Magnetic properties related to hydrothermal alteration processes at the Escondida porphyry copper deposit,northern Chile

Fluid–rock interaction related to the circulation of hydrothermal fluids can strongly modify the physicochemical properties of wall rocks in porphyry Cu deposits. These processes can also produce compositional and textural changes in ferromagnetic minerals, which can be quantified using magnetic methods. In the Escondida porphyry Cu deposit of northern Chile, each hydrothermally altered lithology is characterized by a discrete assemblage of Fe–Ti oxide minerals. These minerals have distinctive bulk magnetic susceptibility (K _bulk), temperature-dependent magnetic susceptibility, and magnetic hysteresis parameters. Selectively altered rocks (i.e., potassic and chloritic alteration types) exhibit the highest K _bulk values (>3.93?×?10^?3 SI units), and their hysteresis parameters indicate multidomain magnetic mineral behavior. This suggests that these rocks are composed of the coarsest magnetic grain sizes within the deposit. Optical analyses and susceptibility–temperature curves confirm that the magnetic signals in selectively altered rocks are mainly carried by secondary magnetite. In contrast, pervasively altered rocks (i.e., quartz-sericite and argillic alteration types) exhibit low K _bulk values (<1.93?×?10^?4 SI units) and contain smaller pseudo-single domain magnetic grain assemblages. This is consistent with the destruction and/or reduction in size of magnetite under acidic conditions. The results therefore demonstrate a genetic relationship between the hydrothermal alteration processes, Fe–Ti oxide minerals, and magnetic properties of the wall rock in the Escondida deposit. These magnetic methods can be considered a sensitive and efficient petrophysical tool for the identification and semi-quantification of alteration assemblages, and facilitating the recognition and mapping of discrete hydrothermal zones during exploration and operation of porphyry Cu deposits.     

Rhyacian (2.23–2.20 Ga) juvenile accretion in the southern São Francisco craton,Brazil: Geochemical and isotopic evidence from the Serrinha magmatic suite,Mineiro belt

The Serrinha magmatic suite (Mineiro belt) crops out in the southern edge of the São Francisco craton, comprising the Brito quartz-diorite, Brumado de Cima and Brumado de Baixo granodiorites, granophyres and felsic sub-volcanic and volcanic rocks, part of which intruded into the Nazareno greenstone belt. The suite rocks have petrographic features that are consistent with magma supercooling due to the low water content combined with volatile loss, leading to crystallization of quartz and alkaline feldspar at the rims of plagioclase phenocrysts (granophyric intergrowth). The investigated rocks are sub-alkaline, calc-alkaline and show low content in rare earth elements. The U–Pb zircon crystallization ages for the Brumado de Cima granodiorite [2227 ± 22 (23) Ma] and a coeval granophyre [2211 ± 22 (23) Ma], coupled with available single-zircon Pb evaporation ages for the Brito and Brumado de Baixo plutons, are significantly older than the “Minas orogeny” (ca. 2100–2050 Ga) of Quadrilátero Ferrífero area, eastward from the Serrinha suite. Our data establish an early Rhyacian event tectonically linked with the evolution of the Mineiro belt. The bulk Nd isotopic signature [low negative to positive ε_Nd(t) values] of the Serrinha samples are consistent with the important role of Paleoproterozoic mantle components in the magma genesis. The integrated geologic, geochemical and isotopic information suggests that Paleoproterozoic evolution of the Mineiro belt initiated in a passive continental margin basin with deposition of the Minas Supergroup at ca. 2500 Ma. This stage was succeeded by outboard rupture of the oceanic lithosphere with development and coalescence of progressively younger magmatic arcs during Rhyacian time. One of the earliest arcs formed the Serrinha suite. The tectonic collage of the Serrinha and Ritápolis (2190–2120 Ma) arcs produced the NE–SW Lenheiro shear zone, resulting in mylonitization and recrystallization of both the granitoid intrusions and host rocks. As a matter of fact juxtaposition of distinct magmatic units in age and origin took place along the Lenheiros structure in this sector of the Mineiro belt.     

Population Dynamics and Secondary Production of Emerita brasiliensis (Crustacea: Hippidae) at Prainha Beach, Brazil

Abstract. The secondary production and population dynamics of the mole crab Emerita brasiliensis Schmitt, 1935 (Decapoda: Hippidae) were studied by taking monthly samples from June 1993 to May 1995 at each of three intertidal transects at Prainha beach, Brazil. The lifespan was ca. 8 months for males and females, but females showed higher growth, mortality, secondary production, and turnover rate. The higher production in spring versus autumn and winter was related to intense recruitment during that period. The population production was estimated at between 39.86 and 46.88 g (AFDW) · m^?2 · a^?1 for the first year (June 93–May 94) and between 150.95 and 156.07 g (AFDW) · m^?2 · a^?1 for the second year (June 94–May 95); the mean annual biomass was 4.91 and 23.09 g (AFDW) · m^?2, respectively. High P/B rates, between ca. 6 and 9 · a^?1, reflected the fast growth, high mortality, and low lifespan of the population, characterized by a high percentage of recently recruited individuals.     

