Oxygen Isotope Evidence for Chemical Interaction of Ki lauea Historical Magmas with Basement Rocks

Klauea historical summit lavas have a wide range in matrix ¹⁸O_VSMOWvalues (4·9–5·6) with lower values in rockserupted following a major summit collapse or eruptive hiatus.In contrast, ¹⁸O values for olivines in most of these lavasare nearly constant (5·1 ± 0·1). The disequilibriumbetween matrix and olivine ¹⁸O values in many samples indicatesthat the lower matrix values were acquired by the magma afterolivine growth, probably just before or during eruption. BothMauna Loa and Klauea basement rocks are the likely sources ofthe contamination, based on O, Pb and Sr isotope data. However,the extent of crustal contamination of Klauea historical magmasis probably minor (< 12%, depending on the assumed contaminant)and it is superimposed on a longer-term, cyclic geochemicalvariation that reflects source heterogeneity. Klauea's heterogeneoussource, which is well represented by the historical summit lavas,probably has magma ¹⁸O values within the normal mid-ocean ridgebasalt mantle range (5·4–5·8) based on thenew olivine ¹⁸O values. KEY WORDS: Hawaii; Klauea; basalt; oxygen isotopes; crustal contamination     

The electrical structure of the Slave craton

The Slave craton in northwestern Canada, a relatively small Archean craton (600×400 km), is ideal as a natural laboratory for investigating the formation and evolution of Mesoarchean and Neoarchean sub-continental lithospheric mantle (SCLM). Excellent outcrop and the discovery of economic diamondiferous kimberlite pipes in the centre of the craton during the early 1990s have led to an unparalleled amount of geoscientific information becoming available.

Over the last 5 years deep-probing electromagnetic surveys were conducted on the Slave, using the natural-source magnetotelluric (MT) technique, as part of a variety of programs to study the craton and determine its regional-scale electrical structure. Two of the four types of surveys involved novel MT data acquisition; one through frozen lakes along ice roads during winter, and the second using ocean-bottom MT instrumentation deployed from float planes.

The primary initial objective of the MT surveys was to determine the geometry of the topography of the lithosphere–asthenosphere boundary (LAB) across the Slave craton. However, the MT responses revealed, completely serendipitously, a remarkable anomaly in electrical conductivity in the SCLM of the central Slave craton. This Central Slave Mantle Conductor (CSMC) anomaly is modelled as a localized region of low resistivity (10–15 Ω m) beginning at depths of 80–120 km and striking NE–SW. Where precisely located, it is spatially coincident with the Eocene-aged kimberlite field in the central part of the craton (the so-called “Corridor of Hope”), and also with a geochemically defined ultra-depleted harzburgitic layer interpreted as oceanic or arc-related lithosphere emplaced during early tectonism. The CSMC lies wholly within the NE–SW striking central zone defined by Grütter et al. [Grütter, H.S., Apter, D.B., Kong, J., 1999. Crust–mantle coupling; evidence from mantle-derived xenocrystic garnets. Contributed paper at: The 7th International Kimberlite Conference Proceeding, J.B. Dawson Volume, 1, 307–313] on the basis of garnet geochemistry (G10 vs. G9) populations.

Deep-probing MT data from the lake bottom instruments infer that the conductor has a total depth-integrated conductivity (conductance) of the order of 2000 Siemens, which, given an internal resistivity of 10–15 Ω m, implies a thickness of 20–30 km. Below the CSMC the electrical resistivity of the lithosphere increases by a factor of 3–5 to values of around 50 Ω m. This change occurs at depths consistent with the graphite–diamond transition, which is taken as consistent with a carbon interpretation for the CSMC.

Preliminary three-dimensional MT modelling supports the NE–SW striking geometry for the conductor, and also suggests a NW dip. This geometry is taken as implying that the tectonic processes that emplaced this geophysical–geochemical body are likely related to the subduction of a craton of unknown provenance from the SE (present-day coordinates) during 2630–2620 Ma. It suggests that the lithospheric stacking model of Helmstaedt and Schulze [Helmstaedt, H.H., Schulze, D.J., 1989. Southern African kimberlites and their mantle sample: implications for Archean tectonics and lithosphere evolution. In Ross, J. (Ed.), Kimberlites and Related Rocks, Vol. 1: Their Composition, Occurrence, Origin, and Emplacement. Geological Society of Australia Special Publication, vol. 14, 358–368] is likely correct for the formation of the Slave's current SCLM.     

