Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.     

Unraveling complex hydrogeological processes in Andean basins in south‐central Chile: An integrated assessment to understand hydrological dissimilarity

Groundwater storage, drainage, and interbasin water exchange are common hydrological processes but often difficult to quantify due to a lack of local observations. We present a study of three volcanic mountainous watersheds located in south‐central Chile (~36.9 ° S) in the Chillán volcanic complex (Chillán, Renegado, and Diguillín river basins). These are neighboring basins that are similar with respect to the metrics normally available for characterization everywhere (e.g., precipitation, temperature, and land cover). In a hydrological sense, similar (proportional) behavior would be expected if these catchments would be characterized with this general information. However, these watersheds show dissimilar behavior when analyzed in detail. The surface water balance does not fit for any of these watersheds individually; however, the water balance of the whole system can be explained by likely interbasin water exchanges. The Renegado river basin has an average annual runoff per unit of area on the order of 60–65% less than those of the Diguillín and Chillán rivers, which is contradictory to the hydrological similarity among the basins. To understand the main processes that control streamflow generation, two analyses were performed: (a) basin metrics (land cover, geologic, topographic, and climatological maps) and hydro‐meteorological data analyses and (b) a water balance model approach. The analyses contribute to a plausible explanation for the hydrogeological processes in the system. The soils, topography, and geology of the Chillán–Renegado–Diguillín system favor the infiltration and groundwater movements from the Renegado river basin, mainly to the neighboring Diguillín basin. The interbasin water exchanges affect hydrological similarity and explain the differences observed in the hydrological processes of these three apparently similar volcanic basins. The results highlight the complexity of hydrological processes in volcanic mountainous systems and suggest that a simple watershed classification approach based on widely available data is insufficient. Simple local analyses such as specific flow analysis with a review of the geology and morphology can contribute to a better understanding of the hydrology of volcanic mountainous areas.     

The respective roles of surface temperature driven feedbacks and tropospheric adjustment to CO2 in CMIP5 transient climate simulations

An overview of radiative climate feedbacks and ocean heat uptake efficiency diagnosed from idealized transient climate change experiments of 14 CMIP5 models is presented. Feedbacks explain about two times more variance in transient climate response across the models than ocean heat uptake efficiency. Cloud feedbacks can clearly be identified as the main source of inter-model spread. Models with strong longwave feedbacks in the tropics feature substantial increases in cloud ice around the tropopause suggestive of changes in cloud-top heights. The lifting of the tropical tropopause goes together with a general weakening of the tropical circulation. Distinctive inter-model differences in cloud shortwave feedbacks occur in the subtropics including the equatorward flanks of the storm-tracks. Related cloud fraction changes are not confined to low clouds but comprise middle level clouds as well. A reduction in relative humidity through the lower and mid troposphere can be identified as being the main associated large-scale feature. Experiments with prescribed sea surface temperatures are analyzed in order to investigate whether the diagnosed feedbacks from the transient climate simulations contain a tropospheric adjustment component that is not conveyed through the surface temperature response. The strengths of the climate feedbacks computed from atmosphere-only experiments with prescribed increases in sea surface temperatures, but fixed CO₂ concentrations, are close to the ones derived from the transient experiment. Only the cloud shortwave feedback exhibits discernible differences which, however, can not unequivocally be attributed to tropospheric adjustment to CO₂. Although for some models a tropospheric adjustment component is present in the global mean shortwave cloud feedback, an analysis of spatial patterns does not lend support to the view that cloud feedbacks are dominated by their tropospheric adjustment part. Nevertheless, there is positive correlation between the strength of tropospheric adjustment processes and cloud feedbacks across different climate models.     

Impacts of experimental dredged material disposal on a shallow, sublittoral macrofauna community in Mecklenburg Bay (western Baltic Sea)

An experimental disposal of dredged material was performed in June 2001 at two adjacent sites in Mecklenburg Bay (western Baltic Sea) to investigate the impacts on a sublittoral fauna community (macrozoobenthos). Temporal changes in community parameters were analysed: Total abundance and multidimensional scaling (MDS) ordination results showed that dredged material disposal causes significant changes in benthic assemblages in comparison to the original situation before the disposal activities. The bivalves Arctica islandica and Macoma balthica were almost not affected by the disposal. Abundances of the polychaete N. hombergii as well as the epibenthic cumacean D. rathkei decreased by a factor of 1.4-3.9 whereas most other invertebrates suffered even more. Two years after the experimental disposal a high level of benthic recovery was found, but also a change in dominance structure. These changes are rather due to inter-annual variability in regional benthic recruitment processes in the Mecklenburg Bay than due to the disposal.     

Late Miocene to Early Pliocene blueschist from Taiwan and its exhumation via forearc extraction

Blueschist facies rocks in the Yuli Belt of Taiwan's Central Range record ongoing subduction of the Eurasian plate. We present a prograde Lu–Hf garnet–whole‐rock age of 5.1 ± 1.7 Ma from a retrogressed blueschist in the Yuli Belt. This age is considerably younger than the previously assumed age of 14–8 Ma for high‐pressure metamorphism in the Yuli Belt and represents the youngest Lu–Hf garnet age ever recorded for blueschist facies metamorphism. The age sheds new light on the palaeogeographic origin and exhumation scenario of the Yuli Belt. We propose that the Yuli Belt originated from the ocean–continent boundary of the Chinese passive margin. It was subducted eastward during collision with the Luzon island arc and rapidly exhumed when the forearc lithosphere was removed from above the continental slab by discrete subduction (extraction). This process reduces the pressure above the continental slab and may prompt the ascent of subducted crust into the opening gap. Thus, it can control the exhumation of high‐pressure rocks.     

