Characterization and cycling of atmospheric mercury along the central US Gulf Coast

Concentrations of atmospheric Hg species, elemental Hg (Hg^°), reactive gaseous Hg (RGM), and fine particulate Hg (Hg-PM_2.5) were measured at a coastal site near Weeks Bay, Alabama from April to August, 2005 and January to May, 2006. Mean concentrations of the species were 1.6 ± 0.3 ng m⁻³, 4.0 ± 7.5 pg m⁻³ and 2.7 ± 3.4 pg m⁻³, respectively. A strong diel pattern was observed for RGM (midday maximum concentrations were up to 92.7 pg m⁻³), but not for Hg^° or Hg-PM_2.5. Elevated RGM concentrations (>25 pg m⁻³) in April and May of 2005 correlated with elevated average daytime O₃ concentrations (>55 ppbv) and high light intensity (>500 W m⁻²). These conditions generally corresponded with mixed continental-Gulf and exclusively continental air mass trajectories. Generally lower, but still elevated, RGM peaks observed in August, 2005 and January–March, 2006 correlated significantly (p < 0.05) with peaks in SO₂ concentration and corresponded to periods of high light intensity and lower average daytime O₃ concentrations. During these times air masses were dominated by trajectories that originated over the continent. Elevated RGM concentrations likely resulted from photochemical oxidation of Hg^° by atmospheric oxidants. This process may have been enhanced in and by the near-shore environment relative to inland sites. The marine boundary layer itself was not found to be a significant source of RGM.     

The impact of wave loads and pore-water pressure generation on initiation of sediment transport

The build-up of pore-water pressure by waves can lead to sediment liquefaction and subsequent transport by traction currents. This process was investigated by measuring pore-water pressures both in a field experiment and laboratory wave tank tests. Liquefaction was observed in the wave tank tests. The results suggest that sand is less susceptible than silts to wave-induced liquefaction because of the tendency to partially dissipate pore-water pressures. However, previous studies have determined that pore-water pressures must approach liquefaction before current velocities necessary to initiate transport are reduced. Once liquefaction has occurred more sediment can be transported.     

Mobile Learning in a Human Geography Field Course

This article reports on reusable mobile digital learning resources designed to assist human geography undergraduate students in exploring the geographies of life in Dublin. Developing active learning that goes beyond data collection to encourage observation and thinking in the field is important. Achieving this in the context of large class sizes presents several challenges. Combining in situ learning with spatially accurate historical and contemporary multimedia, a set of location-aware digital mobile tools, or mediascapes, was developed. How scaffolding can be achieved in such a context, focusing on the development of students’ observational, enquiry, and thinking skills in the field was explored.     

Internal tides and sediment movement on Horizon Guyot,Mid-Pacific Mountains

Internal tidal currents are the likely cause of erosional features such as current ripples, sand waves, and truncated bedding horizons on the sediment cap of Horizon Guyot. Current meter data obtained over a 9 month period in 1983–1984 at about 213 m above the guyot show that the tidal currents are anomalously strong for mid-oceanic depths, probably the result of topographically induced generation of internal tidal waves. An analysis of the initiation of motion of the foraminiferal sand by the internal tidal currents indicates that these currents, particularly during the months of March–May, are likely to transport the surficial sediment and generate the observed bedforms.     

Erosion and slope instability on Horizon Guyot,Mid-Pacific Mountains

Seismic-reflection profiles, sediment cores, and current velocities were assessed to study the impact of erosion and sediment redistribution on the pelagic sediment cap of Horizon Guyot, a flat-topped submarine volcanic ridge in the Mid-Pacific Mountains. These processes seem to concentrate their effect around the rim of the sediment cap. Sediment slumping occurs on the northwest perimeter of the guyot's sediment cap. Slope stability analysis suggests that if overconsolidation on Horizon Guyot is the result of current reworking or if local undercutting by bottom currents steepens the sea floor declivity, the sediment cap may be unstable during infrequent earthquake loading, transporting sediment from the guyot summit to the abyssal sea floor.     