Disjunctive Kriging with Hard and Imprecise Data

This paper presents a methodology for assessing local probability distributions by disjunctive kriging when the available data set contains some imprecise measurements, like noisy or soft information or interval constraints. The basic idea consists in replacing the set of imprecise data by a set of pseudohard data simulated from their posterior distribution; an iterative algorithm based on the Gibbs sampler is proposed to achieve such a simulation step. The whole procedure is repeated many times and the final result is the average of the disjunctive kriging estimates computed from each simulated data set. Being data-independent, the kriging weights need to be calculated only once, which enables fast computing. The simulation procedure requires encoding each datum as a pre-posterior distribution and assuming a Markov property to allow the updating of pre-posterior distributions into posterior ones. Although it suffers some imperfections, disjunctive kriging turns out to be a much more flexible approach than conditional expectation, because of the vast class of models that allows its computation, namely isofactorial models.     

Construction of Structural Geological Model Using Monte Carlo Simulation

Geotechnical and Geological Engineering - To optimize the prediction of structural geological conditions in the underground as of data collected at the surface, due to the usual great uncertainties...     

Spectral simulation of vector random fields with stationary Gaussian increments in <Emphasis Type="Italic">d</Emphasis>-dimensional Euclidean spaces

This paper addresses the problem of simulating multivariate random fields with stationary Gaussian increments in a d-dimensional Euclidean space. To this end, one considers a spectral turning-bands algorithm, in which the simulated field is a mixture of basic random fields made of weighted cosine waves associated with random frequencies and random phases. The weights depend on the spectral density of the direct and cross variogram matrices of the desired random field for the specified frequencies. The algorithm is applied to synthetic examples corresponding to different spatial correlation models. The properties of these models and of the algorithm are discussed, highlighting its computational efficiency, accuracy and versatility.     

Tuning the second-generation SDI: theoretical aspects and real use cases

Spatial data infrastructure (SDI) actors have great expectations for the second-generation SDI currently under development. However, SDIs have many implementation problems at different levels that are delaying the development of the SDI framework. The aims of this article are to identify these difficulties, in the literature and based on our own experience, in order to determine how mature and useful the current SDI phenomena are. We can then determine whether a general reconceptualization is necessary or rather a set of technical improvements and good practices needs to be developed before the second-generation SDI is completed. This study is based on the following aspects: metadata about data and services, data models, data download, data and processing services, data portrayal and symbolization, and mass market aspects. This work aims to find an equilibrium between user-focused geoportals and web service interconnection (the user side vs. the server side). These deep reflections are motivated by a use case in the healthcare area in which we employed the Catalan regional SDI. The use case shows that even one of the best regional SDI implementations can fail to provide the required information and processes even when the required data exist. Several previous studies recognize the value of applying Web 2.0 and user participation approaches but few of these studies provide a real implementation. Another objective of this work is to show that it is easy to complement the classical, international standard-based SDI with a participative Web 2.0 approach. To do so, we present a mash-up portal built on top of the Catalan SDI catalogues.     

Geochemical and hydrodynamic constraints on the distribution of trace metal concentrations in the lagoon of Nouméa, New Caledonia

Seawater samples were collected in the lagoon of Nouméa (southwest New Caledonia) along two transects from eutrophic coastal bays to the oligotrophic barrier reef. Land-based emissions to the lagoon were measured with dissolved and particulate concentrations of chromium (Cr) and nickel (Ni), used as tracers of both terrigenous and industrial (Ni ore treatment) activities, as well as dissolved and particulate concentrations of zinc (Zn), used as a tracer of urban effluents. The spatial variability of metal concentrations was related to geochemical and hydrodynamic conditions, i.e., respectively: (1) natural and anthropogenic emission sources, and chemical processes occurring in the water column; and (2) water residence times. The parameter used to describe the residence time of water masses was the local e-flushing time, i.e. the time required for a tracer mass contained within a given station to be reduced by a factor 1/e. High metal concentrations were found in coastal areas (up to 9000 ng dissolved Ni L⁻¹), and steeply decreased with distance from the coast (down to 101 ng dissolved Ni L⁻¹ near the barrier reef) to reach levels similar to those found in remote Pacific waters, suggesting a rapid renewal of waters close to the barrier. Distributions of metals in the lagoon are controlled upstream by land-based emission sources and later chemical processes. Then hydrodynamics constrain metal distributions, as shown by the observed relationship between local e-flushing times and the spatial variability of metal concentrations. In addition, a change in the direction of prevailing winds yielded a decrease of dissolved metal concentrations at the same site by a factor of 2.5 (Cr and Ni) and 2.9 (Zn). It is suggested that the residence time is a key parameter in the control of elemental concentrations in the lagoon waters, as much as land-based emission sources.