A review of the geodynamic constraints on the development and evolution of geothermal systems in the Central Andean Volcanic Zone (18–28°Lat.S)

ABSTRACT

Geothermal exploration in the Central Andean Volcanic Zone (CAVZ) focuses on heat capacities of known geothermal systems, yet the role of faults, veins, fractures and folds on the evolution and migration of fluids is far from complete. Here, we present a compilation of He and Sr isotope data and newly generated structural maps to examine if particular tectonic configurations are associated with fluids migrating from different crustal levels. Accordingly, we defined three tectono-geothermal environments (T1–T3) depicting specific structural arrangements and spatial relation with geothermal and volcanic manifestations. T1 is dominated by left-lateral strike-slip NW-striking faults, and geothermal and volcanic manifestations occur along the traces of these structures. T2 is dominated by N-striking thrust faults and parallel fault-propagated folds, cut and displaced by NW-striking faults. Here, geothermal manifestations occur at fault intersections and at fold hinges. T3 is defined by left-lateral/normal NW-striking faults, with geothermal and volcanic manifestations lying along fault traces. Each tectono-geothermal environment yields distinctive isotope ratios and geothermal reservoir temperatures. T1 shows high helium and low strontium ratios, and temperatures between 220° and 310°C. T3 shows low helium and high strontium ratios and temperatures between 260° and 320°C. T2 isotope ratios fall between T1 and T3, with lowest (130°-250°C) reservoir temperatures. We argue that these particular isotope signatures are due to a structural control on reservoir location and orientation. The orientation of the fracture mesh genetically associated with each tectono-geothermal environment is a first-order control on the migration pathway of fluids. Our model shows that T1 allows fluxing of deeper fluids, T2 promotes storage and favors longer residence times and T3 enhances subvertical fluid migration. Results here help to explain the evolution of geothermal systems in a wider context, including fault systems and Sr and He isotope variations, thus providing a framework for geothermal exploration in the CAVZ.     

Tectonic rotations during the Chile Ridge collision and obduction of the Taitao ophiolite (southern Chile)

Abstract The < 6 Ma young Taitao ophiolite, exposed at the westernmost promontory of the Taitao Peninsula, is located approximately 40 km southeast of the Chile triple junction and consists of a complete sequence of oceanic lithosphere. Systematic sampling for paleomagnetic study was performed to understand the complex obduction processes of the ophiolite onto the forearc of the South American Plate. Two representative demagnetization paths of remanent magnetization vectors were observed. One is characterized by stable univectorial demagnetization paths and was observed in volcaniclastic rocks and dyke complexes. Orientations of their remanent magnetization vectors indicate various degrees of counterclockwise rotations. The other is characterized by multivectorial demagnetization paths and was observed in the plutonic units (gabbros and ultramafic rocks). From these, two distinct stable remanent magnetization vectors were isolated; one has high coercivity and the other has low coercivity along the demagnetization paths with little influence of viscous magnetizations. This suggests that the complex deformation history involved at least two rotational events. The clockwise rotation, inferred from high coercivity remanent magnetization vectors, was attributed to a ridge collision event and the counterclockwise rotation, inferred from the low coercivity remanent magnetization vectors, was attributed to an accommodation phase into the South American forearc during obduction and final emplacement of the ophiolite. Folds developed during this period. Paleomagnetic restorations of the internal structures of the plutonic units and dyke complexes suggest that they probably originated in a mid‐oceanic ridge environment near a transform fault. The counterclockwise rotation of the plutonic and dyke complex units during the obduction generated tectonic gaps between these and the basement. The volcaniclastic rocks must have been deposited at nearly their present location, filling the tectonic gaps, as less effect of tectonic rotation was identified on these rocks.     

A Comparison of Statistical Techniques for Detecting Analytical Bias in Geoanalysis

Detecting analytical bias is a valuable step during method validation and, in the case of the mining industry, fundamental when one validates the geological databases used for resource estimation. This will generally affect the costs of future investments in new or expanding projects. This paper details frequently used techniques for doing this, with their theoretical background, advantages and shortcomings, providing a deeper insight in how to choose a method for special applications. This is done by means of a review of the specialised literature, and by showing practical applications. The latter is done by choosing some of the most commonly used methods, comparing them using Monte Carlo simulations and testing in some real applications (analytical methods used in Brazilian prospects for copper, gold and iron). Consequently, laboratory specialists will have a better understanding of statistical tools for this purpose, being able to provide their customers with a very consistent assurance of chemical analytical results. It is shown that some commonly used statistical methods for this type of comparison are not applicable, and in some cases, one must resort to more complicated models. These are, however, easily implemented computationally, and the mathematical details are shown.     

Responses of talitrid amphipods to a gradient of recreational pressure caused by beach urbanization

Demands for public outdoor recreation and urbanization are a potential source of environmental disturbances, particularly on sandy beaches. These habitats have therefore experienced rapid degradation worldwide. Talitrid amphipods, which are common inhabitants of sandy beaches, are probably good indicators of such disturbances. In this study, we evaluated the responses of the two amphipods Talitrus saltator and Atlantorchestoidea brasiliensis to human pressure on Spanish and a Brazilian beach, hypothesizing that disregarding species differences, their population sizes will decline under urbanized conditions. The Barra da Tijuca (Brazil) and Levante (Spain) beaches have mixed landscapes with varying levels of development, and each has a protected area (MPA) adjacent to urbanized sites. Numbers of talitrids as well as visitors were compared among sites on each beach. Talitrids were most abundant at the protected sites. This was true of both beaches, even though temporal patterns of human activity were quite different, with Levante experiencing sharp declines in the number of visitors during its harsh winter. Urbanized sites did not experience high Talitrid densities even during a period of low human pressure. On this basis, T. saltator and A. brasiliensis were considered good indicators of urbanization and recreational activities on sandy beaches. MPAs were found to be very important for the successful conservation of the talitrid populations. A feasible method of managing human pressure and thereby conserving beach biodiversity therefore seems to be the establishment of beach MPAs.     

Characterization of a landslide-triggered debris flow at a rainforest-covered mountain region in Brazil

Natural Hazards - Debris flows represent great hazard to humans due to their high destructive power. Understanding their hydrogeomorphic dynamics is fundamental in hazard assessment studies,...