Anthropogenic influence on trace element geochemistry of healing mud (peloid) from Makirina Cove (Croatia)

Due to their balneotherapeutic features, the organic-rich sediments in Makirina Cove are an important source of healing mud. An environmental geochemistry approach using normalization techniques was applied to evaluate the anthropogenic contribution of trace metals to sediments used as healing mud. Sediment geochemistry was found to be associated with land-use change and storm events, as well as with proximity of a road with heavy traffic in the summer months. Local valley topography preferentially channels lithogenic and pollutant transport to the cove. Concentrations and distribution of trace metals indicate lithogenic (Ni, Cr, Co) and anthropogenic (Pb, Cu, Zn and Se) contributions to the sediments. The calculation of enrichment factors indicates a moderate (EFs between 2–3.5) input of anthropogenic Cu and Pb in surficial sediments to a depth of 10 cm. Patients using the Makirina Cove sediments as healing mud could be to some extent exposed to enhanced uptake of metals from anthropogenic sources via dermal contact.     

Absolute spectrophotomery of comets 1973XII and 1975IX: II. Profiles of the Swan bands

Absolute spectrophotometric measurements of the Swan bands of two comets have been compared with computed synthetic spectra using modern Franck-Condon and Hönl-London factors, and varying rotational, vibrational, and electronic excitation temperatures. Rotational and vibrational temperatures were obtained for the comets. Although the electronic excitation temperature and the molecular column density cannot be separated, a relationship is found between these two quantities. A review is made of recent determinations of column densities for CN in comets.     

3rd Regional Symposium on Landslides in the Adriatic-Balkan Region (3rd ReSyLAB)—a final report

The 3rd Regional Symposium on Landslides in the Adriatic-Balkan Region (3rd ReSyLAB) was held in Ljubljana, Slovenia, from June 11 to 13, 2017, with 70 participants from nine countries (Austria, Bosnia and Hercegovina, Croatia, Czech Republic, Italy, Republic of Macedonia, Serbia, Slovenia, Spain)—scientists, engineers, researchers, students, experts, politicians, and other decision-makers working in the area of landslide risk reduction in the region. The ReSyLAB is a biannual event organized by the Adriatic-Balkan Network of the International Consortium on Landslides (ICL ABN). Being an important form of activities of this ICL regional network comprising of six ICL members from four countries, it was also a contribution of the International Consortium on Landslides (ICL) to the implementation of the Sendai Framework for Disaster Risk Reduction 2015–2030. This article reports on the main outcomes of the 3rd ReSyLAB Symposium. Altogether, 41 abstracts were published in the symposium book of abstracts, and the symposium proceedings with over 20 reviewed full papers are under preparation to be printed early in 2018. During the 3rd ReSyLAB, a five invited keynote lectures have been presented, and 28 oral presentations are given to the audience. An important part of the symposium was a Round Table entitled “Enhancing cooperation between landslide research community and end users.” On the last day of the symposium, over 30 experts participated in two post-symposium study tours in Slovenia.     

Geochemical background in soils: a linear process domain? An example from Istria (Croatia)

Definition of geochemical background in exploration and environmental geochemistry has always been regarded as contingent upon scale and investigated locality but mostly under assumption that hosts of processes that produce the data more or less conform individually to Gaussian law of “central tendencies”. Recently, understanding of pedogenesis as synergetic process being characterized by non-linear dynamics renders thermodynamic approach directly applicable in assessment of geochemical thresholds, with concepts of linearity and normality set alongside in solving the problems of soil geochemistry. Seen from this perspective the work is an attempt to relate conceptual fundamentals of non-linear dynamical theory to basic statistical methods in order to elucidate the nature and origins of element subpopulations hidden in the original geochemical data from the soils of Istrian Peninsula (western Croatia). To this purpose the two major groups of soils were selected for analysis depending on the type of bedrock as one of the main soil-forming factors. Geochemical data were subjected to the trimming procedure by which the outliers were removed from the total data collective and attributed to non-linear causes precluding simple cause-and-effect relationships as the sine qua non of Gaussian distribution. Geochemical background is then defined as the normal range of data of the remaining (trimmed) dataset indicating the “thermodynamic branch” of the specific soil processes as opposed to outliers being described as dissipative structures.     

