Argon and nitrogen isotopes of trapped air in the GISP2 ice core during the Holocene epoch (0-11,500 B.P.): Methodology and implications for gas loss processes

Argon and nitrogen isotopes of air in polar ice cores provide constraints on past temperature and firn thickness, with relevance to past climate. We developed a method to simultaneously measure nitrogen and argon isotopes in trapped air from the same sample of polar ice. This method reduces the time required for analysis, allowing large numbers of measurements. We applied this method to the entire Holocene sequence of the GISP2 ice core (82.37-1692.22 m) with a 10-20 year sampling interval (670 depths). δ⁴⁰Ar and δ¹⁵N show elevated values in the oldest part of the dataset, consistent with a thicker firn layer and increased temperature gradient in the firn due to the legacy of the abrupt warming at the end of the Younger Dryas interval and the gradual warming during the Preboreal interval (11.5-10.0 ka). The Preboreal Oscillation and the 8.2k event are clearly recorded. The data show remarkable stability after the 8.2k event.Available data suggests that post-coring gas loss involves two distinct types of fractionation. First, smaller molecules with less than a certain threshold size leak through the ice lattice with little isotopic fractionation. Second, gas composition changes via gas loss through microcracks, which induces isotopic fractionation. These two gas loss processes can explain most trends in our data and in other ice core records.     

Mixed layer depth climatology of the North Pacific based on Argo observations

A monthly mean climatology of the mixed layer depth (MLD) in the North Pacific has been produced by using Argo observations. The optimum method and parameter for evaluating the MLD from the Argo data are statistically determined. The MLD and its properties from each density profile were calculated with the method and parameter. The monthly mean climatology of the MLD is computed on a 2° × 2° grid with more than 30 profiles for each grid. Two bands of deep mixed layer with more than 200 m depth are found to the north and south of the Kuroshio Extension in the winter climatology, which cannot be reproduced in some previous climatologies. Early shoaling of the winter mixed layer between 20–30°N, which has been pointed out by previous studies, is also well recognized. A notable feature suggested by our climatology is that the deepest mixed layer tends to occur about one month before the mixed layer density peaks in the middle latitudes, especially in the western region, while they tend to coincide with each other in higher latitudes.     

A three‐component end‐member analysis of streamwater hydrochemistry in a small Japanese forested headwater catchment

Intensive water sampling in conjunction with hydrological observations was conducted during three different rainstorms in order to understand the effects of rainfall events on the temporal variation of streamwater chemistry in a small headwater forest catchment. Concentrations of Na⁺ and SO₄^2? decreased as the discharge rate increased. Hydrograph separation of the components was made using the three‐component model based on the end‐members mixing analysis (EMMA). The three end‐members were:

• 1 the groundwater in the saturated zone that prescribes the chemistry of the baseflow;
• 2 the throughfall that dilutes the streamwater;
• 3 the groundwater in the transient saturated zone prescribed, which was dependent on the groundwater level.

When the groundwater level was lower, only the two components, groundwater in the saturated zone and throughfall, affected the streamwater chemistry. When the groundwater level rose and the saturated zone spread, the groundwater in the transient saturated zone became the third component. When the groundwater in the transient saturated zone contributed to the discharge, this component became the dominant source and the streamwater chemistry was affected by the groundwater chemistry in the transient saturated zone. When this component was discharged as the saturation overland flow, the streamwater chemistry was greatly affected by this component. Copyright © 2001 John Wiley & Sons, Ltd.     

Reproducibility and variability of submesoscale frontal eddies on a broad,low-energy shelf of freshwater influence

Ocean Dynamics - A multi-decadal simulation of ocean circulation in the northern Gulf of Mexico produces strong submesoscale instabilities in the Mississippi/Atchafalaya plume fronts. The model...     

