Semi-analytical solutions of a contaminant transport equation with nonlinear sorption in 1D

A new method to determine semi-analytical solutions of one-dimensional contaminant transport problem with nonlinear sorption is described. This method is based on operator splitting approach where the convective transport is solved exactly and the diffusive transport by finite volume method. The exact solutions for all sorption isotherms of Freundlich and Langmuir type are presented for the case of piecewise constant initial profile and zero diffusion. Very precise numerical results for transport with small diffusion can be obtained even for larger time steps (e.g., when the Courant-Friedrichs-Lewy (CFL) condition failed).     

Land subsidence and caprock dolines caused by subsurface gypsum dissolution and the effect of subsidence on the fluvial system in the Upper Tigris Basin (between Bismil–Batman, Turkey)

Karstification-based land subsidence was found in the Upper Tigris Basin with dimensions not seen anywhere else in Turkey. The area of land subsidence, where there are secondary and tertiary subsidence developments, reaches 140 km². Subsidence depth ranges between 40 and 70 m. The subsidence was formed as a result of subsurface gypsum dissolution in Lower Miocene formation. Although there are limestones together with gypsum and Eocene limestone below them in the area, a subsidence with such a large area is indicative of karstification in the gypsum. The stratigraphical cross-sections taken from the wells and the water analyses also verify this fact. The Lower Miocene gypsum, which shows confined aquifer features, was completely dissolved by the aggressive waters injected from the top and discharged through by Zellek Fault. This resulted in the development of subsidence and formation of caprock dolines on loosely textured Upper Miocene–Pliocene cover formations. The Tigris River runs through the subsidence area between Batman and Bismil. There are four terrace levels as T1 (40 m), T2 (30 m), T3 (10 m) and T4 (4–5 m) in the Tigris River valley. It was also found that there were some movements of the levels of the terraces in the valley by subsidence. The subsidence developed gradually throughout the Quaternary; however no terrace was formed purely because of subsidence.     

Hydrochemical characterisation of ground and surface water at Dörtyol/Hatay/Turkey

The degradation of ground water quality due to human activities is a widespread environmental problem. Furthermore, coastal aquifers are threatened by sea water intrusion as a result of increasing water exploitation. The investigation area near Dörtyol is located at the Mediterranean coast, southern Turkey, and dominated by agricultural land use. Drinking, domestic and agricultural purposes require different amounts of uncontaminated water. In this study the hydrogeological characteristics of the coastal plain were investigated. Discharge and ground water level measurements as well as geological investigations were undertaken in field in addition to anion and cation analyses of ground and surface water. The results show geological and anthropogenic influence on ground and surface water composition. In spite of a large number of wells in the coastal area sea water intrusion was not detected. With the goal of devising sustainable water use regulations, more emphasis and research needs to be directed to the long-term observation of ground and surface water quality as well as the detailed investigation of hydraulic characteristics of the local aquifer.     

Characterizing site response in the Attock Basin,Pakistan, using microtremor measurement analysis

The Attock Basin is situated close to the northwest of Pakistan. Recent seismic event of October 2015 (7.5M_w) near the Pakistan Afghanistan border has proved that the area of interest is seismically active and triggered a series of aftershocks of magnitude even greater than 6.5M_w. This seismic activity has posed danger to the future of the people and infrastructure especially to the northwestern part of the country. Therefore, site response analysis is essential for estimating local site conditions in response to seismic events. Ambient noise recordings were made at 50 sites within urban and semi-urban settlements in the Attock Basin to analyze the site response of the small but densely populated basin. At each of these sites, the fundamental frequency of the soft sediments (f ₀), the amplitude (A ₀) of corresponding H/V spectral ratios, the thickness of soft sediment (H) lying over competent lithology, and the soil vulnerability index (K _g) were studied. Results were correlated with sparsely available borehole data to enhance the credibility of the study conducted for microzonation and predicting the site response to earthquake seismicity in the Attock Basin. The soil vulnerability index was found to range from moderate to high. Results clearly showed that the study area exhibits low to moderate fundamental frequency with greater soft sediment thicknesses distributed throughout the study area. Moreover, higher impedance contrasts were found at most of the sites within the central part of the Attock Basin, thus reflecting a moderate to high susceptibility of damage in those regions in response to seismic events.     

Embedding eco-friendly and smart technology features in affordable housing for community happiness in Malaysia

GeoJournal - Two phases of study are involved in this research: first, the sales strategies for affordable houses embedded with eco-friendly and smart technology features; and second, the impact of...     

Retention studies of chromium (VI) from aqueous solution on the surface of a novel carbonaceous material

In the present study, the retention capacity of carbonaceous material obtained from the diesel engine exhaust mufflers for Cr(VI) removal has been investigated. The physicochemical properties such as density, pH of aqueous slurry, pH at point of zero charge, ash content, moisture content, volatile matter, surface area, scanning electron microscopy and electron dispersive spectroscopy of the carbonaceous material were determined. The capacity of adsorbent for removal of Cr(VI) from aqueous solution was observed under different experimental condition like contact time, initial concentration of metal ions, pH and temperatures on the adsorption capacity of the adsorbent. Maximum adsorption of Cr(VI) ions was found at low pH. The adsorption process was found to follow second-order kinetics. The rate constant was evaluated at different temperatures along with other thermodynamic parameters like activation energy, Gibbs free energy change, enthalpy change and entropy change. Both Langmuir and Freundlich isotherms were used to describe the adsorption equilibrium of carbonaceous material at different temperatures. Langmuir isotherm shows better fit than Freundlich isotherm at given conditions. The result shows that low-cost carbonaceous material from diesel engine exhaust mufflers can be efficiently used for wastewater treatment containing Cr(VI) ions.     

Retrieval and Validation of Chlorophyll-a Concentrations in the Coastal Waters Off Yanam and Kakinada (Godavari) Basin Along East Coast of India

In this study chlorophyll measurements were made during March 2012 in the estuarine waters of Off Kakinada and Yanam coast, Bay of Bengal onboard a coastal vessel. In-situ water samples and optical data was collected at 21 stations (surface to 150 m depth) using Underwater radiometer (Hyperpro-II). In-vivo chlorophyll profiles were collected using wet labs fluorometer integrated with underwater Hyperspectral radiometer. Chlorophyll-a concentrations were estimated using HPLC by collecting the water samples at each sampling location. And also chlorophyll-a concentrations were retrieved from the OCM-2 data of OCEANSAT-2 satellite, processed using SeaDAS v.6.2 with the available global ocean colour algorithms namely, OC2 and OC4V4. A total of 33 samples used covering all the stations for chlorophyll-a estimation, and surface water samples of all the stations only being used for direct comparison among chlorophyll concentrations of HPLC, in-situ (fluorometrically integrated to Hyperpro-II) and retrieved from OCM-2. A good correlation found between the Fluorometer derived and HPLC measured chlorophyll-a concentration with an R² value of 0.78. The relation between Chlorophyll-a concentration measured from HPLC and retrieved from OCM-2 (OC2 and OC4V4 algorithms) using SeaDASv.6.2 for 10 samples has been compared for validation and obtained an R² value of 0.6. Also comparisons done with the in-situ measured (fluorometer) Chlorophyll-a concentration with OCM-2 chlorophyll data (OC4-V4 and OC2 algorithms) and validation with 10 concurrent in-situ surface measurements showed a significant overestimation by OCM-2 at low chlorophyll-a concentrations and underestimation at high chlorophyll-a concentrations.