Sulfate reduction and sulfide deposition in deep-sea sediments from the southwestern Japan Sea

Vertical profiles of total sulfur and organic carbon have been measured in two deep-sea piston cores from the southwestern Japan Sea where sulfate reduction is proceeding within the sediments. The content of total sulfur, most of which is present as pyrite, increases gradually with increasing depth, showing several peaks. The amount of diagenetically deposited sulfide-sulfur is estimated using a steady-state model that considers vertical change in the diffusion coefficient. It is suggested that two-thirds to three-fourths of the observed total sulfur content has been deposited diagenetically.     

The effects of the reed,Phragmites australis (Trin.), on substratum grain-size distribution in a salt marsh

The effects of the reed,Phragmites australis (Trin.), growing in a brackish water lagoon, were studied in relation to the grain-size distribution of the substratum. At the salt marshes near the lagoon, the upper soils from the surface to a depth of 20 cm contained much silt-clay. These fine particles were found to be transferred from the river and fish ponds near the lagoon, and to be deposited when the tidal rhythm changed, that is, when the water current stopped. In addition, the fine particles, which were deposited on the bottom of the lagoon adjacent to the marshes, became resuspended as a result of wind-caused wave action, and then were transported and redeposited in the salt marshes at the flood tide. Since the reeds further reduced the water current caused by the waves and tide, the reeds were thought to promote redeposition of the resuspended matter. In other words, the reeds were considered to protect deposited and redeposited particles such as silt and clay from resuspension as a result of wave action by reducing the effects of waves and wind. These processes suggested that silt-clay will become abundant in the substratum of the salt marsh adjacent to the lagoon.     

Degradation of lubricating oils by marine bacteria observed by quantitative mass spectrometry

Bacterial degradation of the hydrocarbons of lubricating oils was investigated by mass spectrometric analysis which gives both total amount and the composition of hydrocarbon types of residual oil. An unused lubricating oil, which mainly consisted of hydrocarbon types with only a small percentage ofn-alkanes, was degraded by marineBacillus sp. andPseudomonas sp. with 55 % and 25 % decreases in 10 days, respectively. Susceptibility of respective hydrocarbon types to biodegradation was in the following order: alkanes > non-condensed cycloalkanes, mono-aromatics > condensed cycloalkanes. A used lubricating oil of different brand showed a larger decrease than the unused oil. Both species of bacteria degraded large portions of alkane fraction of Arabian light crude oil.     

Finite-element Simulation of Seismic Ground Motion with a Voxel Mesh

— Accurate simulation of seismic ground motion for three-dimensionally complex topography and structures is one of the most important goals of strong motion seismology. The finite-element method (FEM) is well suited for this kind of simulation, since traction-free conditions are already included in the formulation, and the Courant condition is less strict than for the finite-difference method (FDM). However, the FEM usually requires both large memory and computation time. These limitations can be overcome by using a mesh consisting of voxels (rectangular prisms) with isotropy built into the explicit formulation of the dynamic matrix equation. Since operators in the voxel FEM are the combinations of ordinary FDM operators and additional terms, the method keeps accuracy of the same order as FDM and the terms relax the Courant condition. The voxel FEM requires a similar amount of memory and only takes 1.2～1.4 times longer computation time. The voxel mesh can be generated considerably faster than the popular tetrahedral mesh. Both ground motions and static displacements due to a point or line source can be calculated using the voxel FEM approach. Comparisons with the reflectivity method and theoretical solutions demonstrate the successful implementation of the method, which is then applied to more complex problems.     

Formation Process of Zircon Associated with REE‐Fluorocarbonate and Niobium Minerals in the Nechalacho REE Deposit,Thor Lake,Canada