Experimental study on prevention of acid mine drainage by silica coating of pyrite waste rocks with amorphous silica solution

Acid mine drainage (AMD) is a widespread environmental problem associated with working and abandoned mining operations. It results from the microbial oxidation of pyrite in the presence of water and air, affording an acidic solution that contains toxic metal ions. Pyrite microencapsulation, utilizing silica coating, is a novel approach for controlling AMD that has been shown to be very effective in controlling pyrite oxidation. The roles of the solution pH and silica concentration in the formation mechanism for the AMD-preventing coating were investigated. A silica coating can be formed from silica solution at pH 7, at which the amount of Fe eluted from pyrite into the solution is small. No coating was formed at other pH values, and the amounts of eluted Fe were larger than at pH 7, especially at pH 11. The silica coating forms from 2,500 to 5,000 mg/L silica solutions, but not from 0 or 1,000 mg/L silica solutions. The coating formation rate was slower in the 2,500 mg/L silica solution than in the 5,000 mg/L silica solution. The formation of silica coating on pyrite surfaces depends on three main steps: formation of Fe(OH)₃ on the surface of pyrite, reaction between Fe(OH)₃ and silicate in the solution on the pyrite surface, and growth of the silica layer on the first layer of silica. The best pH condition to enable these steps was around 7, and the silica coating formation rate can be controlled by the concentration of silica.     

GIS-based weights-of-evidence modelling of rainfall-induced landslides in small catchments for landslide susceptibility mapping

Landslide susceptibility mapping is a vital tool for disaster management and planning development activities in mountainous terrains of tropical and subtropical environments. In this paper, the weights-of-evidence modelling was applied, within a geographical information system (GIS), to derive landslide susceptibility map of two small catchments of Shikoku, Japan. The objective of this paper is to evaluate the importance of weights-of-evidence modelling in the generation of landslide susceptibility maps in relatively small catchments having an area less than 4 sq km. For the study area in Moriyuki and Monnyu catchments, northeast Shikoku Island in west Japan, a data set was generated at scale 1:5,000. Relevant thematic maps representing various factors (e.g. slope, aspect, relief, flow accumulation, soil depth, soil type, land use and distance to road) that are related to landslide activity were generated using field data and GIS techniques. Both catchments have homogeneous geology and only consist of Cretaceous granitic rock. Thus, bedrock geology was not considered in data layering during GIS analysis. Success rates were also estimated to evaluate the accuracy of landslide susceptibility maps and the weights-of-evidence modelling was found useful in landslide susceptibility mapping of small catchments.     

A fluidized landslide on a natural slope by artificial rainfall

An experiment to induce a fluidized landslide by artificial rainfall was conducted on a natural slope at Mt. Kaba-san in the village of Yamato, Ibaraki Prefecture, Japan. The experimental slope was 30 m long, 5 m wide, and the average slope gradient was 33°. A landslide initiated 24,627.5 s (410 m/27.5 s) after the start of sprinkling at a rainfall intensity of 78 mm/h. The landslide mass was 14 m long and 1.2 m deep (at maximum). It first slid, then fluidized, and changed into a debris flow. The travel distance was up to 50 m in 17s. The apparent friction angle of the fluidized landslide was 16.7°. Formation of the sliding surface was detected by soil-strain probes. Motion of the surface of the failed landslide mass was determined by stereo photogrammetry.     

Rapid development of arctic cyclone in June 2008 simulated by the cloud resolving global model NICAM

In this study, we conducted a numerical simulation of a rapid development of an arctic cyclone (AC) that appeared in June 2008 using a cloud resolving global model, Nonhydrostatic ICosahedral Atmospheric Model (NICAM). We investigated the three dimensional structure and intensification mechanism of the simulated AC that developed to the minimum sea level pressure of 971 hPa in the model. According to the result, the AC indicates a barotropic structure with a warm core in the lower stratosphere and a cold core in the troposphere. The development of the AC is accompanied by an intense mesoscale cyclone (MC) showing baroclinic structure with a marked local arctic front. The upper level warm core of the AC is formed by an adiabatic heating associated with the downdraft in the lower stratosphere. The rapid development of the AC is caused by the combination of the intensification of the upper level warm core and the merging with the baroclinically growing MC in the lower level. The merging of the AC and MC and the vertical vortex coupling with the upper air polar vortex are the most important mechanisms for the rapid development of the arctic cyclone.     

TIDAL FEATURES IN THE CHINA SEAS AND THEIR ADJACENT SEA AREAS AS DERIVED FROM TOPEX／POSEIDON ALTIMETER DATA

Some important tidal features of 8 major tidal constituents (M2, S2, K1, O1, P1,Sa, N2 and K2 ) in the china Seas and their adjacent sea areas were obtained using six years‘ TOPEX/POSEIDON altimeter data. The results showed that the obtained co-tidal and co-range charts for these major tidal constituents agreed well with those of previous researches using observational data from coastal tidal gauge stations and numerical models.