Preliminary report on radionuclide concentrations in the bottom waters at the entrance of Wakasa Bay with special reference to the Japan Sea Proper Water

Marked fluctuation of concentrations of⁹⁰Sr and¹³⁷Cs was observed in the bottom waters at the entrance of Wakasa Bay during 1987–1992, and the cause was investigated. The concentrations of⁹⁰Sr and¹³⁷Cs in the bottom waters were significantly low when the upper level of the Japan Sea Proper Water (JSPW) was high and covered the sampling depth, but high when the upper level of the JSPW was low. The cause of the fluctuation observed in the bottom waters is, therefore, suggested to be the vertical fluctuation of the upper level of the JSPW on the shelf slope, which has been little described before.     

Nd and Sr isotopic variations in acidic rocks formed under a peculiar tectonic environment in Miocene Southwest Japan

Initial Nd and Sr isotopic ratios were obtained for middle Miocene igneous rocks as well as for related rocks from the Outer Zone of Southwest Japan to investigate the petrogenesis of acidic magmas and their relation to a peculiar tectonic environment bearing on the back-arc spreading of the Japan Sea. On the _Nd- _Sr diagram, data points for the acidic rocks fall in the – _Nd, + _Sr quadrant occupying different positions from those for sedimentary and old crustal rocks, and seem to define several subparallel lines which extend towards the lower-righthand sedimentary field. The S-type acidic rocks occupy an intermediate position between I-type rocks and sedimentary ones, a fact suggesting mixing of an igneous component and a sedimentary one. The linear mixing trend observed on the _Nd- _Sr diagram can be attained in the restricted case that the igneous component has similar Sr/Nd concentration ratios to that of the sedimentary one, which implies an intermediate to acidic composition for the igneous component. Inconsistency between the elemental and isotopic variations observed may be reconciled by considering that mixing, probably in the relatively deep part of the crust, might have occured prior to chemical differentiation processes. The episodic igneous activity and the high heat energy required to melt such materials involving sedimentary rocks may be explained by a model in which a hot mantle region probably corresponding to the rising part of the mantle convection supplied the heating energy to the Outer Zone of Southwest Japan when passing beneath Southwest Japan in the course of movement of the hot rising part from the Shikoku basin areas to the Japan Sea area.     

Sulfur isotope study of Quaternary volcanic rocks from the Japanese Islands Arc

The sulfide and sulfate contents and their δ³⁴S values were determined in Quaternary volcanic rocks from the Japanese Islands Arc. The total sulfur contents are much lower (less than 40 ppm) and the δ³⁴S values are higher (+4.4 ± 2.1) than those of ocean-floor basalts (800 ± 100 ppm and +0.8 ± 0.5, respectively; Moore and Fabbi, 1971; Sakaiet al., 1982). Lateral variations of both sulfur content and δ³⁴S values were observed in the four volcanic belts in Japan. In the Northeast Japan belt, the sulfur content (30 ± 10 ppm) of the rocks in the inner zone (the Japan Sea side) is 3 to 5 times that in the outer zone (the Pacific side), although the δ³⁴S values of the two zones are almost the same (+4.3 ± 1.0). The δ³⁴S values for the two belts in West Japan are on the average 2%. higher than those of East Japan.This study suggests that the primary magmas that formed the island arc volcanic rocks are initially depleted in sulfur (<120 ppm) and enriched in ³⁴S ($\text{δ}{}^{34}\text{S: +5 ～ +7}$) compared to ocean-floor tholeiitic basalts which formed at mantle under oceanic region. This indicates that the upper-mantle is heterogeneous in sulfur content and isotope composition.     

Fast Oxidation Reaction of Nitrite by Dissolved Oxygen in the Freezing Process in the Tropospheric Aqueous Phase

Nitrite oxidation in the tropospheric aqueous phase by freezing was evaluated by freezing a field sample. Nitrite oxidation by dissolved oxygen in the freezing process is much faster than by other oxidation processes, such as reactions with ozone, hydrogen peroxide or dissolved oxygen in an aqueous solution at pHs 3 to –6. At pH 4.5 and 25°C, the lifetime of nitrite in the aqueous phase is ca. 1 hr in oxidation by ozone (6×10^-10 mol dm^-3), ca. 10 hr in oxidation by H₂O₂ (2×10^-4 mol dm^-3), and 7.5 hr (Fischer and Warneck, 1996) in photodissociation at midday in summer. Under the same conditions at a temperature below 0°C, the lifetime of nitrite in the freezing process is estimated as ca. 2 sec when the droplets are frozen within a second. The reaction by freezing is affected by the presence of salts, such as NaCl or KCl, or orgnaic compounds, such as methanol or acetone. The results of freezing a field rain or fog sample showed that nitrite oxidation proceeds below pH 6, and the conversion ratio of nitrate from nitrite increases with decreasing pH. The oxidation of nitrite by freezing was also observed in freezing fog particles generated by an ultrasonic humidifier. The ratios of the concentrations of ions in the winter sample to those in the summer sample (or those in the fog sample) were almost the same values. However, the concentration of nitrite in the winter sample was lower than that estimated by the ratios of other ions. From the present study, it seems that the freezing process plays an important role in the nitrite sink process in the tropospheric aqueous phase.     

