Variation in nitrate and calcium as indicators of recharge pathways in Nolte Spring, PA

This study documents variations in calcium and nitrate concentrations that suggest changes in recharge pathways in a karst spring. The nitrate concentrations increased at the end of the growing season, showing the importance of the soil zone in the recharge pathway. The increase occurred over just a few days, which may be indicative of a change in contribution of baseflow in different seasons from deep to shallow groundwater. The calcium concentrations decreased several days after storm events. A change in the carbonate equilibrium is hypothesized because chloride was not diluted during these events. The decrease in calcium could be due to outgassing and calcite precipitation in the recharge area when older, higher ionic strength matrix water mixes with stormwater in open conduits. The use of geochemical indicators to better understand recharge pathways benefited from long-term monitoring and periods of daily sampling.     

Mineralogy of suspended sediment in three karst springs

Springs in karstic carbonate rocks frequently carry a sediment load as well as a dissolved load. Analysis of morphology and mineralogy of suspended sediment from three contrasting karst springs reveals a suite of clastic particles that reflect both source areas and processes that take place within the aquifer. Nolte Spring in Lancaster County, Pennsylvania, USA, discharges sediment of apparently precipitated calcite, indicating that at some point in the aquifer or vadose zone, water exceeds saturation with respect to calcite. Sediment morphologies and chemical conditions in the aquifer point to two different scenarios for this precipitation. The other two springs, Arch Spring in Blair County, Pennsylvania and Bushkill Spring in Northampton County, Pennsylvania, show no evidence of calcite precipitation. Arch Spring discharges mainly layer silicates, while Bushkill Spring discharges mainly silica.

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Resumen Los manantiales en rocas carbonatadas karstficadas tienen frecuentemente una carga de sedimentos y de sólidos disueltos. Los análisis de la morfología y mineralogía de los sedimentos suspendidos de tres manantiales kársticos contrastados revela un conjunto de partículas clásticas que reflejan ambas áreas fuente y los procesos que tienen lugar dentro del acuífero. Nolte Spring en el Condado de Lancaster, Pennsylvania, USA, descarga sedimento de calcita aparentemente precipitada indicando que en cierto punto del acuífero o en la zona vadosa, el agua supera la saturación con respecto a la calcita. La morfología de los sedimentos y las condiciones químicas en el acuífero apuntan a dos escenarios diferentes para esta precipitación. Los otras dos manantiales, Arch Spring en el Condado de Blair, Pennsylvania y Bushkill Spring en el Condado de Norhtampton, Pennsylvania, no muestran evidencia de precitación de calcita. Arch Spring descarga principalmente filosilicatos mientras que Bushkill Spring descarga fundamentalmente Sílice.

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Résumé Les sources situées en contexte carbonaté karstique charrient fréquemment, outre les matières dissoutes, une charge solide. La morphologie et la minéralogie des sédiments en suspension issus de trois sources karstiques de caractéristiques distinctes ont été analysées : une série de particules clastiques, reflétant à la fois les secteurs des sources et les processus internes de l’aquifère, en ressort. Les sédiments issus de Nolte Spring (Comté de Lancaster, Pennsylvanie, Etats-Unis) sont constitués de calcite apparemment précipitée: ceci indique que l’eau atteint la sursaturation vis-à-vis de la calcite à un certain point de l’aquifère ou de la zone non-saturée. La morphologie des sédiments et les conditions chimiques au sein de l’aquifère mènent à deux scénarii différents pour expliquer cette précipitation. Les deux autres sources, Arch Spring (Comté de Blair, Pennsylvanie) et Bushkill Spring (Comté de Northampton, Pennsylvanie), ne présentent aucun indice de précipitation de calcite. Arch Spring exporte essentiellement des phyllosilicates, alors que la silice est majoritaire à Bushkill Spring.

