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Taitiro Fujinaga Tooru Kuwamoto Eiichiro Nakayama Shinji Tanaka 《Journal of Oceanography》1980,36(4):196-200
A precise and accurate technique for the determination of Li and Rb in sea water has been developed by using a double channel flame emission spectrophotometer. The advantage of this technique is that it is possible to correct the background emission by making use of the double channel system of the apparatus and to obtain constant intensity of emission even if there are large scale changes in the salinity of the sample. Sea water samples collected in the open sea and coastal areas of Japan were analyzed by this method. In one of the coastal areas, an extraordinarily high concentration of Li was found. 相似文献
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Yoshihiro Hiramatsu Masataka Ando Tameshige Tsukuda & Tooru Ooida 《Geophysical Journal International》1998,135(3):801-816
Shear-wave splitting from local deep earthquakes is investigated to clarify the volume and the location of two anisotropic bodies in the mantle wedge beneath central Honshu, Japan. We observe a spatial variation in splitting parameters depending on the combination of sources and receivers, nearly N–S fast in the northern region, nearly E–W fast in the southern region and small time delays in the eastern region. Using forward modelling, two models with 30 and 10 per cent anisotropy are tested by means of a global search for the locations of anisotropic bodies with various volumes. The optimum model is obtained for 30 per cent anisotropy, which means a 5 per cent velocity difference between fast and slow polarized waves. The northern anisotropic body has a volume of 1.00° (longitude) × 0.5° (latitude) × 75 km (depth), with the orientation of the symmetry axis being N20°E. The southern anisotropic body has a volume of 1.25° × 1.25° × 100 km with the symmetry axis along N95°E. Our results show that the anisotropic bodies are located in low-velocity and low- Q regions of the mantle. This, together with petrological data and the location of volcanoes in the arc, suggests that the possible cause of the anisotropy is the preferred alignment of cracks filled with melt. 相似文献
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Masayuki Uesugi Ryo Noguchi Tooru Matsumoto Junya Matsuno Takashi Nagano Akira Tsuchiyama Shigenori Harada Kaori Yokoyama Yoshiaki Yodo Noboru Takeda Toru Yada Shogo Yakame Yuzuru Karouji Yukihiro Ishibashi Masanao Abe Tatsuaki Okada Akio Fujimura Mitsuru Ebihara Fumio Kitajima Keisuke Nagao Tomoki Nakamura Hiroshi Naraoka Takaaki Noguchi Ryuji Okazaki Hisayoshi Yurimoto 《Meteoritics & planetary science》2014,49(7):1186-1201
We report the investigation of cutting methods for Hayabusa samples. The purpose of our study is to explore the possibility of applying multiple analyses to a single particle effectively. We investigated the cutting performance of a blade dicing saw, laser, focused ion beam (FIB), and physical breaking by microindenter. Cutting performance was examined by estimating the aspect ratio of the cut slit, i.e., depth over width of the slit. We also investigated the possible contamination and sample damage by cutting. The result of the investigation shows that we can cut the samples from <50 μm to 500 μm using those methods with aspect ratios from 10 to 20, although they would introduce some contamination or damage to the samples. Our investigations also provide an important basis for the analysis of samples obtained by future sample return missions. 相似文献
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The heat capacity and vibrational entropy of a calcium aluminate and three peraluminous calcium aluminosilicate glasses have been determined from 2 to 300 K by heat-pulse relaxation calorimetry. Together with previous adiabatic data for six other glasses in the system CaO-Al2O3-SiO2, these results have been used to determine partial molar heat capacities and entropies for five species namely, SiO2, CaO and three different sorts of Al2O3 in which Al is 4-, 5- and 6-fold coordinated by oxygen. Given the determining role of oxygen coordination on low-temperature heat capacity, the composition independent entropies found for SiO2 and CaO indicate that short-range order around Si and Ca is not sensitive to aluminum speciation up to the highest fraction of 25% observed for VAl by NMR spectroscopy. Because of the higher room-temperature vibrational entropy of IVAl2O3 (72.8 J/mol K) compared to VAl2O3 (48.5 J/mol K), temperature-induced changes from IVAl to VAl give rise to a small negative contribution of the order of 1 J/mol K to the partial molar configurational heat capacity of Al2O3 in melts. Near 0 K, pure SiO2 glass distinguishes itself by the importance of the calorimetric boson peak. On a g atom basis, the maximum of this peak varies with the composition of calcium aluminosilicate glasses by a factor of about 2. It does not show smooth variations, however, either as a function of SiO2 content, at constant CaO/Al2O3 ratio, or as a function of Al2O3 content, at constant SiO2 content. 相似文献