Permo–Triassic Barrovian-type metamorphism in the ultrahigh-temperature Kontum Massif, central Vietnam: Constraints on continental collision tectonics in Southeast Asia

The Kontum Massif in central Vietnam is composed of various metamorphic complexes including a high-temperature southern part (Kannak and Ngoc Linh complexes) and a low- to medium-temperature northern part (Kham Duc complex). The Kham Duc complex exhibits Barrovian-type medium-pressure metamorphism evidenced by kyanite- and/or staurolite-bearing metapelites. The garnet–gedrite–kyanite gneiss, which is the focus of the present study, preserves several mineral parageneses formed during a prograde and retrograde metamorphic history: staurolite + quartz in gedrite, garnet + gedrite + kyanite in the matrix, and spinel + cordierite symplectite between gedrite and sillimanite. The calculated semiquantitative petrogenetic grid reveals peak pressure conditions of 620–650°C at 1.1–1.2 GPa and peak temperature conditions of 730–750°C at 0.7–0.8 GPa. The monazite U–Th–Pb electron microprobe ages of the garnet–gedrite–kyanite gneiss and associated gneisses yield 246 ± 3 Ma for the Kham Duc complex, which is similar to the age of the high- to ultrahigh-temperature metamorphism in the adjacent Kannak and Ngoc Linh complexes of the southern Kontum Massif. The present results indicate that both the Barrovian-type and ultrahigh-temperature metamorphism occurred simultaneously in the Kontum Massif during an event strongly related to Permo–Triassic microcontinental collision tectonics in Asia.     

Formation and shortening deformation of a back-arc rift basin revealed by deep seismic profiling, central Japan

The northern Fossa Magna (NFM) basin is a Miocene rift system produced in the final stages of the opening of the Sea of Japan. It divides the major structure of Japan into two regions, with north-trending geological structures to the NE of the basin and EW trending structures to the west of the basin. The Itoigawa-Shizuoka Tectonic Line (ISTL) bounds the western part of the northern Fossa Magna and forms an active fault system that displays one of the largest slip rates (4–9 mm/year) in the Japanese islands. Deep seismic reflection and refraction/wide-angle reflection profiling were undertaken in 2002 across the northern part of ISTL in order to delineate structures in the crust, and the deep geometry of the active fault systems. The seismic images are interpreted based on the pattern of reflectors, the surface geology and velocities derived from refraction analysis. The 68-km-long seismic section suggests that the Miocene NFM basin was formed by an east dipping normal fault with a shallow flat segment to 6 km depth and a deeper ramp penetrating to 15 km depth. This low-angle normal fault originated as a comparatively shallow brittle/ductile detachment in a high thermal regime present in the Miocene. The NFM basin was filled by a thick (>6 km) accumulation of sediments. Shortening since the late Neogene is accommodated along NS to NE–SE trending thrust faults that previously accommodated extension and produce fault-related folds on their hanging wall. Based on our balanced geologic cross-section, the total amount of Miocene extension is ca. 42 km and the total amount of late Neogene to Quaternary shortening is ca. 23 km.     

ASCA observations of the Galactic superluminal sources GRO J1655–40 and GRS 1915+105

We summarize the ASCA observations of the two Galactic superluminal sources GRO J1655–40 and GRS 1915+105, focusing on theabsorption line features.The high spectroscopic capability of ASCA enabled us to detectiron-K absorption line features from both objects. This is direct evidence for the presence of highly ionized plasma in a non-spherical configuration around a black hole, and is considered to be a unique signature of superluminal jet systems. The candidate of the line-absorber would be a part of an accretion disk at a distance of 10^9-11 cm from the central X-ray source.     

Evaluation of failure of slopes with shaking-induced cracks in response to rainfall

Landslides - Centrifuge model tests on slopes subject to shaking and rainfall have been performed to examine the response of slopes with shaking-induced cracks to subsequent rainfall and evaluate...