     

Urban stream temperature patterns: Spatial and temporal heterogeneity in the Philadelphia region,Pennsylvania, USA

Stream temperature is a critical water quality parameter that is not fully understood, particularly in urban areas. This study explores drivers contributing to stream temperature variability within an urban system, at 21 sites within the Philadelphia region, Pennsylvania, USA. A comprehensive set of temperature metrics were evaluated, including temperature sensitivity, daily maximum temperatures, time >20°C, and temperature surges during storms. Wastewater treatment plants (WWTPs) were the strongest driver of downstream temperature variability along 32 km in Wissahickon Creek. WWTP effluent temperature controlled local (1–3 km downstream) temperatures year-round, but the impacts varied seasonally: during winter, local warming of 2–7°C was consistently observed, while local cooling up to 1°C occurred during summer. Summer cooling and winter warming were detected up to 12 km downstream of a WWTP. Comparing effects from different WWTPs provided guidelines for mitigating their thermal impact; WWTPs that discharged into larger streams, had cooler effluent, or had lower discharge had less effect on stream temperatures. Comparing thermal regimes in four urban headwater streams, sites with more local riparian canopy had cooler maximum temperatures by up to 1.5°C, had lower temperature sensitivity, and spent less time at high temperatures, although mean temperatures were unaffected. Watershed-scale impervious area was associated with increased surge frequency and magnitude at headwater sites, but most storms did not result in a surge and most surges had a low magnitude. These results suggest that maintaining or restoring riparian canopy in urban settings will have a larger impact on stream temperatures than stormwater management that treats impervious area. Mitigation efforts may be most impactful at urban headwater sites, which are particularly vulnerable to stream temperature disruptions. It is vital that stream temperature impacts are considered when planning stormwater management or stream restoration projects, and the appropriate metrics need to be considered when assessing impacts.     

Structural geology of Kusma-Sirkang section of the Kali Gandaki valley and its bearing on the tectonic framework of Nepal Himalaya

The rocks of the Kali Gandaki valley along the Kusma Sirkang section of Central West Nepal fall into two tectonic units having a marked difference in the grade of metamorphism. The units are demarcated by the NW-SE extending Phalebas Thrust which has been considered equivalent to the Chail Thrust of the Kumaon Himalaya by earlier workers. The Kusma Reverse Fault to the north parallels the Phalebas Thrust, both being related to Late Orogenic movements.The fold pattern shows at least four episodes, and it is believed that two of them existed prior to the main Himalayan orogeny of Tertiary time.     

Collocation of hydrological and biological attenuation of nitrate in an urban stream

The hydrologic and biogeochemical processes that control nutrient export in urban streams are not well understood. Attenuation can occur by tributary dilution, groundwater discharge, and biological processing both in the water column and the hyporheic zone. A wastewater treatment plant on Pennypack Creek, an urban stream near Philadelphia, PA, provided high nitrate concentrations for analysis of downstream attenuation processes. Longitudinal sampling for an 8‐km reach revealed decreases in nitrate concentration of 2 mg l^?1 at high flow and 4.5 mg l^?1 during low flow. During high flow, δ¹⁵N‐NO₃ increased from 9.5 to 10.5‰ and during low flow increased from 10.1 to 11.1‰. Two reaches were sampled at fine spatial intervals (approximately 200 m) to better identify attenuation processes. Mixing analysis indicated that groundwater discharge and biological processing both control nitrate concentration and isotope signatures. However, fine‐scaled sampling did not reveal spatially discrete zones; instead, these processes were occurring simultaneously. While both processes attenuate nitrate, they have opposite isotope signatures, which may have muted changes in δ¹⁵N‐NO₃. At high flow, a decrease in Cl/NO₃ ratios helped distinguish groundwater discharge occurring along both finely sampled reaches. At low flow, biological processing seemed to be occurring more extensively, but the δ¹⁵N‐NO₃ signature was not consistent with either a single process or a sequential combination of groundwater dilution and biological nitrate attenuation. The collocation of processes makes it more difficult to assess biological processing hot spots and predict how urbanization and subsequent stream restoration influence nitrate attenuation. Copyright © 2016 John Wiley & Sons, Ltd.