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基于银因其具有良好的广谱抗茵活性和低毒性而在医学方面有着较为广泛的应用,对银离子(硝酸银)和含银不锈钢的抗茵活性进行了初步研究。实验结果表明,在10^6CFu/mL的初始接种浓度下,银离子对枯草杆菌、大肠杆菌和假单胞茵的最小抑茵质量浓度和最小杀菌质量浓度分别为2,6,8mg/L和2,8,10mg/L。大肠杆菌经8mg/L的银离子处理2h后,有99.9%以上的细菌被破坏。含银不锈钢也表现了较强的抗菌性能。在普通的、银合金和银涂层的sus304不锈钢表面附着的单层生物膜浸泡在PBS溶液中3d后,经CFDA-DAPI双染色和荧光显微镜观察计数获得的假单胞菌的平均存活率为98.0%,38.5%和15.1%。 相似文献
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The influence of ferrous and ferric iron on the low-temperature heat capacity and vibrational entropy of silicate glasses has been determined by adiabatic calorimetry. Two pairs of samples based on sodium disilicate and calcium Tschermak molecule compositions have been studied. Along with previous data for another Fe-bearing glass, these results have been used to complement the available set of composition independent partial molar relative entropies of oxides in silicate glasses with S298 − S0 values of 56.7 and 116 J/mol for FeO and Fe2O3, respectively. The calorimetric data indicate that the fraction of fivefold coordinated Al is significant in the CaO-“FeO”-Al2O3-SiO2 system and that association of Ca2+ and Na+ with Fe3+ in tetrahedral coordination for charge compensation does not entail significant changes in coordination for these two cations. At very low temperatures, however, the heat capacity is no longer an additive function of composition because of unexpectedly high positive deviations from Debye laws. These anomalies are stronger for the reduced than the oxidized glasses and considerably larger than for iron-free glasses, but their origin cannot be established from the present measurements. 相似文献
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M. Akaogi H. Takayama H. Kojitani H. Kawaji T. Atake 《Physics and Chemistry of Minerals》2007,34(3):169-183
The low-temperature isobaric heat capacities (C
p) of β- and γ-Mg2SiO4 were measured at the range of 1.8–304.7 K with a thermal relaxation method using the Physical Property Measurement System.
The obtained standard entropies (S°298) of β- and γ-Mg2SiO4 are 86.4 ± 0.4 and 82.7 ± 0.5 J/mol K, respectively. Enthalpies of transitions among α-, β- and γ-Mg2SiO4 were measured by high-temperature drop-solution calorimetry with gas-bubbling technique. The enthalpies of the α−β and β−γ
transitions at 298 K (ΔH°298) in Mg2SiO4 are 27.2 ± 3.6 and 12.9 ± 3.3 kJ/mol, respectively. Calculated α−β and β−γ transition boundaries were generally consistent
with those determined by high-pressure experiments within the errors. Combining the measured ΔH°298 and ΔS°298 with selected data of in situ X-ray diffraction experiments at high pressure, the ΔH°298 and ΔS°298 of the α−β and β−γ transitions were optimized. Calculation using the optimized data tightly constrained the α−β and β−γ transition
boundaries in the P, T space. The slope of α−β transition boundary is 3.1 MPa/K at 13.4 GPa and 1,400 K, and that of β−γ boundary 5.2 MPa/K at 18.7 GPa
and 1,600 K. The post-spinel transition boundary of γ-Mg2SiO4 to MgSiO3 perovskite plus MgO was also calculated, using the optimized data on γ-Mg2SiO4 and available enthalpy and entropy data on MgSiO3 perovskite and MgO. The calculated post-spinel boundary with a Clapeyron slope of −2.6 ± 0.2 MPa/K is located at pressure
consistent with the 660 km discontinuity, considering the error of the thermodynamic data. 相似文献
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M. Akaogi H. Kojitani T. Morita H. Kawaji T. Atake 《Physics and Chemistry of Minerals》2008,35(5):287-297
Low-temperature isobaric heat capacities (C
p
) of MgSiO3 ilmenite and perovskite were measured in the temperature range of 1.9–302.4 K with a thermal relaxation method using the
Physical Properties Measurement System. The measured C
p
of perovskite was higher than that of ilmenite in the whole temperature range studied. From the measured C
p
, standard entropies at 298.15 K of MgSiO3 ilmenite and perovskite were determined to be 53.7 ± 0.4 and 57.9 ± 0.3 J/mol K, respectively. The positive entropy change
(4.2 ± 0.5 J/mol K) of the ilmenite–perovskite transition in MgSiO3 is compatible with structural change across the transition in which coordination of Mg atoms is changed from sixfold to eightfold.
Calculation of the ilmenite–perovskite transition boundary using the measured entropies and published enthalpy data gives
an equilibrium transition boundary at about 20–23 GPa at 1,000–2,000 K with a Clapeyron slope of −2.4 ± 0.4 MPa/K at 1,600 K.
The calculated boundary is almost consistent within the errors with those determined by high-pressure high-temperature in
situ X-ray diffraction experiments. 相似文献
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