Trends and multi‐annual variability of water temperatures in the river Danube,Serbia

The relationship between air (Ta) and water temperature (Tw) is very important because it shows how the temperature of a water body might respond to future changes in surface Ta. Mean monthly Tw records of three gauging stations (Bezdan, Bogojevo i Veliko Gradi?te) were analysed alongside mean monthly discharge (Q) for the same stations. Additionally, Ta series from two meteorological stations (Sombor and Veliko Gradi?te) were correlated with Tw variations over the period 1950–2012. Locally weighted scatter point smoothing (LOWESS) was used to investigate long‐term trends in the raw data, alongside the Mann–Kendall (MK) trend test. Trend significance was established using Yue–Pilon's pre‐whitening approaches to determine trends in climate data. Also, the rescaled adjusted partial sums (RAPS) method was used to detect dates of possible changes in the time series. Statistically significant warming trends were observed for annual and seasonal minimum and maximum Tw at all investigated sites. The strongest warming was observed at Bogojevo gauging station for seasonal maximum Tw, with +0.05 °C per year on average. RAPS established that the trend began in the 1980s. This behaviour is linked to climate patterns in the North and East Atlantic which determine the amount of heat advected onto mainland Europe. Statistically significant correlations were found for all Tw on an annual basis. Overall, the strongest correlations (p < 0.01) between Tw residuals and the North Atlantic Oscillation (NAO) were recorded for the winter period. These findings suggest possible predictability of Tw over seasonal time‐scales. Copyright © 2016 John Wiley & Sons, Ltd.     

Annual and seasonal variability of precipitation in Vojvodina,Serbia

Annual and seasonal variability of precipitation observed at 92 stations in Vojvodina (Serbia) were analyzed during the period 1946–2006. The rainfall series were examined by means of the empirical orthogonal functions (EOF). The first set of singular vectors explains from 68.8 % (in summer) to 81.8 % (in winter) of the total variance. The temporal variability of the time series associated with the main EOF configurations (the principal components, PCs) was examined using the Mann–Kendall test and the spectral analysis. The time series of PC1 revealed decreasing trend in the winter and spring precipitation and increasing trend in the autumn, summer, and annual precipitation. The relationships between the first PC and circulation patterns, such as the North Atlantic Oscillation (NAO), the East Atlantic (EA) pattern, and East Atlantic/West Russia pattern, were also investigated. The PC1, displaying temporal behavior of the first mode, demonstrated evident correspondence with the NAO index in analysis of the annual, winter, and autumn precipitation. Power spectra of the PC1 show statistically significant oscillations of about 3.3 years for the spring precipitation and about 8 and 15 years for the winter precipitation. Comparisons with spectral analysis of authors for some regions in Europe, most of them in the Mediterranean domain, show that similar periodicities are detected.     

Implications of subsurface thermal–hydraulic–mechanical processes associated with glaciation on Shield flow system evolution and performance assessment

A deep geologic repository (DGR) situated on the Canadian Shield will be subject to long-term climate change that will markedly alter surface conditions as a result of glaciation and permafrost penetration. Systematic, two-dimensional and three-dimensional coupled thermal–hydraulic–mechanical finite-element simulations with varying degrees of coupling, including depth-dependent salinity (represented as a change in groundwater density) and temperature-dependent density and viscosity, were undertaken to address the implications of glaciation on groundwater flow system dynamics as it could affect DGR performance. The modelling domain consisted of a 1.6-km deep sub-regional scale (≈100 km²) fractured Shield flow system. Initial and transient thermal, hydraulic and mechanical boundary conditions were developed from two realizations of the University of Toronto Glacial Systems Model of the last Laurentide glaciation. Results indicate that during the glacial loading/unloading cycle, for this particular conceptual model, there is limited penetration of glacial meltwaters to depth and small residual anomalous hydraulic head. During glacial coverage, the mechanical factor of safety increases in the moderately fractured and sparsely fractured rock mass, but principal effective stress reorientation also occurs. Given the assumed nonglacial in situ state of stress and mechanical properties, the fracture zones were predicted to be less stable under glacial conditions.

Carboniferous foraminifers from the lower part of Paleo-Tethyan seamount-type carbonates in the Changning-Menglian Belt, western Yunnan, Southwest China

The Changning-Menglian Belt in West Yunnan, Southwest China is well-known as a closed remnant of the Paleo-Tethys Ocean in East Asia (Wu et al., 1995; Liu et al., 1996). It is delineated to the east with the Lincang Massif by the Changning-Shuangjiang Fault and to the west with the Baoshan Block by the Kejie-Nandinghe Fault, and is generally subdivided into three zones: east, central, and west zones. In the central zone, various kinds of oceanic rocks such as harzburgite, cumulate websterite, gabbro, both mid-oceanic ridge basalt and oceanic island basalt, Devonian-Triassic radiolarian chert, and Carbonifer-ous-Permian massive and huge carbonates with basaltic effusives as their pedestal are exposed (Liu et al., 1991, 1996; Wu et al., 1995; Ueno et al., 2003). These Central zone rocks are now interpreted to have been emplaced as nappes structurally overlying the East and West zones, which are considered as consisting mainly of passive margin sediments of the Baoshan Block (Wu, 1991; Ueno et al., 2003).     