The two drill holes, which penetrated sub‐horizontal rare earth element (REE) ore units at the Nechalacho REE in the Proterozoic Thor Lake syenite, Canada, were studied in order to clarify the enrichment mechanism of the high‐field‐strength elements (HFSE: Zr, Nb and REE). The REE ore units occur in the albitized and potassic altered miaskitic syenite. Zircon is the most common REE mineral in the REE ore units, and is divided into five types as follows: Type‐1 zircon occurs as discrete grains in phlogopite, and has a chemical character similar to igneous zircon. Type‐2 zircon consists of a porous HREE‐rich core and LREE–Nb–F‐rich rim. Enrichment of F in the rim of type‐2 zircon suggests that F was related to the enrichment of HFSE. The core of type‐2 zircon is regarded to be magmatic and the rim to be hydrothermal in origin. Type‐3 zircon is characterized by euhedral to anhedral crystals, which occur in a complex intergrowth with REE fluorocarbonates. Type‐3 zircon has high REE, Nb and F contents. Type‐4 zircon consists of porous‐core and ‐rim, but their chemical compositions are similar to each other. This zircon is a subhedral crystal rimmed by fergusonite. Type‐5 zircon is characterized by smaller, porous and subhedral to anhedral crystals. The interstices between small zircon grains are filled by fergusonite. Type‐4 and type‐5 zircon grains have low REE, Nb and F contents. Type‐1 zircon is only included in one unit, which is less hydrothermally altered and mineralized. Type‐2 and type‐3 zircon grains mainly occur in the shallow units, while those of type‐4 and type‐5 are found in the deep units. The deep units have high HFSE contents and strongly altered mineral textures (type‐4 and type‐5) compared to the shallow units. Occurrences of these five types of zircon are different according to the depth and degree of the hydrothermal alteration by solutions rich in F and CO₃, which permit a model for the evolution of the zircon crystallization in the Nechalacho REE deposit as follows: (i) type‐1 (discrete magmatic zircon) is formed in miaskitic syenite. (ii) LREE–Nb–F‐rich hydrothermal zircon formed around HREE‐rich magmatic zircon (type‐2). (iii) type‐3 zircon crystallized through the F and CO₃‐rich hydrothermal alteration of type‐2 zircon which formed the complex intergrowth with REE fluorocarbonates; (iv) the CO₃‐rich hydrothermal fluid corroded type‐3, forming REE–Nb‐poor zircon (type‐4). Niobium and REE were no longer stable in the zircon structure and crystallized as fergusonite around the REE–Nb‐leached zircon (type‐4); (v) type‐5 zircon is formed by the more CO₃‐rich hydrothermal alteration of type‐4 zircon, suggested by the fact that type‐4 and type‐5 zircon grains are often included in ankerite. Type‐3 to type‐5 zircon grains at the Nechalacho REE deposit were continuously formed by leaching and/or dissolution of type‐2 zircon in the presence of F‐ and/or CO₃‐rich hydrothermal fluid. These mineral associations indicate that three representative hydrothermal stages were present and related to HFSE enrichment in the Nechalacho REE deposit: (i) F‐rich hydrothermal stage caused the crystallization of REE–Nb‐rich zircon (type‐2 rim and type‐3), with abundant formation of phlogopite and fluorite; (ii) F‐ and CO₃‐rich hydrothermal stage led to the replacement of a part of REE–Nb–F‐rich zircon by REE fluorocarbonate; and (iii) CO₃‐rich hydrothermal stage resulted in crystallization of the REE–Nb–F‐poor zircon and fergusonite, with ankerite. REE and Nb in hydrothermal fluid at the Nechalacho REE deposit were finally concentrated into fergusonite by way of REE–Nb–F‐rich zircon in the hydrothermally altered units.     

Wide-Field Camera for Gravitational Microlensing Survey: MOA-cam2

We have constructed a large, mosaic CCD camera called MOA-cam2 which has 4096 × 6144-pixelsto search for gravitational microlensing events. MOA-cam2 has three4096 × 2048-pixel SITe CCD chips, which have a very high quantum efficiency (nearly 80% in the wave region 500 to 800 nm),and three buttable sides. We have placed the threechips side by side with 100 m dead space. MOA-cam2 has been installed on the 61 cm Boller and Chivens telescope of the MOA collaboration at the Mt. John University Observatory (MJUO) in NewZealand since July 1998. The field coverage is 0.92° × 1.38° per exposure. The technical details of MOA-cam2 and the first images obtained with the Boller and Chivens telescope are presented. MOA-cam2 introduces a second phase of research on gravitational microlensing by the MOA collaboration.     

Vertical zonation and aggregated distribution of the Manila clam on subtidal sand flats in a coastal brackish lagoon along the Sea of Japan

The Manila clam, Ruditapes philippinarum, has maintained small‐sized populations in a semi‐enclosed brackish lake along the Sea of Japan, the Honjo area of Lake Nakaumi, although the environment and biota of this area have changed dramatically due to a large‐scale reclamation project. There should be underlying processes that enable the restoration of this species from small‐sized populations, such as the existence of source (i.e. reproductive) populations in other areas and depth zones of the lake. However, there has been no robust, properly designed evaluation of the distribution of the Manila clam in the subtidal sand flats. In order to elucidate the possible mechanisms that allow for the persistence of populations of the Manila clam, we examined the spatiotemporal and vertical variation in distributions of 0‐age clams in the subtidal zone of sand flats. Seasonal effects on population variations showed erratic changes among depth zones without a decreasing trend along the depth gradient. Further, many local populations became extinct even in the shallower zones due to seasonal (summer) hypoxia at deeper zones and hypoxia by the accumulation of key benthic species (Asian mussel and decaying macroalgae) in mats at shallower zones. A few surviving local populations were stable with a spatial‐fragmental (patchy) distribution, associated with fragmented accumulations of Asian mussels and macroalgae. Efforts to maintain stable populations and to restore this species in the subtidal area may depend on these small, restricted, patchy local populations. These findings suggest that high fertility and productivity of the Manila clam as well as patchy distribution of small populations may contribute to the maintenance of the population and the avoidance of extinction (by spatially diffusing the risk of extinction) in harsh environments resulting from the reclamation project.     

Estimation of snow ablation under a dust layer covering a wide range of albedo

Ablation processes of snow under a thin dust cover are complicated compared with those under a thick cover, mainly owing to the effects of aggregation (redistribution) of dust particles on the conditions of surface melting. Aggregation of dust particles causes the snow surface to brighten after the initial dust configuration, thus affecting the relationship between initial dust concentration and surface albedo. In order to estimate snow ablation rate under a thin dust cover, we used a composite energy balance model in which the surface albedo is taken as a measured input variable. The estimated results of snow ablation agreed reasonably well with the observation, considering the measurement errors inherited in the snow depressions. Comparison of the two cases, that is, one considering the aggregation of dust particles (observation: albedo variable) and the other without aggregation (assumption: albedo constant), showed that the ablation rates were noticeably lower on the former case. This suggests that the aggregation of dust particles induces a reduction of snow ablation. Copyright © 2002 John Wiley & Sons, Ltd.