The Convergence of Newton–Raphson Iteration with Kepler's Equation

Conway (Celest. Mech. 39, 199–211, 1986) drew attention to the circumstance that when the Newton–Raphson algorithm is applied to Kepler's equation for very high eccentricities there are certain apparently capricious and random values of the eccentricity and mean anomaly for which convergence seems not to be easily reached when the starting guess for the eccentric anomaly is taken to be equal to the mean anomaly. We examine this chaotic behavior and show that rapid convergence is always reached if the first guess for the eccentric anomaly is π. We present graphs and an empirical formula for obtaining an even better first guess. We also examine an unstable situation where iterations oscillate between two in correct results until the instability results in sudden convergence to the unique correct solution. This revised version was published online in July 2006 with corrections to the Cover Date.     

The cyanogen bands of Comet Bennett 1970 II

The CN band spectrum of Comet Bennett 1970 II was photographed on April 14, 1970. In addition to the (0,0) band, some other faint lines were observed, which arise either from the (1,1) band of the normal isotopic species or from the (0,0) band of ¹³CN. The Swings effect was investigated theoretically and found to give good agreement with observation. An estimate is made of the pure rotational transition rate in the ground state of CN.Absolute intensities of the CN lines were found by comparison with the lunar spectrum. From these measurements the distribution, density and total mass of cyanogen in the gaseous coma of the comet are estimated.     

Mechanisms of landslides in over-consolidated clays and flysch

In this report, we present the situation in Slovenia, Europe with regard to natural hazards, emphasizing land-sliding problems. Furthermore, we shortly present the University of Ljubljana and the Faculty of Civil and Geodetic Engineering as the new member of the ICL that was selected to be the World Center of Excellence on Landslide Risk Reduction for the period of 2008–2013 with the project entitled “Mechanisms of landslides in over-consolidated clays and flysch” in the Activity scale and targeted region as “National.” Some preliminary results of this project are shortly presented at the end.     

Composition and origin of organic matter in surface sediments of Lake Sarbsko: A highly eutrophic and shallow coastal lake (northern Poland)

We present an organic geochemical study of surface sediments of Lake Sarbsko, a shallow coastal lake on the middle Polish Baltic coast. The aim was to provide evidence concerning the origin of the organic matter (OM) and its compositional diversity in surface deposits of this very productive, highly dynamic water body. The content and composition of the OM in the bottom sediments were investigated at 11 sampling stations throughout the lake basin. OM sources were assigned on the basis of bulk indicators [total organic carbon (TOC), total nitrogen (TN), δ¹³C_TOC and δ¹⁵N and extractable OM yield], biomarker composition of extractable OM and compound-specific C isotope signatures. The source characterization of autochthonous compounds was verified via phytoplankton analysis. The distribution of gaseous hydrocarbons in the sediments, as well as temporal changes in lake water pH, the concentration of DIC (dissolved inorganic carbon) and δ¹³C_DIC were used to trace OM decomposition.The sedimentary OM is composed mainly of well preserved phytoplankton compounds and shows minor spatial variability in composition. However, the presence of CH₄ and CO₂ in the bottom deposits provides evidence for microbial degradation of sedimentary OM. The transformation of organic compounds in surface, bottom and pore waters via oxidative processes influences carbonate equilibrium in the lake and seasonally favours precipitation or dissolution of CaCO₃.The data enhance our understanding of the relationships between the composition of sedimentary OM and environmental conditions within coastal ecosystems and shed light on the reliability of OM proxies for environmental reconstruction of coastal lakes.     

An observational study of a spotted W UMa-type binary star CK Bootis

New photoelectric observations of CK Bootis (a binary star suspected of a spot activity) obtained in 1988 at Mt. Suhora Observatory are presented. On the basis of the spectroscopic observations made in May 1990 at the Toru University Observatory the spectral class F6V of the primary component was estimated. The physical parameters of the system with a circular spot were derived making use of the Wilson-Devinney code.