雾水的D和18O同位素研究进展

凝结水的D、¹⁸O同位素研究目前主要集中在雾水方面,露水和土壤吸附水的相关研究仍属空白。由于形成时的温度较高,大多数雾水的D、¹⁸O同位素较当地雨水富集,但不同类型雾的同位素特征存在差异。平流式海洋雾为单级的蒸发—冷凝封闭循环系统的首次凝结,D、¹⁸O同位素较当地雨水显著富集;热带云雾林中的地形雾与降雨同时发生,且水分源于同一云团,δD、δ¹⁸O值差异较小;内陆辐射雾因部分水汽源于当地水分的再循环,过量氘和δD、δ¹⁸O值高于降雨。目前有少量研究用D、¹⁸O同位素指示雾水对植被、地下水和地表径流的补给作用,但以定性分析为主,基于端元混合模型的定量评价极少。露水和土壤吸附水的稳定同位素研究是干旱区凝结水研究的重要方向;D、¹⁸O同位素与其它同位素或化学指标的结合有助于促进凝结水生态水文效应的研究进展;短间隔、高密度的长期观测和用于稳定同位素分析的凝结水采样器的设计是需要进一步开展的工作。     

X2检验假设分布有效性的岩体工程应用

在工程地质问题中许多现象是不确定、且具有随机分布的特性，而这种随机分布特性往往可以采用某种形式的密度函数来描述。采用Ｘ２检验假设分布有效性是一个重要的方法，采用该法可以获得观测数据最佳拟合的概率模型，通过自编程序可以同时检验多种概率密度函数并选取最佳模型。本文将介绍这一方法，并通过一个实例加以说明。     

关于成岩作用与变质作用界线的讨论：从沸石相谈起

成岩作用与变质作用界线的划分是当前地质学界关注的焦点之一。传统的观点将沸石相作为最低级变质相，本文以鄂尔多斯盆地东部上三叠统延长组的浊沸碱玫吐鲁番－哈密盆地哈密凹陷三叠系的浊沸石为例，提出浊沸石的形成为高ｐＨ值，低Ｐｃｏ２和Ｘｃｏ２高钙离子活度，高ＳｉＯ２活性的高盐度等，稳定在从８０℃到２００℃左右的广大温度范围内，常与油气生成带一致，属成岩矿物相，取消沸石相，用明确的综合划分标志来确定成岩作用与     

Removal of Cu(Ⅱ) from Wastewater Using Acidified Sewage Sludge Ash

Sewage sludge ash (SSA), the waste generated in sewage sludge incineration, was obtained from Wuhan Sewage Treatment Plant and used as a low-cost sorbent for removing Cu(Ⅱ) from wastewaters. The sorbent was first modified with 5 % sulfuric acid to increase its sorption capacity. The specific surface area, porosity, cation-exchange capacity (CEC) and pHZPC of the sorbent were measured. Batch experiments were made to study the effect of contact time, solution pH value and temperature on sorption. Both Langmuir and Freundlich models well described the Cu(Ⅱ) sorption process, with correlation coefficient (R2) values of 0.993 4 and 0.989 9 respectively. And the sorption process follows the Lagergren first order kinetic model. The equilibrium sorption capacity of acidified SSA to Cu(Ⅱ) is estimated to be 7.78 mg/g under optimal conditions.     

Shield Tunneling in Rock–Soil Interface Composite Formations

With increased demand for the tunnel construction in rock–soil interface composite formations, the influence on surrounding environment especially the excavation face instability during construction and ground settlement in the long term has gained great attention. The researches about environmental disturbance by shield tunneling construction in single ground as the soil or rock conditions have been developed continuously. However, due to the complexity and uncertainty of the interaction between rock–soil interface composite formations and shield machines, works on these special conditions have not been carried out sufficiently. In this paper the theoretical, experimental and numerical researches on the excavation face stability and ground settlement are discussed while the in situ datum are used to support them. First, the typical projects in rock–soil interface composite formations are listed and the difficulties met are summarized. Second, the failure model of excavation face and support pressure from the tunneling shield in rock–soil interface composite formations are discussed. Then, a comprehensive survey of the factors of ground settlement during and after construction and some effective prediction models are made. Finally, the existing problems and directions for future research are introduced.     

南海北部天然气水合物富集特征及定量评价

为寻找有资源前景的高富集天然气水合物及水合物储层的精细刻画方法,利用南海6次钻探发现的高饱和度水合物层的测井、岩心和三维地震数据,分析水合物富集层测井与地震异常特征.发现:（1）不同饱和度的孔隙与裂隙充填型水合物层的测井和地震异常不同,裂隙充填型水合物层具有各向异性;（2）受高通量流体运移的影响,在粉砂沉积物的水合物稳定带底界附近能形成中等饱和度的水合物层,识别标志为稳定带内极性与海底一致的强振幅反射,而非BSR和振幅空白;（3）裂隙充填型中等饱和度水合物层在地震剖面上表现为地层上拱和弱-中等强度振幅反射.储层-疏导-气源的耦合控制着水合物的富集特征和分布,断层与流体运移控制着细粒粉砂质沉积物中水合物的富集与厚度.基于饱和度岩相的统计学反演,能识别3 m非水合物和低饱和度水合物层及空间分布.      