Effect of rising atmospheric CO2 on sediment and water 15N interactions in experimental riparian wetland

The experiment was conducted to ascertain net production and consumption rates of ¹⁵NH₄ ⁺ and ¹⁵NO₃ ^? for water and sediment in a wetland. This was done using ¹⁵N isotope pool dilution methodology under ambient and elevated atmospheric CO₂ concentrations in experimental riparian wetlands to obtain the gross N transformation rates. The ¹⁵N budget for sediment was also estimated. The results suggested that the differences in high proportion of ¹⁵N concentration in the overlying water body under elevated CO₂ could be attributed to the low production and high consumption rates of ¹⁵NH₄ ⁺ in sediment. The elevated CO₂ effect on production and consumption of NH₄ ⁺ decreased by 144 % (P = 0.014) and increased by 153 % (P = 0.009), respectively. Thereby, ¹⁵NH₄ ⁺ production rates are negatively related with ¹⁵NO₃ ^? consumption rates and this accounted for the decreases in net ¹⁵NO₃ ^? consumption under CO₂ enrichment in the wetland sediment by 11 % (P = 0.528). Therefore, ¹⁵NO₃ ^? production and consumption rates may strongly depend on NH₄ ⁺ production. Inorganic ¹⁵N and total ¹⁵N exported from sediment to overlying water body by the effect of CO₂ were 41 % (P = 0.071) and 18 % (P = 0.000), respectively. Therefore, low net ¹⁵NH₄ ⁺ production and high ¹⁵NH₄ ⁺ consumption rates under elevated CO₂ may partly explain the significant reduction of N from the sediment.     

Using GIS-based distributed soil loss modeling and morphometric analysis to prioritize watershed for soil conservation in Bago river basin of Lower Myanmar

Bago River is an important river in Myanmar. Although shorter than other rivers, it has its own river system, and people along the river rely heavily on it for their daily lives. The upper part of the watershed has changed rapidly from closed forest to open forest land in the 1990s. Since the recent degradation of the forest environment, annual flooding has become worse during the rainy season in Bago City. This paper aims at determining soil conservation prioritization of watershed based on soil loss due to erosion and morphometric analysis in the Bago Watershed by integrating remote sensing and geographic information system (GIS) techniques. In this study, soil erosion of the Bago watershed was determined using the Universal Soil Loss Equation. Such factormaps as rainfall, soil erodibility, slope length gradient, and crop management were compiled as input parameters for the modeling; and the soil loss from 26 sub-watersheds were estimated. Then, the soil erosion maps of the Bago watershed for 2005 were developed. The resulting Soil Loss Tolerance Map could be utilized in developing watershed management planning, forestry management planning, etc.     

Use of comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry for the characterization of biodegradation and unresolved complex mixtures in petroleum

A comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry (GC × GC/TOFMS) method has been developed for separation of a series of petroleum samples using a polar/non-polar column set configuration. Groups of oils were selected to provide samples from the same oil family to assist in comparison of compositional changes during biodegradation. The groups also represented different sources and ages to allow an assessment of the application of GC × GC for the differentiation of oil source, as well as fluid history. The increased resolution and separation afforded by the GC × GC technique provides more complete compositional information on complex biodegraded oil samples than one-dimensional GC, and improves the ability to study biodegradation trends. Among the components identified, it is proposed that alkyl-decahydronaphthalenes constitute a significant contribution to the UCM.     

Multiple Uplift and Exhumation of the Southeastern Tibetan Plateau: Evidence from Low-Temperature Thermochronology

Since the Cenozoic, the Tibetan Plateau has experienced large-scale uplift and outgrowth due to the India–Asia collision. However, the mechanism and timing of these tectonic processes still remain debated. Here, using apatite fission track dating and inverse thermal modeling, we explore the mechanism of different phases of rapid cooling for different batholiths and intrusions in the southeastern Tibetan Plateau. In contrast to previous views, we find that the coeval granitic batholith exposed in the same tectonic zone experienced differential fast uplift in different sites, indicating that the present Tibetan Plateau was the result of differential uplift rather than the entire lithosphere uplift related to lithospheric collapse during Cenozoic times. In addition, we also suggest that the 5–2 Ma mantle-related magmatism should be regarded as the critical trigger for the widely coeval cooling event in the southeastern Tibetan Plateau, because it led to the increase in atmospheric CO2 level and a hotter upper crust than before, which are efficient for suddenly fast rock weathering and erosion. Finally, we propose that the current landform of the southeastern Tibetan Plateau was the combined influences of tectonic and climate.     

Rock relationships in the Mogok metamorphic belt, Tatkon to Mandalay, central Myanmar

The Mogok metamorphic belt (MMB), over 1450 km long and up to 40 km wide, consists of regionally metamorphosed rocks including kyanite and sillimanite schists and granites lying along the Western margin of the Shan Plateau in central Myanmar and continuing northwards to the eastern Himalayan syntaxis. Exposures in quarries allow correlation of Palaeozoic meta-sedimentary, early Mesozoic meta-igneous and late Mesozoic intrusive rocks within a 230 km long northerly-trending segment of the MMB, from Tatkon to Kyanigan north of Mandalay, and with the Mogok gemstone district 100 km to the northeast. Relationships among the metamorphic and intrusive rocks, with sparse published radiometric age controls, indicate at least two metamorphic events, one before and one after the intrusion of Late Jurassic to early Cretaceous calc-alkaline rocks. These relationships can be explained by either of two possible tectonic histories. One, constrained by correlation of mid-Permian limestones across Myanmar, requires early Permian and early Jurassic regional metamorphic events, prior to an early Tertiary metamorphism, in the western part of but within a Shan-Thai – western Myanmar block. The second, not compatible with a single laterally continuous Permian limestone, requires pre-Upper Jurassic regional metamorphism and orogenic gold mineralization in the Mergui Group and western Myanmar, early Cretaceous collision of an east-facing Mergui-western Myanmar island arc with the Shan Plateau, and early Tertiary metamorphism in the MMB related to reversal in tectonic polarity following the arc-Plateau collision.