with the assumptions that temperature‐induced coral bleaching or cyclones could be the major impacts in Nha Trang Bay. Analysis of the 16‐year thermal history of the bay did not reveal any instances in which the coral thermal bleaching threshold had been exceeded up to the present study. Seasonal upwelling, which occurs annually in the vicinity of Central Vietnam, may contribute to mitigation of thermal anomalies within NTB and to the maintenance of healthy coral communities on the remote reefs with relatively low anthropogenic impact.     

Direct Measurements of Deep Currents in the Northern Japan Sea

Long-term current measurements by means of subsurface moorings were made for the first time at seven sites in the Japan Basin, the northern part of the Japan Sea. The objective was to directly explore the velocity field in the highly homogeneous deep water mass (the Japan Sea Proper Water) that occupies depths below 500 m. On each mooring three current meters were equipped at an approximately equal distance below about 1000 m depth. Duration of the measurements was 1 to 3 years depending on specific site. This paper describes the basic data set from the moored measurements. It is found that the deep water of the Japan Basin is very energetic with eddies and vertically coherent currents of the order of 0.1 m/s. Surprisingly, the currents and eddies exhibit strong seasonal dependence even in the deepest layers of the Basin. The observed new current features are discussed in comparison with conventional deep circulation pictures derived from hydrographic data. This revised version was published online in August 2006 with corrections to the Cover Date.     

Statistical methods as indicator of offset printing wastewater quality

This study presents the application of different chemometric approaches on the dataset obtained during the monitoring of offset printing wastewater quality in Pozarevac, Serbia. Collecting of wastewaters was performed during a working week, five working days, in five offset printing facilities. Twenty five physico-chemical parameters were analyzed in wastewaters using the standard analytical and instrumental methods. The obtained dataset were subjected to cluster analysis and principal component analysis. Cluster analysis showed four groups of similarity between the printing facilities reflecting the different physico-chemical characteristics and pollution levels of studied wastewaters. Principal component analysis identified two principal components responsible for the data structure explaining 86 % of total variance of offset printing wastewaters. The obtained principal components indicate the parameters that are the most responsible for variation of offset printing wastewaters. This study clearly demonstrates the usefulness of chemometric methods in analysis of printing wastewater quality, identification of the main sources and understanding of spatial variations in wastewater quality. Also, it could be useful for the selection of an appropriate wastewater treatment plant.     

Robust Scalings in Compressible Flux Pile-Up Reconnection

Flux pile-up magnetic reconnection is traditionally considered only for incompressible plasmas. The question addressed in this paper is whether the pile-up scalings with resistivity are robust when plasma compressibility is taken into account. A simple analytical argument makes it possible to understand why the transition from a highly compressible limit to the incompressible one is difficult to discern in typical simulations spanning a few decades in resistivity. From a practical standpoint, however, flux pile-up reconnection in a compressible plasma can lead to anomalous electric resistivity in the current sheet and flare-like energy release of magnetic energy in the solar corona.