Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

Spectroscopic studies of three novae

We present our spectroscopic observations of the novae V1425, V1493, and V1494 Aql carried out with the 125-cm telescope at the Crimean Station of the Sternberg Astronomical Institute in the wavelength range 4000–11000 Å. We measured the emission-line intensities, determined the nova shell expansion velocities from the line profile FWHMs and components, and estimated the interstellar reddening from the first members of the Balmer series. The chemical composition of the nova shells is analyzed. Nitrogen and oxygen were found to be overabundant in V1425 and V1494 Aql; the helium abundance turned out to be normal in the two stars.     

Pulsar magnetic field for an infinitely conductive accretion disk

The magnetic-field distribution outside a flat, infinitely conductive unbounded disk in the field of a point magnetic dipole is determined. A relationship is established between the problem of magnetic-field determination and the problem of the flow of an ideal incompressible fluid around an infinitely thin disk.     

Numerical Modeling of the Largest Terrestrial Meteorite Craters

Multi-ring impact basins have been found on the surfaces of almost all planetary bodies in the Solar system with solid crusts. The details of their formation mechanism are still unclear. We present results of our numerical modeling of the formation of the largest known terrestrial impact craters. The geological and geophysical data on these structures accumulated over many decades are used to place constraints on the parameters of available numerical models with a dual purpose: (i) to choose parameters in available mechanical models for the crustal response of planetary bodies to a large impact and (ii) to use numerical modeling to refine the possible range of original diameters and the morphology of partially eroded terrestrial craters. We present numerical modeling results for the Vredefort, Sudbury, Chicxulub, and Popigai impact craters and compare these results with available geological and geophysical information.     

A standard format for reporting PILPS experiments

In model inter-comparisons one major obstacle is the format of the reported data. To facilitate the analysis of the results from the different models they should all be reported in the same format. This requires that the format is flexible enough to be easily implemented into the different land surface schemes. It should also be fault tolerant and allow a few consistence checks to avoid erroneous data to be submitted. The present note describes such a format developed for the PILPS project. After discussing the aim of this new format we present the routines which are used to write and read data. Finally two applications are described which allow the user to perform a number of consistency checks on the data.     

On the stability of particular solutions of the singly averaged Hill problem

We consider the particular solutions of the evolutionary system of equations in elements that correspond to planar and spatial circular orbits of the singly averaged Hill problem. We analyze the stability of planar and spatial circular orbits to inclination and eccentricity, respectively. We construct the instability regions of both particular solutions in the plane of parameters of the problem.     

An approximate method for evaluating the shear band thickness in saturated soils

A formula for the thickness of a shear band formed in saturated soils under a simple shear or a combined stress state has been proposed. It is shown that the shear band thickness is dependent on the pore pressure properties of the material and the dilatancy rate, but is independent of the details of the combined stress state. This is in accordance with some separate experimental observations. Copyright © 2004 John Wiley & Sons, Ltd.