Characterization of dissolved organic matter across the Subtropical Convergence off the South Island,New Zealand

Dissolved organic matter (DOM) was investigated along a gradient across the Subtropical Convergence (STC) off the South Island, New Zealand. Ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS), excitation emission matrix fluorescence (EEM) spectroscopy, and molecular lignin analysis techniques were used to study this DOM. The analysis revealed a group of compounds found only in the coastal DOM samples, which were also characterized by an elevated terrestrial DOM fluorescence pattern and elevated lignin content if compared to the offshore samples. This group exhibited a high degree of carbon unsaturation, as evident from high double bond equivalence minus oxygen values (DBE-O > 9) and maximum fluorescence intensity. Sulfur-containing molecular formulae for summer DOM samples were much more abundant across the entire transect of the STC compared to winter and exhibited distinctly different hydrogen:carbon and oxygen:carbon elemental ratios, suggesting a possible correlation between biological activity and sulfur compounds. The molecular formulae common to all STC samples were compared with those calculated for DOM extracted from freshwater collected from a stream discharging into Doubtful Sound (West Coast, New Zealand). ESI-FT-ICR-MS measurements undertaken in negative electrospray ionization (ESI?) mode indicated that 30% of the molecular formulae were present in both types of DOM, while in positive ESI mode (ESI+) over 90% of the formulae were present in all samples. Hence, a significant portion of the molecular formulae assigned to the solid-phase extractable DOM pool (SPE-DOM) appear to be identical in oceanic and freshwater samples.     

Comparison of lightning activity and radar-retrieved microphysical properties in EULINOX storms

A combined analysis of microphysical thunderstorm properties derived by C-band polarimetric Doppler radar measurements and lightning observations from two ground-based systems are presented. Three types of storms, a multicell, a supercell, and a squall line, that were observed during the European Lightning Nitrogen Oxides project (EULINOX) are investigated. Correlations are sought between the mass of rain, graupel, hail, and snow derived form radar observations at different height levels and the electrical activity, represented either by cloud-to-ground or intracloud flashes. These relationships are explained by connecting the radar-derived properties with the non-inductive charging process. For the multicell and the supercell storm, the lightning activity can be linearly correlated to both the hydrometeor total mass and class specific mass in the upper part of the storm. It is shown that the fractions of graupel and hail above the −20 °C-level in these storms positively correlate with the intracloud flash activity in the supercell, and negatively for the cloud-to-ground lightning frequency in the multicell. No such relation can be established for the squall line, indicating that the convective organization plays a crucial role in the lightning development. The analysis of the masses in the different storms shows that lightning activity cannot be parameterized by total mass alone, other parameters have to be identified. The results provide important information for all lightning studies that rely on bulk properties of thunderstorms, e.g., the parameterization of lightning in mesoscale models or the nowcasting of lightning by radar.     

Catchment precipitation processes in the San Francisco valley in southern Ecuador: combined approach using high-resolution radar images and in situ observations

The precise estimation of precipitation quantities in tropical mountain regions is in great demand by ecological and hydrological studies, due to the heterogeneity of the rainfall distribution and the lack of meteorological station data. This study uses radar images and ground station data to provide the required high-resolution precipitation maps. Also wind data are taken into account, due to its influence on the precipitation formation and to demonstrate the relation between synoptic wind, topography and the precipitation distribution inside small mountain valleys. The study analyses the rainfall distribution and amounts of 4 days inside the San Francisco Valley, a small catchment in the tropical Andes of southern Ecuador, representing different seasons and the typical atmospheric flows, which are correlated to the annual precipitation map. The results show that the rainfall distribution and amounts are generally defined by the wind direction and velocity, besides the topographic location in relation to the main barriers and pathways. The dominant wind direction causes a division of the catchment in a wetter eastern and a dryer western part. Moreover, the annual seasons are reversed; the main rainy season for the eastern part occurs between June and August, while the western part reaches the precipitation maximum between January and March. This may have influence on the species composition at the different slopes and the annual hydrological cycle inside the catchment.     

Cultivable bacteria from bulk water,aggregates, and surface sediments of a tidal flat ecosystem

Most-probable-number (MPN) dilution series were used to enumerate and isolate bacteria from bulk water, suspended aggregates, the oxic layer, and the oxic–anoxic transition zone of the sediment of a tidal flat ecosystem in the southern North Sea. The heterotrophic aerobic bacteria were able to grow on agar-agar, alginate, cellulose, chitin, dried and ground Fucus vesiculosus, Marine Broth 2216, palmitate, and starch. MPN counts of bulk water and aggregate samples ranged between 0.18?×?10¹ and 1.1?×?10⁶ cells per milliliter and those of the sediment surface and the transition zone between 0.8?×?10¹ and 5.1?×?10⁷ cells per gram dry weight. Marine Broth and F. vesiculosus yielded the highest values of all substrates tested and corresponded to 2.3–32% of 4,6-diamidinophenyl indole cell counts. Strains of seven phylogenetic classes were obtained: Actinobacteria, Bacilli, α- and γ-Proteobacteria, Sphingobacteria, Flavobacteria, and Planctomycetacia. Only with agar-agar as substrate could organisms of all seven classes be isolated.