A place-based model for understanding community resilience to natural disasters

There is considerable research interest on the meaning and measurement of resilience from a variety of research perspectives including those from the hazards/disasters and global change communities. The identification of standards and metrics for measuring disaster resilience is one of the challenges faced by local, state, and federal agencies, especially in the United States. This paper provides a new framework, the disaster resilience of place (DROP) model, designed to improve comparative assessments of disaster resilience at the local or community level. A candidate set of variables for implementing the model are also presented as a first step towards its implementation.     

Textural evidence for quartz and feldspar dissolution as a mechanism of formation for Maggs Pipe,Zaaiplaats tin mine,South Africa

Shallowly plunging and branching pipe systems in Lease and Bobbejaankop Granite at the Zaaiplaats mine are host to major tin mineralization. Detailed textural study of Maggs Pipe indicates that dissolution of the granite was a major process in the formation of open space which provided permeability for the passage of hydrothermal fluids, and sites for the precipitation of ore and gangue minerals. The pipe formation process initiates with the dissolution of granite quartz and subsequently extends to feldspar dissolution, particularly in the central portion of Maggs Pipe. Spaces created by mineral dissolution are filled by hydrothermal phases and the relict feldspar matrix becomes progressively more altered toward the centre of the pipe. The distribution of alteration and infill minerals defines a zoning pattern which, from the outer margin to the central core, includes calcite-quartz, chlorite (± cassiterite, albite, fluorite) and synchisite-calcite zones. It is postulated that quartz and feldspar dissolution resulted from interaction between the granite and hydrothermal fluids containing alkali-chloride, -fluoride or -carbonate complexes which had separated from the granite magma during crystallization. Preliminary observations on several other pipes at Zaaiplaats indicate that quartz and feldspar dissolution was a major procress in forming the pipe systems.     

Stream response to repeated coseismic folding, Tiptonville dome, New Madrid seismic zone

Fluvial response to tectonic deformation is dependent on the amount and style of surface deformation and the relative size of the stream. Active folding in the New Madrid seismic zone (NMSZ) forms the Tiptonville dome, a 15-km long and 5-km wide surface fold with up to 11 m of late Holocene structural relief. The fold is crossed by streams of varying size, from the Mississippi River to small flood-plain streams. Fluvial response of these streams to repeated coseismic folding has only been preserved for the past 2.3 ka, since the Tiptonville meander of the Mississippi River migrated across the area forming the present flood plain. This surface comprises a sandy point-bar deposit locally overlain by clayey overbank and silty sand crevasse-splay deposits, an abandoned chute channel infilled with laminated sandy silt and silty clay, and an abandoned neck cutoff filled with a sandy cutoff bar and silty clay oxbow lake deposits.Dating various stream responses to coseismic folding has more tightly constrained the timing of earthquake events in the central NMSZ and provides a means of partitioning the deformation amount into individual seismic events. Three earthquakes have been dated in the Reelfoot Lake area, ca. A.D. 900, 1470, and 1812. The latter two earthquakes had large local coseismic deformation. Both of these events were responsible for numerous stream responses such as shifting depocenters, modification of Mississippi River channel geometry, and derangement of small streams. Overbank sedimentation ceased on the dome as it was uplifted above the normal flood stage, and sedimentation of crevasse-splay deposits from the Mississippi River, colluvium from the scarp, and lacustrine sediment accumulated in the adjacent Reelfoot basin. The much larger Mississippi River channel responded to uplift by increasing its sinuosity across the uplift relative to both upstream and downstream, increasing its width/depth ratio across and downstream of the uplift, and decreasing the width/depth ratio upstream of the uplift. Despite the size of the Mississippi River, it has not yet attained equilibrium since the latest uplift 190 years ago. Small channels that could not downcut through the uplift were filled, locally reversed flow direction, or formed a lake where they were dammed.Uplift and stream response to folding along the Tiptonville dome is less dramatic between 2.3 and 0.53 ka. During this interval, abandoned channel fill and overbank deposition across the dome suggests that it was not a high-relief feature. One earthquake event occurred during this interval (ca. A.D. 900), but coseismic stream response was probably limited to a slight aggradation of a small flood-plain stream.