软土地区人工冻土无侧限瞬时抗压强度的试验研究

冻结法施工在上海隧道建设中(如隧道旁通道、地下泵房等的设计与施工)得到广泛应用,也曾引发过严重的地质灾害(如上海地铁4号线外滩段的地质灾害)。因此安全、经济、合理地将冻结法用于上海软土地区隧道建设中已经成为上海工程建设中的一个重要的研究课题。本文以上海复兴东路越江隧道旁通道冻结法施工中遇到的第⑥层粉质粘土及第⑦层粉细砂为研究对象,针对设计冻结壁重要强度参数无侧限瞬时抗压强度,进行了室内试验研究,揭示了两种土的冻结强度随温度的变化关系,同时研究了粉细砂的冻结强度随含水率的变化规律。     

The behaviour of geosynthetic-reinforced pile foundation under long-term dynamic loads: model tests

In order to reduce the effects of the low strength and high compressibility of soft soil, geosynthetic-reinforced pile foundations (GRPF) are widely applied for the construction of high-speed railways. Though its reinforcement effect is proved acceptable in practices so far, it is unclear whether it will keep this performance as the train speed continues increasing. Since it is impossible to study the problem in field tests, only mathematical and physical models can be used. However, the nonlinear behaviour of the soft soil complicates the use of analytical models. Therefore, this paper presents a small-scale model test to study the possible changes in stress distribution and deformation in the GRPF under increasing dynamic loads. One test with a natural foundation, without piles or geosynthetic, shows the difference with a similar construction with GRPF foundation. Furthermore, three GRPF tests show the influence of the embankment thickness. The results show the long-term dynamic loading significantly affects the dynamic stress and displacements of the subsoil between the piles of the GRPF. This effect can be divided into three stages with an increasing level of load amplitude: no impact, advantageous impact, and adverse impact. When the dynamic load reaches the adverse impact stage, the long-term dynamic loads reduce the dynamic pile–soil stress ratio, which means that more soil settlement will develop, because more dynamic stress is applied to the soft soil. The test results show that the reduction in dynamic stress on the subsoil in the GRPF construction is clearly lower than the dynamic stress on the natural foundation, due to the existence of rigid piles. Moreover, a thicker embankment gives significantly lower dynamic stresses on the subsoil between the piles. For the thickest embankment tested, the adverse impact stage was not found at all: the arching kept enhancing under long-term dynamic loading with high load amplitudes.

     

准噶尔盆地东部中二叠统平地泉组具“斑状”结构热水喷流沉积岩的成因及地质意义*

准噶尔盆地东部中二叠统平地泉组(相当于芦草沟组)发育一套陆内裂谷背景下的湖泊相砂岩、泥岩、灰岩、白云岩、凝灰岩互层以及它们的过渡岩石,是区内最主要的烃源岩和储集层。近年来,在帐北断褶带、石树沟凹陷和吉木萨尔凹陷中二叠统平地泉组暗色泥岩、泥晶白云岩中发现了一类特殊的沉积岩,该类岩石发育类似火山岩的斑状结构。“斑晶”主要为粗晶白云石、方解石、黄铁矿及方沸石等,在岩心标本上呈“树枝状”或“雪花状”散布于基质中;基质则主要由泥晶白云石或泥质沉积物构成,富含有机质,发育水平层理及小型变形层理等。岩石学和矿物学分析表明,“斑晶”往往为粗晶方解石或白云石的集合体,也常见黄铁矿、方沸石与碳酸盐矿物共生,“斑晶”方解石发育环带,而白云石未见明显环带。电子探针分析表明“斑晶”方解石具有低镁、低铁及锶分布不均匀的特点,而“斑晶”白云石(FeO含量介于7.272%~11.086%之间)与“基质”泥晶白云石(FeO含量为1.027%)相比具有明显富铁的特点。流体包裹体分析表明“斑晶”方解石均一温度平均为180.68,℃,“斑晶”白云石均一温度平均为320.95,℃。这种特殊 “斑状”白云岩和“斑状”泥质岩很可能是湖底热液喷流作用的结果。当湖水沿深大断裂下渗至地下深处,与围岩发生物质交换并被加热后再沿断裂返回地表喷涌而出,热液流体携带的离子达到过饱和后就会析出方解石、白云石及黄铁矿等集合体,随热液的喷涌作用上升并破碎散落于湖底细粒沉积物内。“斑状”白云岩的发现对新疆北部中二叠统热水喷流沉积作用及该区油气的成因研究具有重要的意义。     

Exploring Regional Innovation Growth Through A Network Approach:A Case Study of the Yangtze River Delta Region,China

As the leading urban agglomeration in China,the Yangtze River Delta(YRD)is experiencing a factor-driven to innovationdriven transition.However,the dynamics of regional innovation growth are not yet fully understood.This paper combines the complex network methodology with spatial econometrics to disentangle the contributions of innovation endowments,innovation network flows,and innovation network positions to regional innovation growth,as well as their spatial spillover effects.The primary findings suggest that regional innovation growth results from the networked agglomeration economies,which is shaped by the interactions between agglomeration factors and network factors.Specifically,agglomeration factors play a fundamental role in regional innovation growth.In contrast,network factors,such as the network flows and network positions,may contribute to new path creation by promoting access to external innovation resources.Additionally,the institutional factors show multiplexity in fostering regional innovation patterns.Such findings indicate that the YRD region should shift the innovation growth pattern from competitive involution to mutually beneficial cooperation to reduce regional disparities.In this regard,the institutional capacity of organizing network flows and fostering reciprocal inter-city partnerships has become increasingly critical for promoting sustainable innovation and regional development.